Primary system

• US 4,495,156 A
• Filed: 01/05/1983
• Issued: 01/22/1985
• Est. Priority Date: 01/05/1983
• Status: Expired due to Fees

• Current Assignee: American National Can Company (Ball Corporation)
• Original Assignee: American Can Co (Citigroup Incorporated)
• Inventors: Rohowetz, Stanley E.
• Primary Examiner(s): Lusignan, Michael R.
• Application Number:
  US06/455,649
• Time in Patent Office: 748 Days
• Field of Search: 148/6.14 R, 148/6.2, 427/388.2, 427/388.4, 427/399, 427/409, 427/407.1, 427/27, 427/384, 427/417, 427/419.8, 106/287.19, 260/429.5, 252/32
• US Class Current: 556/14
• CPC Class Codes: B05D 7/14 to metal, e.g. car bodies involving a chemical reaction between the metal and the coating C23
• CPC Class Codes: C23F 11/10 using organic inhibitors

Abstract

A method is provided wherein an aqueous titanate chelate is applied "in-line" to non-lubricated or lubricated tinplate surfaces during metal forming operations. The method provides economical benefits in using a non-combustible solvent system and in requiring minimal energy output for application or activation of the chelate. Inks or coatings that are subsequently applied to the chelate treated surfaces show improved adhesion.

Claims

1. A method for priming metal substrates including the steps of:

(a) coating the surface of the metal substrate with an aqueous primer system comprising an organic titanium chelate dissolved in or admixed with water or a water-solvent mixture.

(b) drying the coating to produce a titanate film on the metal surface; and

(c) applying a lubricant over said titanate coated surface.

2. The method of claim 1 wherein said metal is tinplate.

3. The method of claim 2 wherein the primer is applied from an aqueous spray comprising a titanium chelate selected from the group consisting of titanium acetyl acetonate, lactic acid titanium chelate and triethanolamine titanium chelate.

4. The method of claim 3 wherein said lubricant is acetyl tributyl citrate or dioctyl sebacate.

5. A method for priming metal substrates including the steps of:

(a) applying a coating of a lubricant onto the surface of the metal substrate;

(b) coating said lubricated metal with an aqueous primer system comprising an organic titanium chelate dissolved in or admixed with water or a water-solvent mixture.

6. The method of claim 5 wherein the substrate is tinplate.

7. The method of claim 6 wherein the primer is applied from an aqueous spray comprising a titanium chelate selected from the group consisting of titanium acetyl acetonate, lactic acid titanium chelate and triethanolamine titanium chelate.

8. The method of claim 7 wherein said lubricant is acetyl tributyl citrate or dioctyl sebacate.

9. A method for priming metal substrates including the steps of:

(a) applying acetyltributyl citrate or dioctyl sebacate to said metal surface;

(b) coating said lubricated metal with an aqueous spray containing about 0.1% to 5% titanium acetyl acetonate and about 0.5% to 3% acetic acid dissolved in water or a water-isopropanol blend; and

(c) drying the coating to produce a titanate film on said lubricated metal surface.

10. The method of claim 9 wherein the metal is tinplate.

11. A method for priming metal substrates including the steps of:

(a) coating the metal surface with an aqueous spray containing about 0.1% to 5% titanium acetyl acetonate and 0.5% to 3% acetic acid dissolved in water or a water-isopropanol blend;

(b) drying the coating to produce a titanate film on the metal surface; and

(c) applying a acetyltributyl citrate or dioctyl sebacate lubricant over said titanate coated surface.

12. The method of claim 11 wherein said metal is tinplate.