Method of conditioning a water swellable hydrocolloid

• US 4,482,386 A
• Filed: 04/29/1983
• Issued: 11/13/1984
• Est. Priority Date: 03/26/1982
• Status: Expired due to Term

• Current Assignee: Warner-Lambert Company (Pfizer Inc.)
• Original Assignee: Warner-Lambert Company (Pfizer Inc.)
• Inventors: Tomka, Ivan, Wittwer, Fritz
• Primary Examiner(s): Morris, Theodore
• Application Number:
  US06/490,058
• Time in Patent Office: 564 Days
• Field of Search: 260/117, 260/118, 106/125, 106/135, 106/210, 106/146, 106/208, 106/198, 106/213, 523/326, 523/330, 127/32, 528/481, 528/483
• US Class Current: 106/160.1
• CPC Class Codes: C08J 2300/10 Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups
• CPC Class Codes: C08J 3/00 Processes of treating or compounding macromolecular substances

Abstract

Method to condition water-swellable hydrocolloids for use in mechanical forming processes such as die molding or injection molding. To avoid long conditioning times at high temperature, the hydrocolloids are conditioned to the predetermined water content at ambient temperature and then rapidly heated, just before processing, in a gaseous stream loaded with water to the equilibrium conditions needed to maintain the predetermined water content of the hydrocolloids at the high process temperature of the mechanical forming.

Claims

1. A method by which a water-swellable hydrocolloid, for use in mechanical forming processes is conditioned to a given water content and is rapidly heated from a lower temperature to a higher temperature without virtually changing its water content, characterized by

(a) slowly conditioning the hydrocolloid at the lower temperature to obtain an even distribution of water within every particle and through the bulk of the hydrocolloid,

(b) transferring the hydrocolloid into a gaseous atmosphere of the desired higher temperature, said gaseous atmosphere is loaded with water to the proportion in equilibrium at the higher temperature with the predetermined water content of the hydrocolloid, and

(c) removing the hydrocolloid from the said gaseous atmosphere within a short time sufficient to heat the hydrocolloid to the desired higher temperature but not sufficient to affect any substantial exchange of humidity.

2. The method of claim 1 wherein the lower temperature is normal ambient temperature and the higher temperature is near the boiling point of water.

3. The method of claims 1 or 2, wherein the hydrocolloid has a glass-transition point above the lower temperature and below the higher temperature as defined in claim 1 and is able to be plastically deformed at the higher temperature.

4. The method of claims 1 or 2, wherein the hydrocolloid is a plastifiable protein.

5. The method as in any claims 1, 2, 4 or 6 wherein the plastifiable

6. The method of claim 5, wherein the gelatin is in granulated form with a mean particle size between 0,2 and 4 mm.

7. The method of claims 1 to 6, wherein the gaseous atmosphere loaded with water is a gas stream preferably an air stream, of constant velocity, into which the hydrocolloid is fed at a constant rate at a first point, carried away with the gas stream, and removed from the gas stream at a second point after a predetermined elapsed time.

8. The method of claim 7 wherein the gas stream is an air stream.

9. The water-swellable hydrocolloid produced by the method of claim 1 for the feeding of die molding or injection molding machines.

10. The method of claims 1 or 2 wherein the hydrocolloid is a natural hydrophilic polymer selected from a group consisting of casein, soya bean protein, or safflower protein.

11. The method of claims 1 or 2 wherein the hydrocolloid is a modified natural hydrophilic polymer selected from a group consisting of phthalated gelatin and succinated gelatin.

12. The method of claims 1 or 2 wherein the hudrocolloid is a synthetic hydrophilic polymer selected from a group consisting of cellulosephthalate-acetate, polyvinylacetate, polyvinylacetate-phthalate, and polymerisates of acrylic or methacrylic esters modified by hydrophilic groups to render them water-swellable.