Reactive metal battery having continuous supply of cathode reactant

• US 4,481,266 A
• Filed: 03/25/1983
• Issued: 11/06/1984
• Est. Priority Date: 03/25/1983
• Status: Expired due to Fees

• Current Assignee: Lockheed Missiles and Space Co Inc (Martin Marietta Corporation)
• Original Assignee: Lockheed Missiles and Space Co Inc (Martin Marietta Corporation)
• Inventors: Littauer, Ernest L., Momyer, William R.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US06/478,695
• Time in Patent Office: 592 Days
• Field of Search: 429/12, 429/14, 429/13, 429/27, 429/34, 429/40, 429/51, 429/72, 429/80, 429/108, 429/110, 429/118, 429/218
• US Class Current: 429/513
• CPC Class Codes: H01M 12/04 composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type

Abstract

An improved porous cathode structure for use in a battery having a reactive metal electrode and flowed electrolyte. The cathode is preferably formed of an electrically conducting porous material with categorically active surface at an interface with the electrolyte. Alternatively, the cathode may be of an electrochemically reducible porous material and defines an active surface.

Structure is provided for delivering electrochemically reducible cathode reactant material continuously through the cathode to the cathode active surface during operation of the battery. The reactant material is delivered in an amount required to be reduced at the active surface to maintain high energy discharge rate with minimum amount of reactant material being utilized. The reactant material, in the illustrated embodiment, is provided from a storage supply and delivered to the porous cathode as needed during operation of the battery. In one form, the cathode is provided with distribution passages for conducting the reactant material therethrough. In another form, the reactant material is introduced through one or more edge portions of the cathode porous body for flow through the pores to the active surface.

Claims

1. A battery comprising a reactive metal electrode, flowed electrolyte, porous cathode structure defining a catalytically active surface at an interface with said electrolyte, and means for providing electrochemically reducible soluble cathode reactant material through the cathode to said active surface during operation of the battery in an amount sufficient to be reduced at said surface to maintain a high energy discharge rate.

2. The battery of claim 1 wherein said cathode comprises a solid electrochemically reducible porous material.

3. The battery of claim 1 wherein said reactant material providing means comprises means defining flow passages distributed through said cathode to deliver the reactant material through the porous cathode material substantially uniformly to the active surface thereof.

4. The battery of claim 1 wherein said reactant material providing means comprises means defining flow passages distributed through said cathode to deliver the reactant material through the porous cathode material substantially uniformly to the active surface thereof, means for storing a supply of the reactant material, and means for delivering the reactant material from the storing means to the cathode as needed.

5. The battery of claim 1 wherein said reactant material providing means comprises means for storing a supply of the reactant material, and means for delivering the reactant material from the storing means to an edge portion of the cathode to be flowed through the porous cathode as needed.

6. The battery of claim 1 wherein said reactant material providing means comprises means for storing a supply of the reactant material, and means for delivering the reactant material from the storing means to a lower edge portion of the cathode to be flowed through the porous cathode as needed.

7. The battery of claim 1 wherein said reactant material is selected from the group consisting of hydrogen peroxide, lithium peroxide, nitrites, bromates, chlorates, sulfites, dinitrogentrioxide, and hypochlorites.

8. The battery of claim 7 wherein said reactant material comprises soluble peroxide ions.

9. The battery of claim 1 wherein said reactant material comprises a halogen.

10. A battery comprising a reactive metal electrode, flowed electrolyte, a solid electrochemically reducible porous cathode defining an active surface with an inert metal substrate juxtaposed thereto, and means for providing electrochemically reducible soluble cathode reactant material through the cathode to the cathode active surface adjacent to said inert metal substrate during operation of the battery in an amount sufficient to be reduced at said surface to maintain a high energy discharge rate, the reduced reactant material being removed therefrom as it is formed, by the flowed electrolyte.

11. The battery of claim 10 wherein said cathode comprises a thin wall member having reactant metal distribution passages formed therein.

12. The battery of claim 10 wherein said cathode comprises silver oxide active material and said reactant is provided in sufficient quantity to provide a capacity of greater than approximately 23 ampere-minutes per gram of reactant.

13. The battery of claim 10 wherein said reactant material is selected from the group consisting of hydrogen peroxide, lithium peroxide, nitrites, bromates, chlorates, sulfites, dinitrogentrioxide, and hypochlorites.

14. The battery of claim 13 wherein said reactant material comprises a peroxide.

15. The battery of claim 10 wherein said reactant material comprises a halogen.