Separation and purification of gases and vapors by continuous pressure-swing adsorption

• US 4,452,612 A
• Filed: 09/22/1982
• Issued: 06/05/1984
• Est. Priority Date: 09/22/1982
• Status: Expired due to Fees

• Current Assignee: Cubemco Incorporated
• Original Assignee: Cubemco Incorporated
• Inventors: Mattia, Manlio M.
• Primary Examiner(s): Spitzer, Robert H.
• Application Number:
  US06/421,642
• Time in Patent Office: 622 Days
• Field of Search: 55/31, 55/33-35, 55/58, 55/60-62, 55/77, 55/78, 55/179-181, 55/189, 55/208, 55/390, 55/25, 55/26
• US Class Current: 95/100
• CPC Class Codes: B01D 2253/102 Carbon
• CPC Class Codes: B01D 2253/106 Silica or silicates
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2253/34 Specific shapes
• CPC Class Codes: B01D 2256/10 Nitrogen
• CPC Class Codes: B01D 2256/245 Methane
• CPC Class Codes: B01D 2257/104 Oxygen
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2259/40015 with two sub-steps
• CPC Class Codes: B01D 2259/4003 with two sub-steps
• CPC Class Codes: B01D 2259/4006 Less than four
• CPC Class Codes: B01D 2259/40066 Six
• CPC Class Codes: B01D 2259/404 using four beds
• CPC Class Codes: B01D 53/0415 Beds in cartridges
• CPC Class Codes: B01D 53/047 Pressure swing adsorption
• CPC Class Codes: B01D 53/06 with moving adsorbents, e.g. rotating beds B01D53/025 takes precedence
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

An apparatus for separating or purifying gaseous material having more or less adsorbable components includes a high pressure inlet chamber, a high pressure outlet chamber and a low pressure chamber. Adsorbent means retain an adsorbent capable of selectively adsorbing the more adsorbable component at a predetermined pressure level. There are also means for establishing a high pressure flow path for the gaseous material from the high pressure inlet chamber through the adsorbent means to the high pressure outlet chamber. The more adsorbable component is adsorbable by the adsorbent in the high pressure flow path. Further means establish a low pressure desorption flow path from the adsorbent means to the low pressure chamber. The two means for establishing flow paths are operable simultaneously to continuously separate or purify the gaseous material. A process for separating or purifying gaseous material is also disclosed. The gaseous material is pressurized to a pressure at which the more adsorbable component will be adsorbed by an adsorbent preferentially compared the less adsorbable component. The pressurized gaseous material is caused to flow through and contact the adsorbent to adsorb the more adsorbable component, thereby separating the more adsorbable component from the less adsorbable component.

Claims

1. A pressure swing adsorption process for separating or purifying a gas mixture having more and less adsorbable components selectively adsorbable at predetermined pressure levels comprising continuously and simultaneously subjecting a rotating bed of adsorbent material to the following steps by rotating the bed to sequentially align discrete adjacent sections of the bed with a plurality of sectors within a single vessel:

(a) sequentially aligning each section of the bed with a first sector of the vessel in which pressurized gas mixture flows through the section of the bed aligned with the first sector and contacts the adsorbent to adsorb the more adsorbable component, thereby separating the more adsorbable component from the less adsorbable component;

(b) recovering the unadsorbed less adsorbable component as a primary product;

(c) subsequently sequentially aligning each section with a second sector of the vessel in which the pressure is lowered to desorb from the section of the bed aligned with the second sector the adsorbed more adsorbable component and any adsorbed portion of the less adsorbable component; and

(d) recovering the desorbed components as a secondary product.

2. A process according to claim 1 further comprising repressurizing the desorbed components and recycling a portion of the desorbed components through the process beginning at step (a).

3. A process according to claim 1 or 2 further comprising maintaining a constant low pressure in the section of the bed aligned with the second sector during step (c).

4. A process according to claim 1 further comprising a step between steps (b) and (c) of subsequently sequentially aligning each section with a third sector of the vessel in which the pressure is lowered in the section of the bed aligned with the third sector to an intermediate pressure between the pressures of steps (a) and (c).

