Method for activating metal particles

• US 4,477,296 A
• Filed: 09/30/1982
• Issued: 10/16/1984
• Est. Priority Date: 09/30/1982
• Status: Expired due to Term

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Nair, Kumaran M.
• Primary Examiner(s): Lusignan, Michael R.
• Application Number:
  US06/430,871
• Time in Patent Office: 747 Days
• Field of Search: 148/6.15 R, 148/6.14 R, 148/6.27, 427/79, 427/80, 427/216, 75/0.5 A, 252/512-514
• US Class Current: 148/243
• CPC Class Codes: B22F 1/145 Chemical treatment, e.g. passivation or decarburisation
• CPC Class Codes: H01G 4/0085 Fried electrodes
• CPC Class Codes: H05K 1/092 Dispersed materials, e.g. conductive pastes or inks

Abstract

A method for activating the surface of finely divided particles of conductive metals having a thin surface coating of an oxide of the conductive metal comprising the steps of (a) treating the surface with an aqueous solution of a reducing agent when the conductive metal is a noble metal and either a reducing agent for the oxide or an inorganic acid when the conductive metal is a base metal, (b) washing the surface of the treated particles with an aqueous liquid, and (c) drying the surface of the washed particles.

Claims

1. A method for activating the surface of finely divided particles of conductive metals having a thin surface coating of oxide of the conductive metal comprising the steps of (a) treating the surface with an aqueous solution of a reducing agent for the oxide when the conductive metal is a noble metal and either a reducing agent for the oxide or an inorganic acid capable of reacting with the oxide to form a water-soluble salt of the metal ion when the conductive metal is a base metal, the reactive component of the aqueous solution being in molar excess of the oxide, (b) washing the surface of the treated particles with an aqueous liquid having a pH of 5.5-7.0 until essentially no change in pH takes place in the wash liquid, and (c) drying the surface of the washed particles.

2. The method of claim 1 in which the conductive metal is a noble metal selected from the group consisting of palladium, gold, silver and mixtures and alloys thereof, and the reactive component of the aqueous treating solution is a reducing agent for the oxide.

3. The method of claim 2 in which the conductive metal is a mixture of palladium and silver and the reducing agent is H₃ PO₂.

4. The method of claim 1 in which the conductive metal is a base metal selected from the group consisting of aluminum, copper, nickel, and mixtures and alloys thereof and the rective component of the aqueous treating solution is reactive with the oxide to form a water-soluble salt of the metal ion.

5. The method of claim 4 in which the inorganic acid is selected from the group consisting of HNO₃, H₂ SO₄, and phosphorus acids.

6. The method of claim 1 in which the conductive metal is a base metal selected from the group consisting of copper, nickel, aluminum and mixtures and alloys thereof, and the reactive component of the aqueous treating solution is a reducing agent for the conductive metal oxide.

7. The method of claim 6 in which the reducing agent is H₃ PO₂.

8. The method of claim 1 in which the concentration of the reactive compound in the aqueous treating solution does not exceed 10% by weight of the solution.