In situ method for yielding a gas from a subsurface formation of hydrocarbon material

• US 4,473,114 A
• Filed: 09/29/1982
• Issued: 09/25/1984
• Est. Priority Date: 03/10/1981
• Status: Expired due to Term

• Current Assignee: Electro-Petroleum, Inc.
• Original Assignee: Electro-Petroleum, Inc.
• Inventors: Bell, Christy W., Titus, Charles H., Wittle, John K.
• Primary Examiner(s): Suchfield, George A.
• Application Number:
  US06/427,714
• Time in Patent Office: 727 Days
• Field of Search: 166/248, 166/244 C, 166/271, 166/265, 166/302, 166/308, 166/279, 48/DIG. 6, 423/224
• US Class Current: 166/248
• CPC Class Codes: E21B 36/00 Heating, cooling or insulating arrangements for boreholes or wells, e.g. for use in permafrost zones
• CPC Class Codes: E21B 36/001 Cooling arrangements
• CPC Class Codes: E21B 43/2401 by means of electricity
• CPC Class Codes: E21B 43/295 Gasification of minerals, e.g. for producing mixtures of combustible gases E21B43/243 takes precedence
• CPC Class Codes: Y10S 166/902 for inhibiting corrosion or coating

Abstract

Gas is yielded and may be subsequently withdrawn from a subsurface formation of hydrocarbon material by passing a controlled amount of current from a direct source through the formation. The gas produced by this process has a high quality Btu content and is produced, in situ, under relatively moderate operating conditions. Furthermore, the gas yielded by this method has a reduced amount of hydrogen sulfide present therein.

Claims

1. A process for the in situ reduction of the hydrogen sulfide concentration of a gas derived from a subsurface formation, which method comprises providing an aqueous electrolyte in contact with said formation, providing at least two electrically conductive elements, constituting an anode and a cathode, in contact with said electrolyte, passing a controlled amount of electrical current from a direct current source through said formation between said electrically conductive elements at a voltage of at least 0.3 volts and controlling the current relative to the composition of said material and the ambient conditions adjacent to said electrode to heat the surface of the electrodes during application of said voltage to a temperature which is less than 500°

F. thereby to yield a gas which has a hydrogen sulfide content substantially less than the gas naturally occurring in the formation.

2. The process of claim 1 wherein the subsurface formation is a formation of carbonaceous material.

3. The process of claim 1 wherein the subsurface formation is a gas bearing formation.

4. The process of claim 1 wherein the hydrogen sulfide containing-gas produced is a combustible gas consisting essentially of hydrogen, hydrocarbons having from 1 to 8 carbon atoms, and carbon monoxide.

5. The process of claim 1 wherein one of said electrically conductive elements is provided adjacent the earth'"'"'s surface.

6. The process of claim 5 wherein the electrically conductive element provided adjacent the earth'"'"'s surface serves as the anode.

7. The process of claim 1 wherein at least one of said electrically conductive elements is provided by drilling a well which penetrates said formation and inserting in the well bore an elongated liner having an upper portion and electrically conductive lower portion, said upper portion being electrically insulated from said lower portion, which latter portion is connected to said direct current source.

8. The process of claim 7 wherein said lower portion of said liner serves as the cathode.

9. The process of claim 7 wherein the formation has a given thickness and said lower portion of said liner is disposed within the boundary of said formation and is shorter than the thickness of said formation.

10. The process of claim 7 which includes cooling the formation around the electrically conductive lower portion of said liner by introducing a liquid coolant into the well-bore.

11. The process of claim 10 wherein the electrically conductive lower portion of said liner is perforated and said liquid coolant is injected into said formation through said lower portion.

12. The process of claims 10 or 11 wherein said liquid coolant is water.