Method for two stage in-line acid mixing

• US 4,483,357 A
• Filed: 02/22/1983
• Issued: 11/20/1984
• Est. Priority Date: 02/22/1983
• Status: Expired due to Fees

• Current Assignee: Globe-Union Inc.
• Original Assignee: Globe-Union Inc.
• Inventors: Jeglum, James K., Rao, Jagdish J.
• Primary Examiner(s): Schwadron, Martin P.
• Assistant Examiner(s): Hepperle, Stephen M.
• Application Number:
  US06/468,325
• Time in Patent Office: 637 Days
• Field of Search: 137/88, 137/91, 137/3, 137/93, 137/505.12, 137/5
• US Class Current: 137/3
• CPC Class Codes: B01F 35/2209 Controlling the mixing process as a whole, i.e. involving a complete monitoring and controlling of the mixing process during the whole mixing cycle
• CPC Class Codes: B01F 35/82 by adding a material to be mixed to a mixture in response to a detected feature, e.g. density, radioactivity, consumed power or colour
• CPC Class Codes: C01B 17/74 Preparation
• CPC Class Codes: Y10T 137/0329 Mixing of plural fluids of diverse characteristics or conditions
• CPC Class Codes: Y10T 137/2504 By specific gravity

Abstract

A method of preparing mixtures of dilute acid of varying final specific gravities utilizes microprocessor controlled mixing in two in-line stages. Process recycled or production reject acid or water is initially mixed with concentrated acid and directed to an intermediate heat exchanger for removing the exothermic heat generated during mixing. The specific gravity of the mixture exiting from the heat exchanger is continuously measured and fed to a microprocessor which calculates the deviation between the measured specific gravity and a preselected set point specific gravity which is greater than the desired final specific gravity. The calculated deviation is used to generate a control signal which, in turn, is applied to adjust the flow of concentrated acid until the measured specific gravity corresponds to the set point specific gravity. In the second stage, the set point specific gravity acid/water is mixed with water and the specific gravity of this second stage mixture is continuously measured and also fed to the microprocessor which calculates the deviation between the measured specific gravity and the final desired specific gravity. A second control signal based on the second calculated deviation is generated to adjust the flow of water to provide a second stage mixture of the desired final specific gravity. The method is particularly adaptable to providing sulfuric acid mixtures of various specific gravities typically utilized in the manufacture of lead-acid batteries.

Claims

1. The method of preparing mixtures of acid and water of varying desired final specific gravities in two continuous in-line stages comprising the steps of:

a. mixing a first flow of water or dilute acid and a flow of concentrated acid to provide a first stage mixture;

b. establishing a set point specific gravity for the first stage mixture which is greater than the specific gravity of the desired final mixture;

c. continuously measuring the actual specific gravity of the first stage mixture;

d. utilizing a programmed microprocessor to calculate the deviation between the measured specific gravity of the first stage mixture and the set point specific gravity;

e. generating a first control signal based on the calculated deviation;

f. utilizing the first control signal to adjust the flow of one component of the first stage mixture to establish parity between the measured specific gravity of the first stage mixture and the set point specific gravity;

g. selecting a specific gravity for a desired final mixture;

h. mixing a flow of the first stage mixture at the set point specific gravity and a second flow of water to provide a second stage mixture;

i. continuously measuring the actual specific gravity of the second stage mixture;

j. utilizing the microprocessor to calculate the deviation between the measured specific gravity of the second stage mixture and the specific gravity of the desired final mixture;

k. generating a second control signal based on the calculated deviation from the preceding step;

l. utilizing the second control signal to adjust the second flow of water to establish parity between the measured specific gravity of the second stage mixture and the specific gravity of the desired final mixture; and

m. directing the flow of the second stage mixture at the final specific gravity to a reservoir.

2. The method as set forth in claim 1 including the intermediate step of passing the first stage mixture through a heat exchanger to remove at least a portion of the exothermic heat of mixing.

3. The method as set forth in claim 2 wherein the specific gravity of the first stage mixture is measured subsequent to passage through the heat exchanger.

4. The method as set forth in claim 1 wherein the first control signal is utilized to adjust the flow of concentrated acid.

5. The method as set forth in claims 1, 2, 3, or 4 including the intermediate steps of:

a. diverting the flow of the second stage mixture from step h to a source of the flow of dilute acid; and

,

b. terminating the diversion of the flow of the second stage mixture prior to step m.

6. The method of preparing mixtures of acid and water of varying desired final specific gravities comprising the steps of:

a. mixing a first flow of water or dilute acid and a flow of concentrated acid to provide a first mixture;

b. passing the first mixture through a heat exchanger to remove at least a portion of the exothermic heat of mixing;

c. establishing a set point for the specific gravity of the first mixture which is greater than the specific gravity of the desired final mixture;

d. measuring the actual specific gravity of the first mixture as it exits from the heat exchanger;

e. utilizing a programmed microprocessor to calculate the deviation between the actual specific gravity of the first mixture and the set point;

f. generating a first control signal based on the calculated deviation;

g. utilizing the first control signal to adjust, if necessary, the flow of concentrated acid to establish parity between the actual specific gravity of the first mixture and the set point;

h. selecting a specific gravity for a desired final mixture;

i. mixing a flow of the first mixture at the set point specific gravity and a second flow of water to provide a second mixture;

j. measuring the actual specific gravity of the second mixture;

k. utilizing the microprocessor to calculate the deviation between the measured specific gravity of the second mixture and the desired final specific gravity;

l. generating a second control signal based on the calculated deviation from the preceding step;

m. utilizing the second control signal to adjust, if necessary, the second flow of water to establish parity between the actual specific gravity of the second mixture and the final specific gravity; and

,

n. directing a flow of the second mixture at the final specific gravity to a reservoir.

7. The method as set forth in claim 6 wherein the acid is sulfuric acid.

8. The method as set forth in claim 7 wherein the first mixture is cooled to a temperature of less than 125°

F. (52°

C.).

9. The method as set forth in claim 6 including the step of diverting, simultaneously with steps a through m, the flow of the second mixture to the source of the flow of dilute acid in step a.

10. The method as set forth in claim 6 including the additional steps of:

a. establishing a maximum level for the second mixture in the reservoir;

b. generating a level control signal when the maximum level is reached;

c. utilizing the signal to terminate the flow of the second mixture to the reservoir and to divert the flow of the second mixture to the source of the flow of dilute acid;

d. selecting a specific gravity for a second desired final mixture;

e. substituting the second desired final specific gravity for the final specific gravity in steps k through m;

f. repeating steps k through m;

g. terminating the flow of the second mixture to the source of the flow of dilute acid in response to the establishment of parity in step m; and

,

h. directing a flow of the second mixture at the second final specific gravity to a second reservoir.