Impact improvement of high nitrile resins

• US 4,450,254 A
• Filed: 06/25/1982
• Issued: 05/22/1984
• Est. Priority Date: 11/03/1980
• Status: Expired due to Fees

• Current Assignee: Standard Oil Company (BP PLC)
• Original Assignee: Standard Oil Company (BP PLC)
• Inventors: Duke, June T., Prem, Dorothy C., Isley, Ralph E.
• Primary Examiner(s): Henderson, C. A.
• Application Number:
  US06/392,392
• Time in Patent Office: 697 Days
• Field of Search: 524/394, 524/399, 524/400, 524/523, 524/534
• US Class Current: 524/399
• CPC Class Codes: C08K 5/098 Metal salts of carboxylic acids
• CPC Class Codes: C08L 51/04 grafted on to rubbers

Abstract

The impact resistance of high nitrile thermoplastic resins is greatly improved by including metal carboxylate compounds therein. Examples of metal carboxylate compounds useful herein include calcium stearate, calcium pelargonate, calcium laurate, zinc laurate, zinc stearate, aluminum distearate, aluminum laurate and aluminum pelargonate.

Claims

1. An impact resistant resin composition which comprises an intimate mixture of (1) a copolymer produced by the polymerization of a major proportion of a mono-unsaturated nitrile and a minor proportion of at least one monovinyl monomer component copolymerizable therewith in the presence of a preformed diene rubber;

and (2) a metal carboxylate selected from the group consisting of calcium pelargonate, calcium laurate, aluminum pelargonate, aluminum laurate and aluminum distearate.

2. The composition of claim 1 wherein the copolymer comprises (A) from 60 to 90 percent by weight of at least one nitrile having the structure:

##STR9## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (B) from 10 to 40 percent by weight based on the combined weight of (A) and (B) of at least one member selected from the group consisting of (1) an ester having the structure;

##STR10## wherein R₁ is hydrogen, an alkyl group having from 1 to 30 carbon atoms, or halogen, and R₂ is an alkyl group having from 1 to 6 carbon atoms, (2) an alpha-olefin having the structure;

##STR11## wherein R₃ and R₄ are alkyl groups having from 1 to 7 carbon atoms, (3) a vinyl ether selected from the group consisting of methyl vinyl ether, ethyl vinyl ether, the propyl vinyl ethers and the butyl vinyl ethers, (4) vinyl acetate, (5) styrene, and (6) indene, in the presence of from 0 to 40 parts by weight of (C) a rubber polymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and a comonomer selected from the group consisting of styrene, a monomer having the structure;

##STR12## wherein R has the foregoing designation, and an ester having the structure;

##STR13## wherein R₁ and R₂ have the foregoing respective designations, said rubber polymer containing from 50 to 100 percent by weight of polymerized conjugated diene and from 0 to 50 percent by weight of a comonomer.

3. The composition of claim 2 wherein (A) is acrylonitrile.

4. The composition of claim 2 wherein (B) is methyl acrylate.

5. The composition of claim 2 wherein (B) is styrene.

6. The composition of claim 2 which contains more than 70 percent of (A) and less than 30 percent of (B).