Oxygen sensor

• US 4,450,065 A
• Filed: 07/26/1982
• Issued: 05/22/1984
• Est. Priority Date: 03/09/1982
• Status: Expired due to Term

• Current Assignee: NGK Spark PLUG Company Limited (Niterra Co., Ltd.)
• Original Assignee: NGK Spark PLUG Company Limited (Niterra Co., Ltd.)
• Inventors: Nakayama, Yutaka, Yamada, Tetsusyo
• Primary Examiner(s): Kaplan, G. L.
• Application Number:
  US06/402,071
• Time in Patent Office: 666 Days
• Field of Search: 204/425, 204/426, 204/1 S, 204/412, 204/410, 422/94, 422/95, 422/96, 422/97, 123/489, 60/276
• US Class Current: 204/412
• CPC Class Codes: G01N 27/4072 characterized by the diffusion barrier
• CPC Class Codes: G01N 27/417 using cells , i.e. more than one cell and probes with solid electrolytes

Abstract

The disclosed oxygen sensor has a plate-like oxygen pump element with electrodes, a plate-like oxygen concentration cell element with electrodes, and a means to couple the two elements in parallel to each other while forming a gap between those electrodes of the two elements which face with each other, so that the oxygen concentration cell element measures a ratio between oxygen concentration in said gap and oxygen concentration of a gas surrounding outside of the oxygen sensor, while said oxygen pump element causes diffusion of oxygen between said gap and the outside of the oxygen sensor.

Claims

1. An oxygen sensor, comprising an oxygen pump element having a first oxygen-ion-conductive solid electrolyte board with electrode layers attached to opposite surfaces at one end of the first board, an oxygen concentration cell element having a second oxygen-ion-conductive solid electrolyte board with electrode layers attached to opposite surfaces at one end of the second board, and a means for coupling said oxygen pump element and said oxygen concentration cell element in parallel to each other with a gap between the electrode layers attached to the opposing surfaces of the first board and the second board, the edges of said gap being open to the surrounding atmosphere along at least three sides thereof, whereby said oxygen concentration cell element generates electromotive force caused by the difference between oxygen concentration in said gap and oxygen concentration of a gas surrounding the outside of the oxygen sensor while said oxygen pump element performs oxygen transportation therethrough from said gap to the outside of the oxygen sensor or vice versa to cause said oxygen concentration difference therebetween.

2. An oxygen sensor as set forth in claim 1, wherein said means for coupling is an adhesive layer consisting of a heat-resisting inorganic adhesive.

3. An oxygen sensor as set forth in claim 1, wherein said first and second oxygen-ion-conductive solid electrolyte boards are made of solid electrolyte selected from the group consisting of solid solutions of zirconia and yttria, solid solutions of zirconia and calcia, solid solutions of cerium dioxide, solid solutions of thorium dioxide, solid solutions of hafnium dioxide, solid solutions of perovskite type oxides, and solid solutions of oxides of trivalent metals.

4. An oxygen sensor as set forth in claim 1, wherein said electrode layers are made of heat-resisting metallic layers made of at least one metal selected from the group consisting of platinum (Pt), ruthenium (Ru), palladium (Pd), rhodium (Rh), iridium (Ir), gold (Au) and silver (Ag).

5. An oxygen sensor as set forth in claim 1, wherein said gap is 0.01-0.5 mm wide.

6. An oxygen sensor as set forth in claim 1, wherein said gap is substantially square and has one side thereof closed by said means for coupling and three sides thereof left open.

7. An oxygen sensor comprising an oxygen pump element having a first oxygen-ion-conductive solid electrolyte board with electrode layers attached to opposite surfaces at one end of the first board;

an oxygen concentration cell element having a second oxygen-ion-conductive solid electrolyte board with electrode layers attached to opposite surfaces at one end of the second board;

a means for coupling said oxygen pump element and said oxygen concentration cell element in parallel to each other with a gap between the electrode layers attached to the opposing surfaces of the first board and the second board, the edges of said gap being open to the surrounding atmosphere along at least three sides thereof; and

at least one heater element attached to the outer surface of said oxygen pump element, said heater element having through holes bored at those portions which correspond to the electrode layer of said oxygen pump element, said electrode layer being exposed to the outside of said oxygen sensor through said opening of the heater element, whereby said oxygen concentration cell element generates electromotive force caused by the difference between the oxygen concentration in said gap and the oxygen concentration of a gas surrounding the outside of the oxygen sensor while said oxygen pump element performs oxygen transportation therethrough from said gap to the outside of the oxygen sensor, or vice versa, to cause said oxygen concentration difference therebetween.

8. An oxygen sensor as set forth in claim 7, wherein the heater element has a main body made of an electrically insulating inorganic material selected from the group consisting of alumina and spinel.

9. An oxygen sensor as set forth in claim 7, wherein heater elements are attached to the outer surfaces of said oxygen pump element and said oxygen concentration cell element, said heater elements having through holes bored at those portions which correspond to electrode layers of said oxygen pump element and said oxygen concentration cell element, whereby said electrode layers are exposed to the outside of said oxygen sensor through said openings of the heater elements.