Polyphotoinitiators and compositions thereof

• US 4,477,326 A
• Filed: 06/20/1983
• Issued: 10/16/1984
• Est. Priority Date: 06/20/1983
• Status: Expired due to Term

• Current Assignee: Samuel Q.S. Lin
• Original Assignee: Loctite Corporation (Henkel AG & Co KGaA)
• Inventors: Lin, Samuel Q. S.
• Primary Examiner(s): MARQUIS, MELVYN I
• Application Number:
  US06/505,588
• Time in Patent Office: 484 Days
• Field of Search: 204/159.13, 204/159.22, 204/159.24, 528/15, 528/24, 528/25, 528/26, 528/29, 528/33, 528/37
• US Class Current: 522/21
• CPC Class Codes: C08F 2/50 with sensitising agents
• CPC Class Codes: C08F 299/08 from polysiloxanes
• CPC Class Codes: C08G 77/14 containing silicon bound to oxygen-containing groups C08G77/045 takes precedence
• CPC Class Codes: C08G 77/38 Polysiloxanes modified by chemical after-treatment C08G77/045 takes precedence
• CPC Class Codes: Y10S 522/904 Monomer or polymer contains initiating group

Abstract

Polysiloxane polymers with photoinitiating functionality. The polymers may be obtained by reacting α-allylbenzoin ethers with a siloxane or polysiloxane containing a plurality of silicon hydride groups. Alternatively, the allylbenzoin ethers may be reacted with a hydrolyzable hydrosilane and further reacted with other hydrolyzable organosilanes or siloxanes to form the polysiloxane with pendant photoinitiating benzoin ether groups. The other hydrolyzable silanes or siloxanes may include photocurable groups to yield self curing polymers. In the same manner, photoinitiating siloxane polymers of the first method may be further polymerized to yield self curing products. The photoinitiating polymers may also be combined with ethylenically unsaturated monomers or other silicones with photocurable groups to yield photocurable compositions.

Claims

1. A UV curable composition comprising a mixture of an organosiloxane polymer and at least one ethylenically unsaturated free radical polymerizable organic monomer, the organosiloxane polymer including a plurality of photoinitiating units along the chain thereof the units having the formula:

##STR10## wherein R¹ is alkyl, aryl, alkoxy, substituted alkyl or substituted aryl;

R² is alkyl, aryl, substituted alkyl or substituted aryl; and

R³ and R⁴ are phenyl or substituted phenyl.

2. A composition as in claim 1 wherein the ethylenically unsaturated monomer is selected from the group consisting of acrylate, methacrylate, maleate and itaconate esters;

vinyl ketones;

styrenes;

acrylamide, methacrylamide and their N-substituted derivatives, and mixtures thereof.

3. A composition as in claim 1 wherein said organosiloxane polymer is present in the range of between about 1% and 70% by weight of the composition.

4. A composition as in claim 1 wherein said organosiloxane polymer is present in the range of between about 5% and 40% by weight of the composition.

5. A composition as in claim 1 further comprising an inhibitor selected from the group consisting of hydroquinone, benzoquinone and hindered phenols.

6. A composition as in claim 1 wherein the ethylenically unsaturated monomer is selected from cyclohexylmethacrylate, tetrahydrofurfural methacrylate, hexanediol dimethacrylate, isobornylacrylate, and mixtures thereof.

7. A cured product of the composition of claim 1.