Adsorbent compositions

• US 4,474,896 A
• Filed: 03/31/1983
• Issued: 10/02/1984
• Est. Priority Date: 03/31/1983
• Status: Expired due to Fees

• Current Assignee: Union Carbide Corporation (Dow, Inc.)
• Original Assignee: Union Carbide Corporation (Dow, Inc.)
• Inventors: Chao, Chien C.
• Primary Examiner(s): Gantz, Delbert E.
• Assistant Examiner(s): Wright, William G.
• Application Number:
  US06/480,699
• Time in Patent Office: 551 Days
• Field of Search: 252/439
• US Class Current: 502/216
• CPC Class Codes: B01J 20/00 Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
• CPC Class Codes: B01J 20/186 Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
• CPC Class Codes: B01J 20/3204 Inorganic carriers, supports or substrates
• CPC Class Codes: B01J 20/3236 containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
• CPC Class Codes: B01J 20/3248 the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
• CPC Class Codes: B01J 20/3251 comprising at least two different types of heteroatoms selected from nitrogen, oxygen or sulphur
• CPC Class Codes: C01G 13/003 Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
• CPC Class Codes: C22B 3/24 by adsorption on solid substances, e.g. by extraction with solid resins
• CPC Class Codes: C22B 3/42 by ion-exchange extraction
• CPC Class Codes: Y02P 10/20 Recycling

Abstract

Adsorbent compositions and their preparation are disclosed for the adsorption of elemental mercury.

Claims

1. Adsorbent compositions for use in the adsorption of elemental mercury consisting essentially of a support material selected from the class consisting of aluminosilicates, ion-exchange resins, alumina, silica and carbon;

a cation selected from the group consisting of antimony, arsenic, bismuth, cadmium, cobalt, copper, gold, indium, iron, lead, manganese, molybdenum, mercury, nickel, platinum, silver, tin, tungsten, titanium, vanadium, zinc, zirconium and mixtures thereof wherein the cation is present in an amount which is at least 20 percent of the total of the amount required to occupy the cation sites; and

a polysulfide.

2. The adsorbent composition of claim 1 for use in the adsorption of elemental mercury from a gas or liquid stream comprising a crystalline aluminosilicate selected from the class consisting of Zeolite X and Zeolite Y, at least one cation selected from the group consisting of copper, cobalt, manganese, nickel and mixtures thereof and a polysulfide.

3. The process for the preparation of adsorbent compositions for elemental mercury comprising:

(a) providing a support material selected from the class consisting of aluminosilicates, alumina, ion-exchange resins, carbons and silicas with at least one cation capable of forming an insoluble polysulfide and selected from the group consisting of antimony arsenic, bismuth, cadmium, cobalt, copper, gold, indium, iron, lead, manganese, molybdenum, mercury, nickel, platinum, silver, tin, tungsten, titanium, vanadium, zinc, zirconium and mixtures thereof; and

(b) contacting the cation-containing support material of step (a) with a sulfide-forming species and a polysulfide-forming species.

4. The process of claim 3 wherein the sulfide-forming species and polysulfide-forming species are selected from the class of sulfides and polysulfides, respectively, consisting of alkali metals, alkaline earth metals, ammonium, quaternary ammonium cations and mixtures thereof.

5. The process of claim 3 wherein the mole ratio of sulfide to polysulfide is between about 50 to 1 and about 1 to 50.

6. The process of claim 3 wherein the mole ratio of sulfide to polysulfide is between 10 to 1 and about 1 to 10.

7. The process of claim 3 wherein the process is carried out in the vapor state.

8. The process of claim 3 wherein the process is carried out in the liquid state.

9. The process of claim 3 wherein the polysulfide-forming species is a sulfane.

10. The process of claim 3 wherein the polysulfide-forming species is a tetrasulfide of ammonium or an alkali metal.

11. The process of claim 10 wherein the sulfide-forming species is a sulfide of an alkali metal.

12. The process of claim 3 wherein the support material is a crystalline aluminosilicate.

13. The process of claim 3 wherein the support material is an ion-exchange resin.

14. The process of claim 3 for the preparation adsorbent compositions comprising contacting a zeolite selected from the class consisting of zeolites X and Y wherein such zeolite cotains a cation selected from the class consisting of copper, cobalt, manganese, nickel and mixtures thereof with a mixture of a sulfide and a polysulfide wherein the mole ratio of sulfide to polysulfide is betwen about 5 to 1 and about 1 to 5.

15. The process of claim 14 wherein the polysulfide is an alkali metal tetrasulfide.

16. The process of claim 14 wherein at least 20 percent of the cations of zeolite Y and/or zeolite X are selected from the class consisting of copper, nickel, cobalt, manganese and mixtures thereof.

17. The process of claim 12 wherein the aluminosilicate is selected from the class consisting of Zeolite X, Zeolite Y, Zeolite A and ZSM-type zeolites.

18. The process of claim 17 wherein the aluminosilicate is Zeolite X.

19. The process of claim 17 wherein the aluminosilicate is Zeolite Y.

20. The composition prepared by the process of claim 14.

21. The adsorbent composition prepared by the process of claim 12.