Method for the manufacture of contact lenses using microwave energy

• US 4,495,117 A
• Filed: 03/17/1983
• Issued: 01/22/1985
• Est. Priority Date: 03/17/1982
• Status: Expired due to Fees

• Current Assignee: CIBA Vision Corporation (Bayer AG)
• Original Assignee: Alcon Pharmaceuticals Limited (Alcon Incorporated)
• Inventors: Feurer, Bernard, Pigot, Gilles
• Primary Examiner(s): Woo, Jay H.
• Assistant Examiner(s): McGurk, Michael
• Application Number:
  US06/476,385
• Time in Patent Office: 677 Days
• Field of Search: 264/1.4, 264/1.1, 264/2.2, 264/25, 264/23, 264/26, 425/808, 425/174.4, 425/174.2, 350/410, 350/409, 350/417, 351/177
• US Class Current: 264/1.36
• CPC Class Codes: B29C 2035/0855 using microwave
• CPC Class Codes: B29C 33/0022 Multi-cavity moulds B29C33/301 takes precedence
• CPC Class Codes: B29C 35/08 by wave energy or particle radiation B29C64/00, B29C71/04 take precedence
• CPC Class Codes: B29C 35/0805 using electromagnetic radiation
• CPC Class Codes: B29D 11/00134 Curing of the contact lens material
• CPC Class Codes: H05B 6/80 Apparatus for specific applications stoves or ranges F24C7/02
• CPC Class Codes: Y10S 425/808 Lens mold

Abstract

The invention concerns a method for manufacturing a contact lens, through molding within water-tight molds. The polymerization of lenses is insured by arranging a number of molds within one or several sealed metallic chambers (9) constituting a resonant cavity of a unique mode for an ultra high frequency wave; these molds are positioned in an area of the cavity where the electromagnetic field approximately of ultra high frequency waves is homogeneous, and are distributed so that the amounts of basic composition to be polymerized act as a load fitted to the inside of said cavity.

Claims

1. A method of manufacturing a contact lens of appropriate optical quality consisting of:

constructing water-tight molds, reproducing, in the mold cavity, the shape of the lens desired and wherein said water-tight molds are composed of a substantially transparent material with respect to ultra high frequency electromagnetic waves, and said water-tight molds being constructed so as to possess a thermic inertia much higher than the portion of basic composition needed to make a lens;

preparing a basic composition starting with one or several monomers having double polymerizable bonds, and having an absorbent quality with respect to ultra high frequency waves;

insuring polymerization of the composition within the sealed molds, through irradiation by means of ultra high frequency waves;

said method being characterized in that the polymerization operation is realized by arranging several molds (1), each containing an amount of basic composition, within at least one sealed metallic chamber (9) constituting a resonant cavity of a unique mode for the frequency of the ultra high frequency waves used, said molds being positioned in an area of the cavity where the electromagnetic field is approximately homogeneous and being distributed so that the amounts of basic composition contained in said molds act as a load fitted to the inside of said resonant cavity.

2. Method according to claim 1, characterized in that the molds (1) are arranged in a chamber (9) possessing ring geometry, constituting a resonant cavity according to TM 010 or TM 110 modes, said chamber being excited so as to favor this mode of resonance.

3. Method according to claim 2, characterized in that the molds (1) are arranged in chamber (9) excited by ultra high frequency radiation means (10, 25) fit to generate an electromagnetic field composed of an electrical field whose lines of force are appreciably straight lines parallel to chamber'"'"'s rotational axis, and of a magnetic field whose lines of force are curves located in planes perpendicular to the chamber'"'"'s axis.

4. Method according to claim 3, characterized in that the molds (1) are arranged in stacks, superposed upon one another to form at least one column situated the length of or around the chamber'"'"'s rotational axis (9), said column(s) being positioned in a usable central volume of chamber representing a fraction of this latter'"'"'s total volume.

5. Method according to claim 4, characterized in that the molds are inserted in a resonant cavity according to the TM 010 mode and are arranged, on the one hand, as four stacks, called central columns, in the immediate vicinity of a radiating antenna (10) extending the length of chamber'"'"'s axis, and on the other hand, as four additional stacks, called peripheral columns, arranged at the immediate circumference of the central columns, each peripheral column being set in the space separating the exterior circumference of the two neighboring central columns.

6. Method according to claim 5, characterized in that the molds (1) are arranged, on the one hand, as central columns in the immediate vicinity of the antenna (10) and extending almost the height of chamber (9), and on the other hand, as peripheral columns, arranged at the immediate circumference of central columns and extending over a fraction of chamber'"'"'s height.

7. Method according to claim 4, characterized in that the molds are inserted in a resonant cavity according to the TM 010 mode excited by means of an iris (25), symmetrical in relation to the chamber'"'"'s transverse median plane, said molds being arranged in a tubular central guide (28, 30) running through chamber the length of its axis.

8. Method according to claim 7, characterized in that the molds pass through central guide (30) at the appropriate speed so that each mold remains in the chamber'"'"'s usable central volume the necessary time for processing.

9. Method according to claim 6, characterized in that one interposes in one of the columns of molds (1) auxiliary dielectric loads of an absorbent material with respect to ultra high frequency waves, so as to increase the homogeneity of the electromagnetic field at molds'"'"' level.

10. Method according to claim 2, characterized in that one insures ventilation a cooling of the upper portion of the chamber, to make the temperature homogeneous within this latter and to insure, at the level of the molds, a temperature lower than approximately 40°

C.

11. Method according to claim 3, characterized in that chamber (9) is supplied with ultra high frequency waves so that the average energy density within this latter may be comprised between approximately 10^-2 and 50×

10^-2 cm³ /watts.

12. Method according to claim 1, in which the basic composition is a monomer or a mixture of monomers, having a high volume molecule, from the following group:

hydrox ethyl methacrylate, hydroxy propyl methacrylate, hydroxy ethyl acrylate, ethylene glycol dimethacrylate, vinyl pyrrolidone N, methyl methacrylate, methacrylic acid characterized in that one mixes with said basic composition an initiator made in particular of azobis iso butyro nitril, or a hydro-peroxide or a peroxide, in weight proportion comprised between approximately 0.04% and 0.15%.