Thermotropic liquid crystalline polymer blend with reduced surface abrasion

• US 4,458,039 A
• Filed: 02/07/1983
• Issued: 07/03/1984
• Est. Priority Date: 02/07/1983
• Status: Expired due to Term

• Current Assignee: Celanese Corporation
• Original Assignee: Celanese Corporation
• Inventors: Eickman, Nancy C.
• Primary Examiner(s): Jacobs, Lewis T.
• Application Number:
  US06/464,272
• Time in Patent Office: 512 Days
• Field of Search: 524/456, 523/216
• US Class Current: 523/216
• CPC Class Codes: C08K 2201/016 Additives defined by their aspect ratio
• CPC Class Codes: C08K 3/34 Silicon-containing compounds
• CPC Class Codes: C08K 7/10 Silicon-containing compounds
• CPC Class Codes: C08K 9/04 Ingredients treated with organic substances treated with macromolecular compounds C08K9/08

Abstract

A thermotropic liquid crystalline polymer matrix having wollastonite fibers incorporated therein for reinforcement to prepare a molding compound. The wollastonite fibers have an average aspect ratio of greater than 3 to 1, and may be coated on their surface with a coupling agent to produce better bonding between the fibers and the thermotropic liquid crystalline polymer. The surface abrasion of an article produced from a blend of wollastonite with a thermotropic liquid crystalline polymer is reduced as compared to that of unfilled polymer.

Claims

1. A molding compound comprising a thermotropic liquid crystalline polymer matrix having wollastonite fibers incorporated therein, the wollastonite fibers having an average aspect ratio of greater than about 3 to 1.

2. The molding compound of claim 1 wherein the wollastonite fibers have an average aspect ratio of at least 10 to 1.

3. The molding compound of claim 1 wherein the wollastonite fibers have an average aspect ratio of at least 20 to 1.

4. The molding compound of claim 1 wherein the wollastonite fibers are treated with a titanate coupling agent prior to being blended with the thermotropic liquid crystalline polymer to produce the molding compound.

5. The molding compound of claim 1 wherein the wollastonite fibers are present in the molding compound at between about 10 and about 70% by weight.

6. The molding compound of claim 1 wherein the wollastonite fibers are present in the molding compound at between about 10 and about 40% by weight.

7. The molding compound of claim 1 wherein the thermotropic liquid crystalline polymer has an inherent viscosity of between about 1.0 and about 15 dl./g. when dissolved in a concentration of 0.1 percent by weight of pentafluorophenol at 60°

C.

8. The molding compound of claim 1 wherein the thermotropic liquid crystalline polymer is selected from the group consisting of a wholly aromatic polyester, an aromatic-aliphatic polyester, a wholly aromatic poly(ester-amide), an aromatic-aliphatic poly(ester-amide), an aromatic polyazomethine, an aromatic polyester-carbonate, and mixtures thereof.

9. The molding compound of claim 1, wherein the thermotropic liquid crystalline polymer is selected from the group consisting of a wholly aromatic polyester, a wholly aromatic poly(ester-amide), an aromatic-aliphatic poly(ester-amide), and mixtures thereof.

10. The molding compound of claim 1, wherein the thermotropic liquid crystalline polymer is a melt processable poly(ester-amide) capable of forming an anisotropic melt phase at a temperature below approximately 400°

C. consisting essentially of recurring moieties I, II, III, and, optionally, IV wherein;

##STR8## where A is a divalent radical comprising at least one aromatic ring or a divalent trans-1,4-cyclohexylene radical;

III is --Y--Ar--Z--, where Ar is a divalent radical comprising at least one aromatic ring, Y is O, NH, or NR, and Z is NH or NR, where R is an alkyl group of 1 to 6 carbon atoms or an aryl group; and

IV is --O--Ar'"'"'--O--, where Ar'"'"' is a divalent radical comprising at least one aromatic ring;

wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures thereof, and wherein said poly(ester-amide) comprises approximately 10 to 90 mole percent of moiety I, approximately 5 to 45 mole percent of moiety II, approximately 5 to 45 mole percent of moiety III, and approximately 0 to 40 mole percent of moiety IV.

11. The molding compound of claim 1, wherein the thermotropic liquid crystalline polymer is a melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 400°

C., consisting essentially of the recurring moieties I, II, and III which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein;

##STR9## II is a dioxy aryl moiety of the formula --O--Ar--O-- where Ar is a divalent radical comprising at least one aromatic ring, and

III is a dicarboxy aryl moiety of the formula ##STR10## where Ar'"'"' is a divalent radical comprising at least one aromatic ring, with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, a phenyl group and mixtures of the foregoing, and wherein said polyester comprises approximately 10 to 90 mole percent of moiety I, approximately 5 to 45 mole percent of moiety II, and approximately 5 to 45 mole percent of moiety III.

12. The molding compound of claim 1, wherein the thermotropic liquid crystalline polymer is a melt processable wholly aromatic polyester capable of forming a thermotropic melt phase at a temperature below approximately 350°

C. consisting essentially of the recurring moieties I and II which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein;

##STR11## with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures of the foregoing, and wherein said polyester comprises approximately 10 to 90 mole percent of moiety I, and approximately 10 to 90 percent of moiety II.

13. A molded article produced from the molding compound of claim 1.

14. An extruded article produced from the molding compound of claim 1.