5. A process according to claim 1 further comprising the use of two rotating beds, each in separate vessels operating in a series manner and containing different adsorbent materials each capable of preferentially adsorbing different components of the gas mixture and further comprising the steps of:

(e) pressurizing the desorbed components from step (d);

(f) causing the pressurized desorbed components to contact and flow through a first section of the second rotating bed containing a different adsorbent capable of selectively adsorbing the previously less adsorbable component of the first rotating bed to adsorb the previously less adsorbable component of the first rotating bed, the first section of the second bed being aligned with a first sector of the second vessel;

(g) recovering from the second bed the unadsorbed previously more adsorbable component of the first bed;

(h) subsequently sequentially aligning each section of the second bed with a second sector of the second vessel in which the pressure is lowered to desorb from the aligned section of the second bed aligned with the second sector of the second vessel the adsorbed previously less adsorbable component of the first bed and any adsorbed portion of the previously more adsorbable component of the first bed;

(i) recovering the desorbed components from the second bed; and

(j) pressurizing at least a portion of the desorbed components and recycling them to the first vessel to join with the process stream in step (a).

8. A process according to claim 1 or 6 further comprising purging and regenerating the adsorbent with a hot gas.

9. A process according to claim 1 or 6 further comprising the steps of heating at least a portion of the adsorbed and desorbed more adsorbable component and at least a portion of any adsorbed and desorbed portion of the less adsorbable component, and purging and regenerating the adsorbent with the heated components.

6. A pressure swing adsorption process for separating or purifying a gas mixture having more and less adsorbable components selectively adsorbable at predetermined pressure levels comprising continuously and simultaneously subjecting a rotating bed of adsorbent material to the following steps by rotating the bed to sequentially align discrete adjacent sections of the bed with a plurality of sectors within a single vessel:

(a) sequentially aligning each section of the bed with a first sector of the vessel in which the pressurized gas mixture flows through the section of the bed aligned with the first sector and contacts the absorbent to adsorb the more adsorbable component, thereby separating the more adsorbable component from the less adsorbable component;

(b) recovering the unadsorbed less adsorbable component as a primary product;

(c) subsequently sequentially aligning each section of the bed with a second sector of the vessel in which the pressure is lowered in the section of the bed aligned with the second sector to an intermediate pressure between the pressures of steps (a) and (d), whereby some of the adsorbed more adsorbable component and some of the unrecovered adsorbed portion of the less adsorbable component are partially desorbed;

(d) subsequently sequentially aligning each section of the bed with a third sector of the vessel in which the pressure is lowered in the section of the bed aligned with the third sector to desorb the adsorbed more adsorbable component, and to purge and regenerate the adsorbent with a first portion of the partially desorbed components of step (c);

(e) recovering the desorbed components as a secondary product;

(f) subsequently sequentially aligning each section of the bed with a fourth sector of the vessel and increasing the pressure within the section of the bed aligned with the fourth sector to the intermediate pressure of step (c); and

(g) subsequently sequentially aligning each section of the bed with the first segment of the vessel and repeating the process.

7. A process according to claim 6 further comprising at least one step between steps (c) and (d) wherein each section of the bed is aligned with another sector of the vessel in which the pressure is lowered in the section aligned with the other sector to a different intermediate pressure between the pressures of steps (c) and (d), and at least one step between steps (e) and (f) wherein each section of the bed is aligned with an additional sector of the vessel in which the pressure is raised in the section aligned with the additional sector to the level of pressure of the corresponding step between steps (c) and (d).

10. Pressure swing adsorption apparatus for separating or purifying a gas mixture having more and less adsorbable components comprising within a common housing a high pressure inlet chamber, a high pressure outlet chamber, and a low pressure chamber, a rotating bed of adsorbent capable of selectively adsorbing the more adsorbable component at a predetermined pressure level, means for establishing a high pressure flow path for the gas mixture from the high pressure inlet chamber through the adsorbent means to the high pressure outlet chamber, the more adsorbable component being adsorbable by the adsorbent in the high pressure flow path, means for establishing a low pressure desorption flow path from the adsorbent means to the low pressure chamber, the means for establishing the flow paths being operable simultaneously to continuously separate or purify the gas mixture.

