Apparatus for near infrared quantitative analysis with temperature variation correction

• US 4,466,076 A
• Filed: 03/08/1982
• Issued: 08/14/1984
• Est. Priority Date: 05/15/1981
• Status: Expired due to Term

• Current Assignee: Trebor Industries Incorporated (Brownie's Marine Group Incorporated)
• Original Assignee: Trebor Industries Incorporated (Brownie's Marine Group Incorporated)
• Inventors: Rosenthal, Robert D.
• Primary Examiner(s): Chin, Gary
• Application Number:
  US06/355,325
• Time in Patent Office: 890 Days
• Field of Search: 364/496-499, 364/526, 364/557, 364/571, 250/338, 250/341, 250/343, 250/345, 356/416, 356/418
• US Class Current: 702/85
• CPC Class Codes: G01N 21/3563 for analysing solids; Preparation of samples therefor
• CPC Class Codes: G01N 21/359 using near infrared light
• CPC Class Codes: G01N 21/85 Investigating moving fluids or granular solids
• CPC Class Codes: G01N 33/10 Starch-containing substances, e.g. dough
• CPC Class Codes: Y10S 250/91 Food sample analysis using invisible radiant energy source

Abstract

A near infrared quantitative analysis instrument provides for correction of wide temperature variations in unground cereal grain sample and the ambient by providing thermistors to measure the temperature of the sample and the ambient and utilizing the measurements as additional variables in multiple regression equations.

Claims

1. An apparatus for near infrared quantitative analysis providing for correcting wide temperature variations of sample, the apparatus comprising:

(a) means for holding a sample to be analyzed including at least a portion of a wall thereof being transparent to infrared energy,

(b) means to transmit infrared energy toward a sample in the holding means,

(c) a plurality of narrow bandpass filters between the means to transmit infrared energy and the sample holding means to produce desired wavelengths required for quantitative analysis,

(d) sensor means positioned to receive and sense infrared energy transmitted through a sample to be analyzed contained in the holding means, said sensor means producing a signal related to the infrared energy received thereby,

(e) sample temperature measuring means positioned in the sample holding means to measure the temperature of a sample therein and to produce a signal related thereto,

(f) computer means for receiving the signals from the sensor means and sample temperature measuring means and combining them in multiple regression equations to compensate for variations in sample temperature, and

(g) means for reading out the results of the analysis from the computer means.

2. An apparatus as in claim 1 further comprising ambient temperature measuring means positioned outside of the sample holding means to measure the temperature of the ambient and to produce a signal related thereto, and wherein the computer means also requires signals from ambient temperature measuring means and combines them into multiple regression equations to also compensate for variations in ambient temperature.

3. An apparatus as in claim 2 wherein the means to transmit infrared energy toward a sample comprises a plurality of sequentially pulsed infrared emitting diodes (IRED'"'"'s).

4. An apparatus as in claim 3 further comprising;

switch means in a circuit between the output of the sensor means and the sample temperature measuring means and the ambient temperature measuring means and before the computer means for providing a signal to the computer from both temperature measuring means and the sensor means during a cycle of the pulse IREDs.

5. An apparatus as in claim 4 wherein both the sample temperature measuring means and the ambient temperature measuring means are thermistors.

6. An apparatus as defined in claim 5 further comprising a timer for controlling the switch and the pulsing of the IREDs to provide for a cycle including a readout from the IREDs and the thermistors.

7. An apparatus as defined in claim 6 wherein the read out means includes a digital display operated by the computer in response to the result of solving the multiple regression equations.

8. An apparatus as defined in claim 7 wherein the sample is an unground cereal grain.