Latent contractable elastomers, composite yarns therefrom and methods of formation and use

• US 4,467,595 A
• Filed: 09/14/1983
• Issued: 08/28/1984
• Est. Priority Date: 08/18/1980
• Status: Expired due to Fees

• Current Assignee: Akzona Incorporated (Nouryon BV)
• Original Assignee: Akzona Incorporated (Nouryon BV)
• Inventors: Kramers, Aloysius A. J.
• Primary Examiner(s): Woo, Jay H.
• Application Number:
  US06/532,338
• Time in Patent Office: 349 Days
• Field of Search: 264/176 F, 264/342 RE, 264/210.8, 528/283, 528/289, 528/272, 57/207, 57/228, 57/226, 57/908, 428/230, 28/156
• US Class Current: 57/225
• CPC Class Codes: D01D 5/08 Melt spinning methods D01D5/0023 takes precedence
• CPC Class Codes: D01F 6/78 from copolycondensation products
• CPC Class Codes: D01F 6/84 from copolyesters
• CPC Class Codes: D02G 3/328 containing elastane

Abstract

This invention relates to melt extruded latent contractable elastic filaments which are formed by melt extruding certain segmented crosslinked thermoplastic polymers to form filaments, which filaments, when heat processed at elevated temperatures, significantly contract to yield an elastic filament. This invention also relates to the formation of composite covered yarn comprising said latent contractable melt extruded filaments. In addition, this invention relates to processes for forming articles from said latent contractable filaments or covered yarns comprising said contractable filaments and subsequently contracting said yarns to form an elastic article.

Claims

1. A latent contractable melt extruded segmented, inherently elastic polyester-polyester or polyester-polyether thermoplastic polymer filament characterized by containing interspersed relatively hard segments and relatively soft segments, which contracts at least 15% in length when subjected to an elevated temperature, as compared to the length of the melt extruded filament without deliberate drawing prior to contraction to yield an elastic filament.

2. The melt extruded filament of claim 1, said segmented thermoplastic copolyester consisting essentially of a multiplicity of recurring long-chain ester units and short-chain ester units joined head to tail through ester linkages, said long-chain ester units comprising from 40-70% by weight of the copolyester and being represented by the formula:

##STR7## and said shot-chain ester units being represented by the formula;

##STR8## where L in said long-chain unit is a divalent radical remaining after removal of terminal hydroxyl groups from a poly(oxyalkylene) glycol having at lest one thermally stable hydantoin ring per molecule, each of said rings attached to said chain through amide or imide linkages and giving said radical, L, a carbon to nitrogen ratio between about 3/1 and about 350/1, and a number average molecular weight of between 200 and 8,000;

R is a divalent radical remaining after removal of carboxyl groups from a dicarboxylic acid having a molecular weight of less than 300; and

E in short-chain unit is a divalent radical remaining after removal of hydroxyl groups from a low molecular weight diol having 2 to 15 carbon atoms per molecule and a molecular weight less than about 250.

3. The melt extruded copolyester filament of claim 2, wherein substantially all of the dicarboxylic acid is terephthalic acid and wherein substantially all of the diol having a molecular weight less than about 250 is 1,4-butane diol.

4. The melt extruded copolyester filament of claim 2, wherein --OLO-- in said long chain ester unit is a poly(oxyalkylene) glycol unit formed by the oxyalkyation of:

##STR9## where R'"'"' and R" are methyl.

5. The melt extruded filament of claims 1, 2, 3, or 4 in the form of a composite yarn wherein the melt extruded filament is intimately associated with inelastic fibers or filaments.

6. The melt extruded filament of claims 1, 2, 3, or 4 which has been contracted at least 15% in length as compared to the length of the melt extruded filament without deliberate drawing by exposure to an elevated temperature above about 80°

C to provide an elastic filament.

7. The contracted filament of claim 6 in the form of a composite yarn wherein the melt extruded filament is intimately associated with inelastic fibers or filaments.

8. The melt extruded filament of claim 6 which has been contracted at least 25% in length.

9. The melt extruded filament of claim 6 which has been contracted at least 40% in length.

10. The melt extruded filament of claim 1 which contracts at least about 40% in length when subjected to an elevated temperature as compared to the length of the melt extruded filament prior to contraction.

11. The melt extruded filament of claim 1 incorporating a stabilizer selected from the group consisting of heat stabilizers and ultraviolet radiation stabilizers.

12. A method of forming a latent-contractable elastic filament which comprises melt extruding a polymer as defined in claims 1, 2, 3, or 4 and then without prior deliberate drawing exposing said melt extruded polymer to an elevated temperature above about 80°

C. to linearly contract said melt extruded polymer at least 15% to provide an elastic filament.

13. A process which comprises core spinning relatively inelastic fibers about the melt extruded filaments as in claims 1, 2, 3 or 4.

14. A process as in claim 13, where the melt extruded filament is not appreciably stretched during the core-spinning process.