Process for producing a high strength porous polytetrafluoroethylene product having a coarse microstructure

• US 4,482,516 A
• Filed: 09/10/1982
• Issued: 11/13/1984
• Est. Priority Date: 09/10/1982
• Status: Expired due to Term

• Current Assignee: W. L. Gore & Associates (W.L. Gore & Associates)
• Original Assignee: W. L. Gore & Associates (W.L. Gore & Associates)
• Inventors: Lewis, James D., Staley, Richard A., Hubis, Daniel E., Bowman, Jeffery B., Newman, Stephen C.
• Primary Examiner(s): Lowe, James
• Application Number:
  US06/416,466
• Time in Patent Office: 795 Days
• Field of Search: 264/127, 264/175, 264/288.8, 264/289.3, 264/280
• US Class Current: 264/127
• CPC Class Codes: B29C 55/005 characterised by the choice of materials
• CPC Class Codes: B29K 2027/18 PTFE, i.e. polytetrafluorethene , e.g. ePTFE, i.e. expanded polytetrafluorethene
• CPC Class Codes: B29K 2105/04 cellular or porous
• CPC Class Codes: C08J 2327/18 Homopolymers or copolymers of tetrafluoroethylene
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets
• CPC Class Codes: D01F 6/12 from polymers of fluorinated hydrocarbons

Abstract

Porous polytetrafluoroethylene materials having high strength and coarse microstructure are produced by densifying the materials after removal of lubricant and then stretching. The term, "coarse," is used to indicate that the nodes are larger, the fibrils are longer, and the effective pore size is larger than conventional materials of the same matrix tensile strength. Densification can be achieved through the use of such devices as a densification die, a calender machine, or a press. This invention can be used to produce all kinds of shaped articles.

Claims

1. A process for producing a porous material of polytetrafluoroethylene polymer, which material is characterized by relatively large nodes interconnected by realtively long fibrils and having relatively high matrix tensile strength, the material having been produced from paste-extruded unsintered polytetrafluoroethylene extrudate, the process comprising the steps:

(a) providing an unsintered dry extrudate;

(b) increasing the density of the dry extrudate to greater than about 1.80 gm/cc at a temperature below the crystalline melt temperature of PTFE; and

(c) stretching said densified dry extrudate at an elevated temperature less than the crystalline melt temperature.

2. The process as in claim 1 wherein said densification step increaes the dry extrudate density to greater than about 2.0 gm/cc.

3. The process as in claim 1 wherein said densification step increases the dry extrudate density to greater than about 2.2 gm/cc.

4. The process as in claim 1 wherein said densification step increases the dry extrudate density to about its maximum value.

5. The process as in claim 1 wherein the densification step is accomplished by densifying the dry extrudate in a press.

6. The process as in claim 1 wherein the densification step is accomplished by calendering the dry extrudate.

7. The process as in claim 1 wherein the densification step is accomplished by drawing the dry extrudate through a densification die.

8. The process as in claim 1, 5, 6 or 7 wherein the densified dry extrudate is stretched uniaxially.

9. The process as in claim 1, 5 or 6 wherein the densified dry extrudate is stretched biaxially.

10. The process as in claim 1 wherein the stretching step is carried out at about 300°

C.

11. The process as in claim 1 wherein the densification step is carried out at an elevated temperature less than the crystalline melt temperature.

12. The process as in claim 11 wherein the densification step is carried out at about 300°

C.

13. The process as in claim 1 further including the step of heating the stretched article above the crystalline melt temperature, to sinter the stretched article, while restraining the stretched article from shrinking.

14. The process as in claim 1, 6 or 7 wherein the densification and stretching steps are carried out continuously.

15. The process as in claim 1, 2, 3 or 4 further including the step of stretching said dry extrudate before said densification step.

16. The process as in claim 1 wherein the step of providing a dry extrudate includes the substeps of:

(i) mechanically working an extrudate containing an extrusion aid lubricant to obtain a desired shape; and

(ii) drying the worked extrudate to remove the lubricant.

17. The process as in claim 16 wherein said mechanical working substep includes the step of calendering the extrudate containing lubricant.

18. The process as in claim 16 wherein said mechanical working substep includes the step of stretching the extrudate containing the lubricant.