Calibration standard for infrared absorption gauge

• US 4,465,929 A
• Filed: 08/27/1982
• Issued: 08/14/1984
• Est. Priority Date: 06/18/1982
• Status: Expired due to Term

• Current Assignee: Infrared Engineering Limited Blue Mill Woodham Water Maldon Essex CM9 6LS England
• Original Assignee: Infra-Red Engineering Limited
• Inventors: Edgar, Roger F.
• Primary Examiner(s): Howell, Janice A.
• Assistant Examiner(s): Hannaher, Constantine
• Application Number:
  US06/413,151
• Time in Patent Office: 718 Days
• Field of Search: 250/252.1, 250/338 PY, 250/338, 250/341, 250/353, 356/243
• US Class Current: 250/252.1
• CPC Class Codes: G01J 5/52 using comparison with reference sources, e.g. disappearing-filament pyrometer
• CPC Class Codes: G01N 21/3554 for determining moisture content
• CPC Class Codes: G01N 21/3559 in sheets, e.g. in paper
• CPC Class Codes: G01N 2201/13 Standards, constitution

Abstract

The calibration standard is attached to a sensing head of an infrared absorption gauge for the purpose of calibrating the gauge. The calibration standard includes spectrally selective absorption means having a spectrum closely resembling that of a substance to be measured, such as water sorbed onto a paper sample. The calibration standard also includes optical means for returning infrared radiation, which has passed through the absorption means, to the absorption gauge substantially along the same path as would normally be followed by the radiation reflected from the sample in the absence of the standard. The spectrally selective absorption means is preferably made of anhydrous material, such as glass containing a rare earth substance, or polypropylene, which is stable. The optical means may include diffusing means and a reflective plane. According to one arrangement, the calibration standard comprises a housing with a window at one end, a plurality of diffusing elements attached to a central portion of the window and a reflective plane spaced from the diffusing elements. The window and/or the diffusing elements and/or the reflective plane may comprise or include the spectrally selective absorption means. Various arrangements are described.

Claims

1. A calibration standard for an infrared absorption gauge, said gauge having a source of infrared radiation, an exit to enable said radiation to reach a sample zone and an entrance to transmit the radiation reflected from the sample zone whereby the amount of sorbed substance on a sample, located in the sample zone, can be measured, the calibration standard comprising an assembly which includes spectrally selective absorption means to receive infrared radiation from said exit when said calibration standard co-operates with said absorption gauge, said spectrally selective absorption means having an infrared absorption spectrum resembling that of the substance to be measured, and optical means to return infrared radiation, which has passed through said spectrally selective absorption means, to said entrance substantially along the same path as that followed by infrared radiation from the sample zone to said entrance in the absence of the calibration standard.

2. A calibration standard according to claim 1, wherein the optical means comprises means for diffusing the infrared radiation and means for returning diffused radiation to the entrance of the absorption gauge.

3. A calibration standard according to claim 2, wherein the means for returning the diffused radiation to said entrance comprises a reflective plane.

4. A calibration standard according to claim 1, wherein the optical means is located, within said assembly, so that it is positioned at about one half of the normal operating distance between said exit of the absorption gauge and said sample zone.

5. A calibration standard according to claim 1, wherein said assembly comprises a housing having a window at one end to receive the infrared radiation from the exit of the absorption guage and having a reflective plane adjacent its other end for returning radiation to said entrance of the absorption guage, said spectrally selective absorption means being provided in said assembly to intercept the radiation on its path from said exit in said entrance, and diffusing means being provided to diffuse the radiation passing through said window onto said reflective plane.

6. A calibration standard according to claim 5, wherein said housing is supported by means enabling the housing to be tilted when fitted to the exit of said guage.

7. A calibration standard according to claim 6, wherein said diffusing means is located adjacent a central portion of said window, the diffused radiation reflected from said reflective plane passing through a region of the window surrounding said central portion.

8. A calibration standard according to claim 7, wherein said diffusing means comprises a plurality of spaced diffusing elements.

9. A calibration standard according to claim 8, wherein the diffusing means and the spectrally selective absorption means are structured as a sub-assembly or optical component which is attached to a central portion of said window.

10. A calibration standard according to claim 9, wherein said spectrally selective absorption means and said reflective means are structured or combined as a sub-assembly or optical component.

11. A calibration standard according to claim 10, wherein said window comprises said spectrally selective absorption means.

12. A calibration standard according to claim 11, wherein said spectrally selective absorption means is made of anhydrous material.

13. A calibration standard according to claim 12, wherein said anhydrous material is made of glass containing a rare earth substance.

14. A calibration standard according to claim 12, wherein said anhydrous material is made of polypropylene.

15. A calibration standard according to claim 14, further including spectrally unselective means for absorbing the infrared radiation in its band width in order to reduce the amount of infrared returned by said optical means.

16. A calibration standard according to claim 15, wherein said unselective absorption means absorbs about 70% of the infrared radiation.

17. A calibration standard according to claim 15, wherein the absorption means is made of a radiation transmissive material having a radiation absorptive coating.

18. A calibration standard according to claim 17, wherein said radiation transmissive material comprises said spectrally selective absorption means.

19. A calibration standard according to claim 18, wherein said material is glass in the form of a disc having one side ground and the other side coated with said infrared radiation spectrally unselective absorptive coating.

20. A calibration standard for an infra-red absorption gauge comprising a window for transmitting infra-red radiation, diffusing means for diffusing the infra-red radiation, a reflective plane, and spectrally selective absorption means having an infra-red absorption spectrum resembling that of the substance to be measured, said spectrally selective absorption means being arranged to transmit the infra-red radiation therethrough, and said reflective plane being spaced from said diffusing means and arranged to return the infra-red radiation to said window.

21. A calibration standard according to claim 20, comprising a housing having the window at one end, said reflective plane being adjacent the other end of the housing.

22. A calibration standard according to claim 20, wherein said diffusing means is located adjacent a central portion of said window, the diffused radiation reflected from said reflective plane passing through a region of the window surrounding said central portion.

23. A calibration standard according to claim 20, wherein said diffusing means comprises a plurality of spaced diffusing elements.

24. A calibration standard according to claim 20, wherein said diffusing means and the spectrally selective absorption means are structured as a sub-assembly or optical component which is attached to a central portion of said window.

25. A calibration standard according to claim 20, wherein said spectrally selective absorption means and said reflective plane are structured or combined as a sub-assembly or optical component.

26. A calibration standard according to claim 20, wherein said window comprises said spectrally selective absorption means.

27. A calibration standard according to claim 20, wherein said spectrally selective absorption means is made of inherently anhydrous material.

28. A calibration standard according to claim 27, wherein said anhydrous material is made of glass containing a rare earth substance.

29. A calibration standard according to claim 27, wherein said anhydrous material is made of polypropylene.

30. A calibration standard according to claim 20, wherein spectrally unselective means are also provided for absorbing the infra-red radiation in its bandwidth in order to reduce the amount of infra-red radiation returned to said optical window.

31. A calibration standard according to claim 30, wherein said unselective absorption means absorbs about 70% of the infra-red radiation.

32. A calibration standard according to claim 20, wherein said spectrally selective absorption means is made of a radiation transmissive material having the spectrally selective absorption property.

33. A calibration standard according to claim 32, wherein said material is glass in the form of a disc having one side ground and the other side coated with an infra-red radiation spectrally unselective absorptive coating.