Bitumen recovery from tar sands

• US 4,470,899 A
• Filed: 02/14/1983
• Issued: 09/11/1984
• Est. Priority Date: 02/14/1983
• Status: Expired due to Term

• Current Assignee: University of Utah (State of Utah)
• Original Assignee: University of Utah (State of Utah)
• Inventors: Miller, Jan D., Hupka, Jan
• Primary Examiner(s): Gantz, Delbert E.
• Assistant Examiner(s): Pal, A.
• Application Number:
  US06/466,282
• Time in Patent Office: 575 Days
• Field of Search: 208/11 LE, 208/8 LE
• US Class Current: 208/390
• CPC Class Codes: C10G 1/047 Hot water or cold water extraction processes

Abstract

A process for recovering bitumen from tar sands wherein the tar sands are pretreated with a diluent, such as kerosene in the preferred embodiment, to lower the viscosity of the bitumen such that it is in the range of about 5 to about 20 poise at the digestion temperature. The tar sands are then digested at a temperature in the range of about 45° C. to about 60° C. and at a pH of about 7.8 to about 8.6. The tar sands are then transferred to a flotation cell where the bitumen-rich concentrate is separated from the sand.

Claims

1. A process for recovering bitumen from tar sands, the process comprising the step of:

obtaining bitumen-containing tar sands;

pretreating the tar sands with a diluent so as to lower the viscosity of the bitumen such that the viscosity is in the range of from about 5 to about 20 poise at a digestion temperature of from about 40°

C. to about 70°

C.;

digesting the tar sand in a slightly basic solution at a temperature in the range of from about 40°

C. to about 70°

C. to disengage the bitumen from said particles in the tar sand;

mixing the tar sand during the digestion step so as to create a shear stress force field in the range of from about 20 to about 100 dynes per square centimeter; and

separating the tar sand into a bitumen-rich concentrate and tailings by flotation.

2. A process for recovering bitumen from tar sands as defined in claim 1 wherein the pretreating step comprises adding a diluent which is insoluble in water but is a solvent for bitumen.

3. A process for recovering bitumen from tar sands as defined in claim 2 wherein the diluent is kerosene.

4. A process for recovering bitumen from tar sands as defined in claim 2 wherein the pretreating step comprises gently mixing the tar sands for at least about one-third of the penetration time.

5. A process for recovering bitumen from tar sands as defined in claim 1 wherein the pretreatment step comprises adding diluent until the viscosity is in the range of between about 10 poise and about 15 poise at 50°

C.

6. A process for recovering bitumen from tar sands as defined in claim 1 wherein the digesting step further comprises adding a surfactant for enhancing the wetting tendency of the sand particles.

7. A process for recovering bitumen from tar sands as defined in claim 1 wherein the digesting step is performed at a temperature in the range of about 45°

C. to about 60°

C.

8. A process for recovering bitumen from tar sands as defined in claim 7 wherein the digesting step is performed at a temperature of about 50°

C.

9. A process for recovering bitumen from tar sands as defined in claim 1 wherein the digesting step further comprises maintaining the solution at a pH in the range of about 7.5 to about 9.0.

10. A process for recovering bitumen from tar sands as defined in claim 9 wherein the digesting step further comprises maintaining the solution at a pH of between about 7.8 and about 8.6.

11. A process for recovering bitumen from tar sands as defined in claim 1 wherein the separating step further comprises washing the concentrate.

12. A process for recovering bitumen from tar sands as defined in claim 1 wherein the obtaining step further comprises comminuting the tar sand to obtain particles of tar sand of about one inch in diameter for high grade, low viscosity tar sands and about six mesh for low grade, high viscosity tar sands.

13. A process as defined in claim 1 wherein the digesting step further comprises digesting the tar sand at a solids concentration of about 75% in the slightly basic solution.

14. A process for recovering bitumen from tar sands, the process comprising the steps of:

obtaining a bitumen-containing tar sand;

pretreating the tar sand with a diluent which is insoluble in water and which is readily dissolved by bitumen so as to lower the viscosity of the bitumen such that the viscosity is in the range of from about 5 to about 20 poise at 50°

C.;

digesting the tar sand in a slightly basic solution at a temperature in the range of from about 45°

C. to about 60°

C. to disengage the bitumen from sand particles in the tar sand;

mixing the tar sand during the digestion step so as to create a shear stress force field in the range of from about 20 to about 100 dynes per square centimeter; and

separating the tar sand into a bitumen-rich concentrate and tailings by flotation.

15. A process for recovering bitumen from tar sands as defined in claim 14 wherein the pretreating step comprises adding kerosene to the tar sands.

16. A process for recovering bitumen from tar sands as defined in claim 15 wherein the pretreating step further comprises gently mixing the tar sands and diluent for at least about one-third of the penetration time.

17. A process for recovering bitumen from tar sands as defined in claim 16 wherein the digesting step further comprises maintaining the solution at a pH of between about 7.8 and about 8.6.

18. A process as defined in claim 14 wherein the digesting step further comprises digesting the tar sand at a solids concentration of about 75% in the slightly basic solution.

19. A process for recovering bitumen from tar sands, the process comprising the steps of:

obtaining a bitumen-containing tar sand;

pretreating the tar sands with a solvent which is insoluble in water but is readily dissolved by bitumen so as to lower the viscosity of the bitumen such that the viscosity is in the range of from about 5.5 to about 20 poise at 50°

C.;

digesting the tar sand at a solids concentration of about 75% in a solution having a pH in the range of from about 7.8 to about 8.6 and a temperature in the range of from about 45°

C. to about 60°

C.;

mixing the tar sand during the digestion step so as to create a shear stress force field in the range of from about 20 to about 100 dynes per square centimeter; and

separating the tar sand into a bitumen-rich concentrate and tailings in a flotation cell at a temperature in the range of from about 35°

C. to about 45°

C. and at a pH in the range of from about 6.8 to about 7.8.