Electrochromic device

• US 4,447,133 A
• Filed: 04/27/1981
• Issued: 05/08/1984
• Est. Priority Date: 04/27/1981
• Status: Expired due to Term

• Current Assignee: Seiko Instruments & Electronics Ltd. (Seiko Group)
• Original Assignee: Seiko Instruments & Electronics Ltd. (Seiko Group)
• Inventors: Miyoshi, Taisuke
• Primary Examiner(s): Davie, James W.
• Application Number:
  US06/257,873
• Time in Patent Office: 1,107 Days
• Field of Search: 350/357
• US Class Current: 359/265
• CPC Class Codes: C23C 14/226 in order to form films with columnar structure
• CPC Class Codes: C23C 14/24 Vacuum evaporation
• CPC Class Codes: G02F 1/1524 Transition metal compounds
• CPC Class Codes: G02F 1/1525 characterised by a particular ion transporting layer, e.g. electrolyte

Abstract

An electrochromic device includes a layer of electrochromic material, such as tungsten oxide, which is deposited by oblique evaporation at an acute angle of incidence in the range of from 30° to 70° between the normal to the substrate and the direction of the evaporation. Due to the anisotropic topography achieved by the oblique evaporation, the layer of electrochromic material exhibits improved fast response time and long life time of cycling of coloration and bleaching.

Claims

1. In an electrochromic device of the type having a substrate, an electrode disposed on the substrate, a layer of electrochromic material disposed in a predetermined pattern on the electrode and an electrolyte disposed on the layer of electrochromic material, the improvement comprising:

said layer of electrochromic material having anisotropic topography formed by depositing by evaporation said electrochromic material such that the direction of evaporation makes an acute angle in the range of from 30°

to 70°

with respect to the normal to said substrate.

2. An electrochromic device according to claim 1;

wherein said layer of electrochromic material having anisotropic topography comprises a film deposited by the evaporation of electrochromic material with the angle of incidence between the normal to the substrate and the direction of the evaporation in the range of from 40°

to 6°

.

3. An electrochromic device according to claim 1;

in which said electrolyte comprises an acid.

4. An electrochromic device according to claim 3;

in which said acid comprises sulfuric acid.

5. An electrochromic device according to claim 1;

in which said electrolyte comprises a salt.

6. An electrochromic device according to claim 5;

in which said salt comprises lithium perchlorate.

7. An electrochromic device according to claim 1;

in which said electrolyte comprises an ionic conductive compound.

8. An electrochromic device according to claim 7;

in which said ionic conductive compound comprises lithium nitride.

9. An electrochromic device according to claim 1;

wherein said layer of electrochromic material comprises tungsten oxide.

10. An electrochromic device according to claim 1;

wherein the thickness of said layer of electrochromic material is in the range of from about 0.1 μ

m to 0.5 μ

m.

11. An electrochromic device according to claim 1, or 2 wherein said layer of electrochromic material having anisotropic topography comprises rowlike columnar arrays of electrochromic material which make an acute angle with respect to the normal to said substrate.

12. In an electrochromic device of the type having a substrate, an electrode disposed on the substrate, a layer of electrochromic material disposed in a predetermined pattern on the electrode and operable to undergo cycles of coloration and bleaching during use of the electrochromic device, and an electrolyte disposed on the layer of electrochromic material, the improvement comprising:

said layer of electrochromic material having an anisotropic topography formed by the deposition by evaporation of electrochromic material at a direction of evaporation which makes an acute angle in the range of from 30°

to 70°

with respect to the normal to said substrate to effectively speed up the response time of coloration and bleaching as compared to electrochromic material of the same composition having isotropic topography.

13. An electrochromic device according to claim 12;

wherein said layer of electrochromic material having anisotropic topography comprises rowlike columnar arrays of electrochromic material which make an acute angle with respect to the normal to said substrate.

14. An electrochromic device according to claim 12;

wherein the predetermined pattern of the layer of electrochromic material comprises a plurality of display segments each capable of exhibiting colored and bleached states; and

means for applying a DC electric field between preselected ones of the colored and bleached display segments to effect the transfer of electric charges for coloration through the electrolyte from the colored to the bleached display segments.

15. In an electrochromic display device of the type having a substrate, an electrode disposed on the substrate, layers of electrochromic material forming plural segments and disposed on the electrode, and an electrolyte disposed on the layers of electrochromic material, the improvement comprising:

said layers of electrochromic material having anisotropic topography formed by depositing by evaporation said electrochromic material such that the direction of evaporation makes an acute angle in the range of from 30°

to 70°

with respect to the normal to said substrate, and means for applying a DC electric field between preselected ones of the electrochromic layers on the electrode to effect the transfer of electric charges through the electrolyte between the selected electrochromic layers.

16. An electrochromic display device according to claim 15;

wherein the layers of electrochromic material are formed by depositing by evaporation said electrochromic material such that the direction of evaporation makes an acute angle in the range of from 40°

to 60°

with respect to the normal to said substrate.