Apparatus and method for measuring optically active materials

• US 4,467,204 A
• Filed: 02/25/1982
• Issued: 08/21/1984
• Est. Priority Date: 02/25/1982
• Status: Expired due to Term

• Current Assignee: American Crystal Sugar Company
• Original Assignee: American Crystal Sugar Company
• Inventors: Kysilka, James O., Sawicki, Charles A.
• Primary Examiner(s): Howell, Janice A.
• Assistant Examiner(s): Hannaher, Constantine
• Application Number:
  US06/352,321
• Time in Patent Office: 908 Days
• Field of Search: 250/343, 356/364, 356/366, 356/367, 356/368, 356/51
• US Class Current: 250/343
• CPC Class Codes: G01J 1/30 using electric radiation detectors
• CPC Class Codes: G01J 4/04 Polarimeters using electric detection means G01J4/02 takes precedence
• CPC Class Codes: G01N 21/21 Polarisation-affecting properties G01N21/19 takes precedence
• CPC Class Codes: G01N 21/35 using infrared light G01N21/39 takes precedence
• CPC Class Codes: G01N 21/3577 for analysing liquids, e.g. polluted water
• CPC Class Codes: H03F 3/187 in integrated circuits

Abstract

A polarimeter system and method for sensing optical rotation caused by otically active materials in a solution are disclosed. The polarimeter system (10) includes a light source (11) for emitting infrared light, a polarizer (14) operatively connected to intercept the infrared light to produce a polarized beam therefrom and means for directing the beam through a sample of optically active material (15), which rotates the light beam. A beam splitting prism (16) splits the rotated polarized beam into its horizontal and vertical components. Infrared light detectors (17a) and (17b) convert the horizontal and vertical components into electrical signals representative of the optical rotation caused by the sample solution. Shaping circuitry (26) conditions the electrical signals for use by analog or digital (28) networks, that present the optical rotation or its physical correlative factor. Feedback circuitry (36) may be used to vary the light source (11) intensity in response to the detected light signals.

Claims

1. A polarimeter system for sensing optical rotation caused by optically active material in a dark sugar solution, said polarimeter system comprising:

(a) means for containing a liquid sample of optically active material in the dark sugar solution;

(b) an infrared light source for emitting infrared light;

(c) polarizer means operatively connected to intercept at least a portion of said infrared light for producing a polarized light beam therefrom;

(d) means for directing said polarized light beam through at least a portion of said liquid sample; and

(e) infrared light detection means operatively connected to intercept said light beam after passing through said liquid sample, for producing a signal in response to the rotational condition of said polarized light beam, whereby the optical rotation caused by the dark sugar solution may be determined.

2. The polarimeter system of claim 1, wherein the light emitted from said infrared light source has a wavelength equal to or greater than 700 nanometers.

3. The polarimeter system of claim 1, wherein the light emitted from said infrared light source has a wavelength equal to or greater than 875 nanometers.

4. The polarimeter system of claim 1, wherein said infrared light souce comprises an infrared laser diode.

5. The polarimeter system of claim 1, wherein said detection means comprises:

(a) means for splitting said polarized light beam after passing through said liquid sample into two components with orthogonal polarizations;

(b) means for receiving and sensing said components; and

(c) means for determining the ratio of one of said components to the other of said components.

6. The polarimeter system of claim 1, further comprising collimating optic means operatively connected between said light source and said containing means, for collimating at least a portion of said infrared light emitted by said light source.

7. The polarimeter system of claim 1, further comprising a band pass filter operatively connected between said light source and said polarizer means to intercept at least a portion of said infrared light, for passing, only a predetermined wavelength of said infrared light to said polarizing means.

8. The polarimeter system of claim 1, further comprising means for sensing the temperature of the optically active material and means for transmitting a signal responsive to the sensed temperature to said detection means.

9. The polarimeter system of claim 1, further comprising means for varying the intensity of said infrared light source in response to the light absorption property of said liquid sample.

