Coated optical fiber

• US 4,492,428 A
• Filed: 08/16/1982
• Issued: 01/08/1985
• Est. Priority Date: 10/27/1981
• Status: Expired due to Term

• Current Assignee: Fitel USA Corporation
• Original Assignee: AT&T, Inc.
• Inventors: Levy, Alvin C.
• Primary Examiner(s): LEE, JOHN D
• Application Number:
  US06/408,713
• Time in Patent Office: 876 Days
• Field of Search: 350/96.30, 350/96.31, 350/96.33, 350/96.34, 350/96.29, 65/3.1, 65/3.11, 65/3.4, 65/3.43, 65/3.44, 427/163, 524/505
• US Class Current: 385/141
• CPC Class Codes: C08L 25/10 with conjugated dienes
• CPC Class Codes: C08L 91/00 Compositions of oils, fats or waxes; Compositions of derivatives thereof
• CPC Class Codes: G02B 1/048 characterised by the cladding material
• CPC Class Codes: G02B 6/02395 Glass optical fibre with a protective coating, e.g. two layer polymer coating deposited directly on a silica cladding surface during fibre manufacture G02B6/02052, G02B6/02057, G02B6/024, G02B6/032, G02B6/105, G02B6/14 take precedence; coating on fibre gratings G02B6/02104; multilayer core or cladding G02B6/036; reinforcing splice joints G02B6/2558; optical cables, i.e. comprising protective structures external to the protective coating such as a jacket or plural coated optical fibres G02B6/44; coating of glass to obtain optical fibres C03C25/104

Abstract

An optical fiber coating comprising a thermoplastic rubber block copolymer reduces microbending losses over a wide service temperature range, typically down to at least -40 degrees Celsius, while obtaining an upper temperature limit of typically at least 90 degrees Celsius. The processing properties, including shelf life, cure rate, and toughness, are superior to typical prior art materials, such as silicones. The inventive coating can be used as the inner coating of a dual-layer coated fiber or as an outer or single coating layer.

Claims

1. A coated optical fiber comprising an optical fiber and one or more coated layers thereon, characterized in that

at least one coated layer comprises a mixture of:

(X) An ASTM type 103, 104A, 104B, or mixture thereof, napthenic or paraffinic oil, with a wax optionally substituted for a portion of said oil;

(Y) a styrene-rubber-styrene block copolymer having a styrene-rubber ratio of 0.2 to 0.5; and

optionally (Z) a coumarone-indene copolymer or vinyl toluene -α

methyl styrene copolymer; and

further comprises a thermal oxidative stabilizer, wherein the ingredients X, Y, and Z have relative proportions by weight falling within the shaded area bounded by A'"'"'B'"'"'C'"'"'D'"'"' of FIG. 2 for a styrene-rubber-styrene block copolymer having a viscosity of 1190 cps and with the acceptable proportions of said block copolymer adjusted corresponding to a reduction by 3 parts for block copolymer material having a viscosity of 1800 cps, and to an increase by 6 parts for block copolymer material having a viscosity of 500 cps, with said viscosity being measured for a solution of 20 weight percent block copolymer in toluene at 25 degrees Celsius.

2. The coated optical fiber of claim 1 wherein 0 to 12 percent microcrystalline wax substitutes for 0 to 12 percent of said oil, based on total weight percentage of said mixture.

3. The coated fiber of claim 1 wherein said at least one coated layer is the inner layer of a dual-layer coated fiber.

4. A coated optical fiber comprising an optical fiber and one or more coated layers thereon, characterized in that

at least one coated layer comprises a mixture of:

(X) an ASTM type 103, 104A, 104B, or mixture thereof, napthenic or paraffinic oil, with a wax optionally substituted for a portion of said oil;

(Y) a styrene-rubber-styrene block copolymer having a styrene-rubber ratio of 0.2 to 0.5; and

optionally (Z) a coumarone-indene copolymer; and

further comprises a thermal oxidative stabilizer; and

wherein said at least one coated layer is the inner layer of a dual-layer coated fiber, and wherein said mixture comprises by weight 59 to 61 percent of said oil;

24 to 26 percent of said styrene-ethylene butylene-styrene block copolymer;

4 to 6 percent of said coumarone-indene copolymer;

8 to 10 percent of said wax; and

0.5 to 1.5 percent of said thermal oxidative stabilizer.