Stable dentifrice containing neutral siliceous polishing agent

• US 4,455,293 A
• Filed: 11/17/1982
• Issued: 06/19/1984
• Est. Priority Date: 11/19/1981
• Status: Expired due to Fees

• Current Assignee: Colgate-Palmolive Company
• Original Assignee: Colgate-Palmolive Company
• Inventors: Harvey, Kenneth, Connors, Stephen T.
• Primary Examiner(s): Rose, Shep K.
• Application Number:
  US06/442,476
• Time in Patent Office: 580 Days
• Field of Search: 424/47-58, 206/524.1, 206/524.4
• US Class Current: 424/52
• CPC Class Codes: A61K 2800/526 Corrosion inhibitors
• CPC Class Codes: A61K 8/24 Phosphorous; Compounds thereof
• CPC Class Codes: A61K 8/25 Silicon; Compounds thereof
• CPC Class Codes: A61K 8/26 Aluminium; Compounds thereof
• CPC Class Codes: A61K 8/55 Phosphorus compounds
• CPC Class Codes: A61K 8/556 Derivatives containing from 2 to 10 oxyalkylene groups
• CPC Class Codes: A61Q 11/00 Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses

Abstract

There is disclosed a dentifrice formulation which is stable in the sense of not producing gassing as evidenced by visually discernable distention over a period of 168 days at 43° C. in an unlined aluminium tube.

The formulation comprises an aqueous dentally acceptable oral vehicle at least 27.5% by weight of the dentifrice comprising water and dispersed in the said oral vehicle from 10 to 40% by weight of the dentifrice of a neutral siliceous polishing agent having a stirred slurry pH (as herein defined) in the range from 6.5 to 7.5, and a stabilizing amount of monofluorophosphate ion, the dentifrice having a stirred slurry pH in the range from 5.5 to 8.

Claims

1. A stable dentifrice contained in an unlined aluminium tube consisting essentially of an aqueous dentally acceptable oral vehicle, at least 27.5% by weight of the dentifrice comprising water and dispersed in the said oral vehicle from 10 to 40% by weight of the dentifrice of a neutral sodium aluminosilicate polishing agent containing about 4-5% total aluminium as Al and having a stirred slurry pH in the range from 6.5 to 7.5, and a stabilizing amount of monofluorophosphate ion, the dentifrice having a stirred slurry pH in the range from 5.5 to 8, said monofluorophosphate ion stabilizing said dentifrice against gas generating reaction between the components of said dentifrice when said dentifice is in contact with the surface of said unlined aluminium tube.

2. A dentifrice as claimed in Claim 1 in which the dentifrice comprises at least 30% by weight of water.

3. A dentifrice as claimed in Claim 2 in which the dentifrice comprises 35 and 60% by weight of water.

4. A dentifrice as claimed in Claim 3 in which the dentifrice comprises 39.69 to 55% by weight of water.

5. A dentifrice as claimed in Claim 1 in which the polishing agent comprises 10 to 30% by weight of the dentifrice.

6. A dentifrice as claimed in Claim 5 in which the siliceous agent comprises 15 to 25% by weight of the dentifrice.

7. A dentifrice as claimed in Claim 1 in which the stirred slurry pH of the polishing agent is in the range 6.5 to 7.5.

8. A dentifrice as claimed in Claim 7 in which the stirred slurry pH of the polishing agent is in the range 6.7 to 7.3.

9. A dentifrice as claimed in Claim 1 comprising at least 0.01% of monofluorophosphate ion.

10. A dentifrice as claimed in Claim 9 comprising at least 0.05% of monofluorophosphate ion.

11. A dentifrice as claimed in Claim 10 comprising at least 0.09% of monofluorophosphate ion.

12. A dentifrice contained in an unlined aluminium tube consisting essentially of 35% to 50% by weight water, 0% to 30% by weight of glycerine, 15 to 25% of sodium aluminosilicate polishing agent containing about 4-5% total aluminium as Al and having a stirred slurry pH in the range 6.5 to 7.5, at least 0.5% by weight of alkali metal monofluorophosphate, calcined alumina in an amount in the range 0% to 15% by weight and one or more organic surface active agents in an amount not in excess of 5% by weight, the dentifrice having a stirred slurry pH in the range 5.5 to 8, said monofluorophosphate ion stabilizing said dentifrice against gas generating reaction between the components of said dentifrice when said dentifrice is in contact with the surface of said unlined aluminium tube.