10. A polarimeter system for sensing optical rotation caused by optically active material in a dark sugar solution, said polarimeter system comprising:

(a) means for containing a liquid sample of optically active material in the dark sugar solution;

(b) an infrared light source for emitting infrared light, the light emitted from said infrared light source having a wavelength equal to or greater that 700 nanometers;

(c) polarizer means operatively connected to intercept at least a portion of said infrared light for polarizing said portion of said infrared light to produce a polarized beam of said light;

(d) means for directing said polarized beam through at least a portion of said liquid sample;

(e) collimating optics operatively connected to and positioned between said light source and said containing means;

(f) a band pass filter operatively connected to and positioned between said light source and said polarizer means;

(g) detection means operatively connected to intercept said beam passing through said liquid sample for producing a signal in response to the rotational condition of said polarized beam; and

(h) means for varying the intensity of said infrared light source, in response to the amount of said polarized light beam being asorbed by said liquid sample, whereby the optical rotation caused by the dark sugar solution may be determined.

11. A polarimeter system for sensing optical rotation caused by a dark sugar solution without the need to clarify the dark sugar solution, said polarimeter system comprising:

(a) a sample container for holding a liquid sample of the dark sugar solution;

(b) an infrared light source for emitting infrared light;

(c) polarizer means operatively connected to intercept at least a portion of said infrared light for polarizing said portion of said infrared light to produce a polarized beam of said light;

(d) collimating optics operatively connected to and positioned between said light source and said polarizing means, whereby said infrared light is collimated;

(e) means for positioning said container in alignment with said infrared light source for intercepting said, polarized, collimated light beam wherein said polarized, collimated light beam passes through at least a portion of said sample container holding the dark sugar solution; and

(f) detection means operatively connected to intercept said beam passing through said liquid sample, producing a signal in response to the rotational condition of said polarized beam, whereby the optical rotation caused by the dark sugar solution may be determined.

12. The polarimeter system of claim 11, wherein the light emitted from said infrared light source has a wavelength equal to or greater than 700 nanometers.

13. The polarimeter system of claim 11, wherein said detection means comprises:

(a) means for splitting said polarized beam after passing through said liquid sample into two components with orthogonal polarizations;

(b) means for receiving and sensing said components and for producing sensed output signals in response thereto; and

(c) means for conditioning said sensed signals for processing by electrical networks.

14. The polarimeter system of claim 13, wherein said conditioning means includes means for determining ratio of one of said orthogonal components to the other of said orthogonal components.

15. The polarimeter system of claim 11, further comprising a band pass filter operatively connected to and positioned between said light source and said polarizer means, whereby only a predetermined wavelength of said infrared light passes through said filter to said polarizer means.

16. The polarimeter system of claim 11, further comprising means for measuring the temperature of the optically active material and means for transmitting the temperature measurement to said detection means.

17. A method for determining the optical rotation caused by optically active material in a liquid solution, such material in solution being characterized by being highly absorbent of visible light wavelengths, said method comprising:

(a) polarizing light emitted from an infrared light source;

(b) directing the polarized light through a sample of optically active material; and

(c) detecting the polarized light after passing through the optically active material to determine the optical rotation caused by the optically active material in the liquid solution.

18. A method for determining the optical rotation caused by a dark sugar solution of the type that is highly absorbent to visible light wavelengths, said method comprising:

(a) producing infrared light waves;

(b) transmitting at least portion of said infrared light waves through collimating optics;

(c) polarizing said collimated light emitting from the collimating optics;

(d) directing said polarized light through a dark sugar solution; and

(e) analyzing the optical rotation of the polarized infrared light after passing through said sugar solution, and caused by the sugar solution.

19. The method of claim 18, wherein the analyzing step includes detecting the polarized infrared light after passing through the sugar solution by splitting the polarized light into two components with orthogonal polarizations for use in determining optical rotation.

20. The method of claim 18, wherein the analyzing step includes the step of forming a ratio of the two orthogonal components.