Method of preparing a light weight cement composition from sea water

• US 4,450,009 A
• Filed: 04/29/1983
• Issued: 05/22/1984
• Est. Priority Date: 04/29/1983
• Status: Expired due to Fees

• Current Assignee: Halliburton Company
• Original Assignee: Halliburton Company
• Inventors: Brothers, Lance E., Childs, Jerry D., Taylor, Mary J.
• Primary Examiner(s): Poer, James
• Application Number:
  US06/490,088
• Time in Patent Office: 389 Days
• Field of Search: 106/76, 106/89, 106/90, 166/293
• US Class Current: 106/606
• CPC Class Codes: C04B 22/0026 Salt water, e.g. seawater
• CPC Class Codes: C04B 22/062 of the alkali or alkaline-earth metals
• CPC Class Codes: C04B 22/08 Acids or salts thereof C04B22/0013 takes precedence
• CPC Class Codes: C04B 24/18 Lignin sulfonic acid or derivatives thereof, e.g. sulfite lye
• CPC Class Codes: C04B 28/24 containing alkyl, ammonium or metal silicates; containing silica sols reaction mixtures resulting in mineral polymers C04B28/006; polymeric reaction products of alkali metal silicates with isocyanates C08G18/3895
• CPC Class Codes: C04B 7/02 Portland cement
• CPC Class Codes: C09K 8/46 containing inorganic binders, e.g. Portland cement

Abstract

A method of preparing a light weight cement composition from sea water. The light weight cement composition is prepared by adding a hydroxide compound to sea water and subsequently adding a hydraulic cement and silicate compound to the sea water. Optionally, a mixture of hydroxide compound and silicate compound may be formed and this mixture can be added to the sea water prior to the addition of hydraulic cement.

Claims

1. A method of preparing a cement composition having a density of from about 11.0 to about 16.0 pounds per gallon comprising:

(a) adding to sea water a hydroxide compound selected from the group consisting of an alkali metal hydroxide, ammonium hydroxide and mixtures thereof said hydroxide compound being present in the range of about 0.2 percent to about 2.0 percent by weight of sea water;

(b) adding to the mixture of step (a) a silicate compound selected from the group consisting of an aqueous alkali metal silicate, an aqueous ammonium silicate and mixtures thereof; and

(c) adding to the mixture of step (b) a hydraulic cement;

wherein said sea water is present in the range of from about 42 percent to about 190 percent by weight of hydraulic cement and said silicate compound is present in the range of from about 0.40 percent to about 3.40 percent by weight of hydraulic cement.

2. The method recited in claim 1 further comprising adding a cement set retarder to said sea water prior to the addition of the hydroxide compound to the sea water.

3. The method recited in claim 2 wherein said silicate is an alkali metal silicate and has a molar ratio of silicon dioxide to alkali metal oxide in the range of from about 1.5:

2 to about 3.3;

1 and the alkali metal is selected from the group consisting of potassium, sodium, and mixtures thereof.

4. The method recited in claim 3 wherein said silicate has a molar ratio of silicon dioxide to alkali metal oxide of about 3.22:

1.

5. The method recited in claim 3 wherein said hydraulic cement is API Class G Portland cement.

6. The method recited in claim 3 wherein said hydroxide is sodium hydroxide.

7. The method recited in claim 6 wherein the density of said cement composition is from about 11.4 pounds to about 14.0 pounds per gallon.

8. The method recited in claim 7 wherein said sea water is present in the range of about 73 percent to about 170 percent by weight of hydraulic cement.

9. The method recited in claim 8 wherein said sodium hydroxide is present in an amount that raises the pH of the sea water to at least 12 and is at least stoichiometric to the amount of magnesium present in the sea water.

10. The method recited in claim 8 wherein said cement set retarder is sodium lignosulfonate.

11. A method of preparing a cement slurry having a density of from about 11 to about 16 pounds per gallon from sea water comprising:

(a) forming a mixture of a hydroxide compound selected from the group consisting of an alkali metal hydroxide, ammonium hydroxide, calcium hydroxide, and mixtures thereof and a silicate compound selected from the group consisting of an aqueous alkali metal silicate, an aqueous ammonium silicate and mixtures thereof;

(b) adding the mixture of step (a) to sea water; and

,

(c) add a hydraulic cement to the mixture of step (b);

wherein said hydroxide is present in the range of from about 0.2 percent to about 2.0 percent by weight of sea water, said sea water is present in the range of from about 42 percent to about 190 percent by weight of hydraulic cement and said silicate compound is present in the range of about 0.40 percent to about 3.40 percent by weight of hydraulic cement.

12. The method recited in claim 11 further comprising adding a cement set retarder to the sea water before the mixture of step (a) is added to the sea water.

13. The method recited in claim 12 wherein said silicate compound is an alkali metal silicate and has a molar ratio of silicon dioxide to alkali metal oxide in the range of from about 1.5:

2 to about 3.3;

1 and the alkali metal is selected from the group consisting of potassium, sodium, and mixtures thereof.

14. The method recited in claim 13 wherein said silicate has a molar ratio of silicon dioxide to alkali metal oxide of about 3.22:

1.

15. The method recited in claim 14 wherein said hydraulic cement is API Class G Portland cement.

16. The method recited in claim 15 wherein said hydroxide is sodium hydroxide.

17. The method recited in claim 16 wherein the density of said cement composition is in the range of from about 11.4 to about 14.0 pounds per gallon.

18. The method recited in claim 17 wherein said sea water is present in the range of about 73 percent to about 170 percent by weight of hydraulic cement.

19. The method recited in claim 18 wherein said sodium hydroxide is present in an amount that raises the pH of the sea water to at least 12 and is at least stoichiometric to the amount of magnesium present in the sea water.

20. The method recited in claim 19 wherein said cement set retarder is sodium lignosulfonate.