Method of and apparatus for monitoring gaseous pollutants

• US 4,490,043 A
• Filed: 03/01/1982
• Issued: 12/25/1984
• Est. Priority Date: 03/02/1981
• Status: Expired due to Fees

• Current Assignee: Imperial Chemical Industries PLC (IMPERIAL CHEMICAL INDUSTRIES)
• Original Assignee: Imperial Chemical Industries PLC (IMPERIAL CHEMICAL INDUSTRIES)
• Inventors: Cramp, John H. W.
• Primary Examiner(s): Evans, F. L.
• Application Number:
  US06/353,418
• Time in Patent Office: 1,030 Days
• Field of Search: 356/51, 356/407, 356/409, 356/437, 356/438, 356/342, 250/339, 250/343, 250/345, 343/7.5
• US Class Current: 356/407
• CPC Class Codes: G01N 21/39 using tunable lasers

Abstract

Laser scanning apparatus for the monitoring of gaseous pollutants (e.g. on a chemical plant) in which two laser beams having different wavelengths (one corresponding to an absorption line of the gas to be monitored) and modulated at different frequencies are combined into a single scanning beam. A portion of the scattered radiation is collected, detected and measured to give, for each chosen beam direction, the amount of the gas being monitored. The amount of radiation reaching the detector from the laser source is varied according to a predetermined programme or in response to an external stimulus, and by this means the detector can be protected against severe overload when the beam scans over positions of abnormally high reflectivity.

Claims

1. A method for the remote quantitative monitoring of one or more selected gases in a gaseous environment, which comprises the steps of generating electromagnetic radiation from laser sources to give at least one detection beam containing a specific absorption wavelength of the gas or gases being monitored and at least one reference beam having a wavelength that is significantly less strongly absorbed by the gas or gases being monitored, modulating the amplitude of each of the beams with different modulation frequencies or phases, combining the modulated beams into a single beam in which the component modulated beams are substantially coincident with one another, displacing the combined beam angularly through the gaseous environment so as to direct the combined beam towards a plurality of locations sequentially and repetitively, collecting at least a portion of the radiation which is reflected from each of the locations, deriving electrical signals corresponding to the intensity of the collected radiation, isolating the electrical signals corresponding to the intensity of the radiation having the aforesaid modulation frequencies or phases, obtaining a ratio of the isolated signals corresponding to radiation collected from a detection beam and a related reference beam thereby to provide a measure of the amount of the selected gas or gases in each beam path traversed by the collected radiation originating from the laser sources, and varying according to a predetermined programme or in response to an external stimulus, the amount of radiation from the laser sources which is detected by the detector thereby to prevent the detected amount from exceeding a predetermined level.

2. A method as claimed in claim 1 which comprises varying according to the predetermined programme or in response to the external stimulus, the amount of radiation reaching the detector from the laser sources.

3. A method as claimed in claim 2, which comprises monitoring the amount of radiation collected and varying the amount of radiation reaching the detector from the laser sources in response to the amousnt of radiation monitored.

4. A method as claimed in claim 3 in which, whenever the collected radiation exceeds a predetermined threshold, the amount of laser radiation reaching the detector is varied so as to remain within a predetermined range in excess of the threshold for so long as an excess of radiation is collected.

5. A method as claimed in any one of claims 2 to 4, in which the amount of radiation reaching the detector from the laser sources is varied by varying the amount of laser radiation which is directed at the locations.

6. A method as claimed in claim 1 in which the amount of radiation detected by the detector is varied by at least partially desensitising the detector in response to an increase in its output signal.

7. Apparatus for the remote quantitative monitoring of one or more selected gases in a gaseous environment, which comprises laser sources for generating electromagnetic radiation capable of being tuned to give at least one detection beam containing a specific absorption wavelength of the gas or gases to be monitored and at least one reference beam having a wavelength that is significantly less strongly absorbed by the gas to be monitored, means for modulating the amplitude of each of the beams with different modulation frequencies or phrases, means for combining the modulated beams into a single combined beam in which the component modulated beams are substantially coincident with one another, scanning means to displace the combined beam angularly through the gaseous environment so as to direct the combined beam towards a plurality of locations sequentially and repetitively, means for collecting at least a portion of the radiation which is returned from each of the locations, a detector for deriving electrical signals corresponding to the intensity of the collected radiation, means for isolating the electrical signals corresponding to the intensity of radiation having the aforementioned modulation frequencies or phases, means for obtaining the ratio of the isolated signals corresponding to radiation collected from a detection beam and a related reference beam thereby to provide a measure of the amount of the selected gas or gases in each beam path traversed between the apparatus and the scanned locations, means for indicating the amount of gas detected, and means for varying according to a predetermined programme or in response to an external stimulus, the amount of radiation from the laser sources which is detected by the detector thereby to prevent the detected amount from exceeding a predetermined level.

8. Apparatus as claimed in claim 7, having means for varying the intensity of the combined beam which is directed at the various locations.

9. Apparatus as claimed in claim 8 is one wherein the intensity varying means comprises means for varying the outputs of the laser sources.

10. Apparatus as claimed in claim 9 comprising position indicating means having a parameter which varies according to the orientation of the scanning means, programme means for storing a predetermined programme correlating the variations of radiation intensity with specific positions of the scanning means, trigger means for comparing the programme and the position of the scanning means and for providing a signal wherever the scanning means position and predetermined programme match, and a laser power control means responsive to signals from the trigger means.

11. Apparatus as claimed in any one of claims 7 to 9 comprising means for monitoring the electrical signals derived by the detector, reference means for providing a reference signal characteristic of a predetermined threshold level, a comparator for comparing the detector-derived signal with the reference signal, and a laser power control means connected to and responsive to the output from the comparator.

12. Apparatus as claimed in claim 11 which comprises means for activating the laser power control means in reponse to a predetermined programme in addition to that in response to the variations in the amount of radiation collected.