11. Apparatus according to claim 10 wherein the rotating bed comprises a bundle of tubes generally parallel to the longitudinal axis, the tubes containing the adsorbent material, the rotating bed and the housing having a common longitudinal axis about which the rotating bed rotates, the rotating bed including apertured plates having a plurality of apertures formed therein, and being attached to opposite ends thereof perpendicular to the longitudinal axis through which the gas mixture flows, the edges of the plates being sealed against the housing with circumferential seals, and wherein the high pressure inlet chamber and the low pressure chamber are located between one end of the housing and one apertured plate at one end of the rotating bed, the apparatus further comprising first baffle means to separate the high pressure inlet chamber from the low pressure chamber to prevent direct flow of the gas mixture therebetween, first sealing means extending between the baffle means and the one apertured plate to seal the interface of the baffle means and the one apertured plate, the high pressure outlet chamber being located between the other end of the housing and the other apertured plate at the other end of the rotating bed, the high pressure outlet chamber being at least partially axially aligned with the high pressure inlet chamber without being aligned with the low pressure chamber, an additional chamber within the housing located adjacent to and separated from the high pressure outlet chamber by second baffle means to prevent flow of the gas mixture therebetween, and second sealing means extending between the second baffle means and the other apertured plate to seal the interface of the second baffle means and the other apertured plate.

12. Apparatus according to claim 11 further comprising means within the housing for establishing a flow path first from the rotating bed to the additional chamber which then becomes an intermediate pressure chamber and then from the intermediate pressure chamber through the rotating bed to the low pressure chamber, wherein the means for establishing the flow path to and from the intermediate pressure chamber comprises a first apertured stationary assembly within the intermediate pressure chamber adjacent to the other apertured plate, the first apertured stationary assembly including means for restricting the flow of the gas mixture therethrough, and a second stationary assembly within the low pressure chamber adjacent to the one apertured plate, the second stationary assembly having a substantially unrestricted flow path between impermeable portions of the second stationary assembly, the first and second stationary assemblies being so aligned as to create a restricted flow path from the intermediate pressure chamber, through the first apertured stationary assembly, through the rotating bed, through the unrestricted flow path between the impermeable portions of the second stationary assembly and into the low pressure chamber.

13. Apparatus according to claim 12 wherein the first stationary apertured assembly is axially aligned with the unrestricted flow path between two impermeable portions of the second stationary assembly.

14. Apparatus according to claim 12 further comprising means for at least partially repressurizing the gas mixture remaining in the rotating bed after the desorbed more adsorbable component flows into the low pressure chamber.

15. Apparatus according to claim 14 further comprising means for repressurizing and recycling from the low pressure chamber to the high pressure inlet chamber a portion of the more adsorbable component and any adsorbed and desorbed portion of the less adsorbable component.

16. Pressure swing adsorption apparatus for separating and purifying a gas mixture having more and less adsorbable components comprising a first apparatus according to claim 10, means for pressurizing the desorbed more adsorbable component and any desorbed portion of the less adsorbable component exiting from the low pressure chamber of the first apparatus, means for conveying at least a portion of the pressurized desorbed more adsorbable component and the pressurized desorbed portion of the less adsorbable component to the high pressure inlet chamber of a second apparatus according to claim 10.

17. Apparatus according to claim 16 wherein both apparatus are housed within the same common housing, and further comprising means for establishing a flow path from the high pressure inlet chamber of the second apparatus through the rotating bed of the second apparatus and directly into the high pressure inlet chamber of the first apparatus.

18. Pressure swing adsorption apparatus for separating and purifying a gas mixture having more and less adsorbable components comprising a first apparatus according to claim 10, means for pressurizing the desorbed more adsorbable component and any desorbed portion of the less adsorbable component exiting from the low pressure chamber of the first apparatus, means for conveying the pressurized desorbed more adsorbable component and the pressurized desorbed portion of the less adsorbable component to the high pressure inlet chamber of a second apparatus according to claim 10, the rotating bed of the second apparatus containing adsorbent capable of selectively adsorbing the component which was the less adsorbable component in the first apparatus, and means for establishing a flow path from the low pressure chamber of the second apparatus to the high pressure inlet chamber of the first apparatus.