Polyurethane

• US 4,447,591 A
• Filed: 02/23/1982
• Issued: 05/08/1984
• Est. Priority Date: 05/08/1981
• Status: Expired due to Term

• Current Assignee: Daicel Chemical Industries Limited (Daicel Corporation)
• Original Assignee: Daicel Chemical Industries Limited (Daicel Corporation)
• Inventors: Watanabe, Shoji, Miho, Takuya
• Primary Examiner(s): Nielsen, Earl A.
• Application Number:
  US06/351,578
• Time in Patent Office: 805 Days
• Field of Search: 528/354, 528/355, 528/357, 528/80, 528/81, 560/185
• US Class Current: 528/80
• CPC Class Codes: C08G 18/4277 Caprolactone and/or substituted caprolactone
• CPC Class Codes: C08G 63/08 Lactones or lactides

Abstract

A polyurethane comprises (a) organic diisocyanate units and (b) polycaprolactone polyol units having a narrow molecular weight distribution in which a ratio of the weight average molecular weight to the number average molecular weight is in the range of from 1.1 to 2.0 and the average molecular weight is 500 to 5,000, the units (a) and (b) being connected linearly through urethane linkages.

Claims

1. A process for the preparation of polyurethanes which comprises reacting an organic diisocyanate with a polycaprolactone polyol having a narrow molecular weight distribution in which the ratio of the weight average molecular weight to the number average molecular weight is in the range of from 1.1 to 2.0 and the average molecular weight is 500 to 5,000, said polycaprolactone polyol having been prepared by subjecting a lactone to ring-opening polymerization in the presence of 0.1 to 50 ppm of stannous halide selected from the group consisting of stannous chloride, stannous bromide and stannous iodide, as a catalyst, and at a temperature of from 100°

to 230°

C.

2. A process claimed in claim 1 in which said lactone is epsilon-caprolactone.

3. A polyurethane prepared by the process of claim 1.