Dentifrice packaging process

• US 4,473,988 A
• Filed: 08/06/1982
• Issued: 10/02/1984
• Est. Priority Date: 10/24/1979
• Status: Expired due to Fees

• Current Assignee: Colgate-Palmolive Company
• Original Assignee: Colgate-Palmolive Company
• Inventors: Scott, George V.
• Primary Examiner(s): Rose, Shep K.
• Application Number:
  US06/406,610
• Time in Patent Office: 788 Days
• Field of Search: 424/49-58, 53/440, 219/10.55 M
• US Class Current: 53/440
• CPC Class Codes: A61K 2800/52 Stabilizers
• CPC Class Codes: A61K 2800/81 Preparation or application process involves irradiation
• CPC Class Codes: A61K 8/042 Gels
• CPC Class Codes: A61K 8/73 Polysaccharides
• CPC Class Codes: A61Q 11/00 Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
• CPC Class Codes: H05B 6/68 for monitoring or control
• CPC Class Codes: H05B 6/78 Arrangements for continuous movement of material

Abstract

A method for stabilizing a cosmetic composition containing carrageenan, specifically, a toothpaste, wherein microwave radiation, preferably in the 0.8 to 3 gigahertz frequency range, is directed onto the toothpaste so as to raise its temperature to at least the gel-sol transition temperature of the carrageenan, after which the toothpaste is quiescently cooled to room temperature. The use of microwave radiation facilitates an even heating of the toothpaste, so that temperature sensitive components thereof are not adversely affected, and promotes excellent control of temperature regulation. Heating of the dentifrice, with improved thickening and stabilization thereof, is obtainable by passing it through a conduit while directing microwave radiation onto it and then filling it into suitable dispensing containers, or by filling the dentifrice into such containers and then subjecting them to microwave radiation.

Claims

1. A process for packaging a dentifrice containing carrageenan, in which such carrageenan is stabilized, which comprises directing microwave radiation onto such a dentifrice while it is being moved into a filling apparatus or into a vessel from which it is to be delivered to such filling apparatus, with the microwave radiation applied being in such quantity as to raise the temperature of the dentifrice to at least the gel-sol transition temperature of the carrageenan, filling the dentifrice into an end use package, and quiescently cooling the dentifrice to room temperature in the package.

2. A process according to claim 1 wherein the dentifrice is a toothpaste in which carrageenan is present as a gelling agent in a proportion from about 0.1 to 5% by weight, the microwave radiation is at a frequency of 0.3 to 50 gigahertz and such radiation is directed onto the dentifrice while the dentifrice is being moved through a walled passageway into a filling apparatus or is being moved into a vessel from which it is to be delivered to such a filling apparatus.

3. A process according to claim 2 wherein the passageway defining walls through which the microwave radiation is directed onto the dentifrice are of a material through which microwave radiation passes readily.

4. A process according to claim 2 wherein the dentifrice is being moved through a walled passageway into a filling apparatus when the microwave radiation is applied.

5. A process according to claim 2 wherein the dentifrice is being delivered to a filling apparatus when the microwave radiation is applied.

6. A process according to claim 3 wherein the material of the passageway walls through which the microwave radiation is directed onto the dentifrice is transparent to microwave radiation.

7. A process according to claim 3 wherein the dentifrice is heated in a closed system, thereby preventing aeration and loss of volatile components of the dentifrice.

8. A process according to claim 7 wherein the dentifrice is exposed a plurality of times to microwave radiation as the dentifrice is passed through a continuous length of piping, so as intermittently to heat the dentifrice.

9. A process according to claim 1 wherein the dentifrice comprises a kappa carrageenan gelling agent and a lossy dielectric material, and tends to decrease in viscosity when subjected to mechanical working at room temperature, the microwave radiation is directed onto such composition in a closed system over a period of no more than two minutes while the dentifrice is being passed through a line, the microwave radiation is of a frequency in the range of 0.8 to 3 gigahertz, and is in such quantity as to heat the dentifrice, due to the effect of the microwave radiation on the lossy dielectric component of the dentifrice, and raise the temperature thereof to at least the gel-sol transition temperature of the carrageenan, and the heated dentifrice is quiescently cooled to room temperature.

10. A process according to claim 9 wherein the carrageenan gelling agent is present in the dentifrice in a proportion from about 0.1 to 5% by weight and the dentifrice viscosity is increased by the process.

11. A process according to claim 10 wherein the carrageenan gelling agent is at least 20% of the gelling agent in the dentifrice and the total of gelling agent in the dentifrice is no more than 5% of the weight of the dentifrice.

12. A process according to claim 10 wherein the dentifrice contains a temperature sensitive flavoring agent which is of improved stability when subjected to closed system microwave heating, compared to other types of heating.

13. A process according to claim 1 wherein the dentifrice comprises from about 10 to 70% of particulate polishing agent, 0.2 to 3% of carrageenan, 0.2 to 20% of foaming agent, 2 to 50% of polyhydric alcohol and 5 to 50%of water, the polishing agent, carrageenan, foaming agent, polyhydric alchol and water are mixed together before microwave heating of the dentifrice and such microwave heating is to a temperature of at least 46°

C.

14. A process according to claim 10 wherein the microwave heating of the dentifrice is effected intermittently to promote even heating of the dentifrice.

15. A process according to claim 11 wherein the dentifrice comprises about 10 to 70% of particulate polishing agent, 0.2 to 3% of kappa carrageenan, 0.2 to 20% of foaming agent, 20 to 50% of polyhydric alchol and 5 to 50% of water, the polishing agent, kappa carrageenan, foaming agent, polyhydric alcohol and water are mixed together before microwave heating of the dentifrice, and the microwave heating is to a temperature of at least 46°

C.

16. A process according to claim 3 wherein the passageway defining walls are of synthetic organic polymeric plastic or glass piping or tubing.

17. A process according to claim 16 wherein the dentifrice is being mixed in the piping or tubing through which it is passed while microwave radiation is directed thereon.

18. A process according to claim 16 wherein the dentifrice being heated and filled comprises from 10 to 70% of particulate polishing agent, 0.2 to 3% of carrageenan, 0.2 to 20% of foaming agent, 2 to 50% of polyhydric alcohol and 5 to 50% of water, the heating is to a temperature of at least 46°

C., and the heating time is less than two minutes.

19. A process according to claim 16 wherein the temperature of the dentifrice, increased by directing microwave radiation onto it, is monitored and controlled by detecting the temperature of the dentifrice and regulating the directing of microwave radiation onto it in response to the detected temperature.

20. A process for stabilizing a dentifrice containing carrageenan which comprises directing microwave radition onto such a dentifrice while it is in motion, with the microwave radiation applied being in such quantity as to raise the temperature of the dentifrice to at least the gel-sol transition temperature of the carrageenan, and quiescently cooling the dentifrice to room temperature.