Method of measuring oxygen using a membrane covered polarographic electrode

• US 4,464,230 A
• Filed: 04/19/1982
• Issued: 08/07/1984
• Est. Priority Date: 04/19/1982
• Status: Expired due to Fees

• Current Assignee: The Board of Regents for Education for the State of Rhode Island
• Original Assignee: University of Rhode Island
• Inventors: Langdon, Christopher
• Primary Examiner(s): Andrews, R. L.
• Assistant Examiner(s): Chapman, Terryence
• Application Number:
  US06/369,474
• Time in Patent Office: 841 Days
• Field of Search: 204/406, 204/415, 204/400, 204/1 T
• US Class Current: 205/782.5
• CPC Class Codes: G01N 27/404 Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid , e.g. Clark-type oxygen sensors

Abstract

An oxygen analyzer which measures the level of dissolved oxygen in a liquid stream. The measuring process embodies chronoamperoemetry of pulsed potential voltammetry. The signal from the electrode is real time averaged. The analyzer does not require temperature, salinity or pressure compensation circuitry and does not have to be calibrated repeatedly.

Claims

1. A method for detecting the level of oxygen in a fluid stream which includes

(a) placing an electrode in electrolytic communication with a fluid stream containing oxygen;

(b) energizing the electrode for a first duration of time (d);

(c) preventing energization of the electrode for an interval of time (i), which is longer than the duration time (d) the electrode providing a signal corresponding to the level of the oxygen in the fluid stream to be measured;

(d) sampling repeatedly the signal generated from the electrode, which signal corresponds to time (d) at a rate and within a predetermined time such that the sampled signal when averaged produces an average signal substantially free of drift;

(e) averaging the signal so sampled;

(f) storing the signals so averaged;

(g) calculating temperature and salinity correction factors and applying said factors to the averaged signals;

(h) providing data corresponding to the level of oxygen in the fluid stream; and

(i) controlling the energization of the electrode and the sampling, averaging and storing of the signal and the application of the correction factors to the averaged signal in timed sequence.

2. The method of claim 1 which includes energizing the electrode with a polarizing voltage.

3. The method of claim 1 wherein the signal generated from the electrode which corresponds to the level of oxygen to be measured is a first signal, and which includes:

sensing a second signal, which signal corresponds to the temperature of the fluid stream.

4. The method of claim 3 which includes selecting alternately for sampling both the first and second signals.

5. The method of claim 4 which includes displaying simultaneously the level of oxygen in the fluid stream and the temperature of the fluid stream.

6. The method of claims 1 or 5 which includes averaging the signal so taken over at least two cycles of the predominant noise frequency.

7. The method of claim 1 which includes:

calculating the time rate of change of oxygen concentration and using linear regression analysis,

displaying said time rate of change.