Method for determining optimum concentration of hydration inhibitor for clays in drilling fluids

• US 4,495,800 A
• Filed: 11/15/1982
• Issued: 01/29/1985
• Est. Priority Date: 11/15/1982
• Status: Expired due to Fees

• Current Assignee: Baroid Technology Incorporated
• Original Assignee: NL Industries Incorporated (Valhi Holding Company)
• Inventors: Wilcox, Roy D.
• Primary Examiner(s): Gill, James J.
• Assistant Examiner(s): ROSKOS, JOSEPH
• Application Number:
  US06/441,855
• Time in Patent Office: 806 Days
• Field of Search: 73/61.4, 73/53
• US Class Current: 73/61.63
• CPC Class Codes: C09K 8/16 characterised by the inorganic compounds other than clay
• CPC Class Codes: E21B 49/005 Testing the nature of borehole walls or the formation by using drilling mud or cutting data

Abstract

A method is provided for selecting the optimum concentration of inhibitors such as soluble salts to effect maximum clay swelling and dispersion inhibition in an aqueous fluid of water-swellable, argillaceous materials including clays as exemplified by bentonite and argillaceous sediments, such as shales, encountered in drilling operations. In this method filtration measurements are first taken to develop a filtration parameter from which the optimum inhibitor concentration is readily determined.

Claims

1. A method for determining the optimum inhibitor concentration required in an aqueous inhibited fluid for maximum clay swelling and dispersion inhibition of water-wettable argillaceous materials encountered in drilling operations comprising:

(a) determining a parameter for said aqueous inhibited fluid having dispersed therein a quantity of the water-swelling argillaceous material which parameter is a function of the swelling of the argillaceous material and approaches a substantially constant value with increasing concentration of said inhibitor; and

(b) determining from said parameter the minimum inhibitor concentration at which said substantially constant value is first obtained.

2. The method of claim 1 wherein said parameter comprises a filtration property of said fluid.

3. The method of claim 2 wherein said filtration property is filtration time.

4. The method of claim 3 wherein said parameter is determined by measuring the filtration time of dispersions of said argillaceous material in aqueous solutions of varying inhibitor concentration and determining the substantially constant minimum filtration time as a function of inhibitor concentration.

5. The method of claim 1 wherein said parameter comprises a hydration property of said argillaceous material.

6. The method of claim 5 wherein said hydration property is the sorption index defined as gm. solu. sorbed/gm. argillaceous material.

7. The method of claim 6 wherein said parameter is determined by measuring the sorption index of dispersions of said argillaceous material in aqueous solutions of varying inhibitor concentration and determining the substantially constant minimum sorption index as a function of inhibitor concentration.

8. The method of claim 1 wherein the said aqueous inhibited fluid comprises a dispersion of the said argillaceous material in a water solution of the inhibitor.

9. The method of claim 1 wherein said argillaceous material is a clay.

10. The method of claim 1 wherein said argillaceous material is bentonite

11. The method of claim 1 wherein said argillaceous material is an argillaceous sediment.

12. The method of claim 1 wherein said argillaceous material is shale.

13. The method of claim 1 wherein said inhibitor is selected from the group consisting of alkali metal salts, alkaline earth metal salts, organic flocculants, and coagulants.

14. The method of claim 1 wherein said inhibitor is an alkali metal salt.

15. The method of claim 1 wherein said inhibitor is potassium chloride.

16. The method of claim 1 wherein said inhibitor is an alkaline earth metal salt.

17. The method of claim 1 wherein said inhibitor is calcium chloride.