Process for removal of hydrogen sulfide and carbon dioxide from gas streams

• US 4,496,371 A
• Filed: 09/21/1983
• Issued: 01/29/1985
• Est. Priority Date: 09/21/1983
• Status: Expired due to Fees

• Current Assignee: UOP Des Plaines IL A NY General Partnership
• Original Assignee: UOP Llc (Honeywell International Inc.)
• Inventors: Johnson, Russell W., Urban, Peter
• Primary Examiner(s): Woo, Jay H.
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US06/534,227
• Time in Patent Office: 496 Days
• Field of Search: 423/573 G, 423/573 R, 423/221, 423/232, 48/196 R, 48/196 A, 48/197 R
• US Class Current: 95/174
• CPC Class Codes: B01D 53/1418 Recovery of products
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1462 Removing mixtures of hydrogen sulfide and carbon dioxide
• CPC Class Codes: C10K 1/122 containing only carbonates, bicarbonates, hydroxides or oxides of alkali-metals (including Mg)
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02P 20/151 Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Abstract

A gas treating process is disclosed. Hydrogen sulfide and carbon dioxide are removed from a hydrocarbon vapor stream by absorption into an aqueous carbonate solution. Hydrogen sulfide picked up by the circulating carbonate solution is oxidized to produce liquid sulfur, which is withdrawn. The carbonate solution is then stripped to release carbon dioxide and produce the lean carbonate solution used for absorption. By-product thiosulfate formed in the oxidation step is eliminated by reaction with hydrogen sulfide. Metal phthalocyanines are used as the catalyst for the elimination of thiosulfate and for the oxidation of hydrogen sulfide.

Claims

1. A gas treating process which comprises the steps of:

(a) contacting a feed gas stream which comprises a normally vaporous hydrocarbon, hydrogen sulfide and carbon dioxide with a hereinafter characterized first liquid stream, which comprises an aqueous carbonate solution, in an absorption zone operated under absorption conditions which promote the removal of hydrogen sulfide and carbon dioxide from the feed gas stream, and producing a treated gas stream and a second liquid stream comprising the aqueous carbonate solution, which is rich in hydrogen sulfide and carbon dioxide;

(b) passing at least a portion of the second liquid stream into an oxidation zone wherein the second liquid stream is admixed with an oxygen-containing gas stream in the presence of an oxidation catalyst under conditions which promote the oxidation of hydrogen sulfide to sulfur, including a temperature at which sulfur is present as a liquid, and thereby effecting the production of a mixed phase stream comprising liquid sulfur and the aqueous carbonate solution, which contains thiosulfate ions and is rich in carbon dioxide;

(c) separating the mixed phase stream in a phase separation zone and producing a liquid phase sulfur stream, which is withdrawn from the process, and a third liquid stream comprising the aqueous carbonate solution and which is rich in carbon dioxide; and

,

(d) passing the third liquid stream into a stripping zone operated at stripping conditions effective to effect the production of a first vapor stream comprising carbon dioxide, which is withdrawn from the process, and a fourth liquid stream comprising the aqueous carbonate solution which is lean in both hydrogen sulfide and carbon dioxide, and recycling at least a portion of the fourth liquid stream to the absorption zone as the previously referred to first liquid stream.

2. The process of claim 1 further characterized in that a fixed bed of oxidation catalyst is present within the oxidation zone.

3. The process of claim 2 further characterized in that the oxidation catalyst comprises a metal phthalocyanine compound.

4. The process of claim 3 further characterized in that an oxidation catalyst comprising a metal phthalocyanine compound is present in the aqueous carbonate solution which circulates through the process.

5. The process of claim 4 further characterized in that the oxygen-containing gas stream is air and in that a second vapor stream comprising residual components of the oxygen-containing gas stream is withdrawn from the phase separation zone.

6. The process of claim 5 further characterized in that the aqueous carbonate solution comprises a carbonate chosen from the group consisting of ammonia carbonate, sodium carbonate, and potassium carbonate.

7. The process of claim 6 further characterized in that a temperature between about 120°

and about 220°

C. is maintained at some point in the absorption zone.

8. The process of claim 6 further characterized in that the oxidation zone is maintained at a temperature between about 120°

and about 220°

C.

9. The process of claim 1 further characterized in that a fifth liquid stream comprising the aqueous carbonate solution, and which contains thiosulfate ions and is relatively rich in hydrogen sulfide, is withdrawn from the absorption zone and is passed into a reaction zone wherein thiosulfate is catalytically reduced to elemental sulfur by reaction with hydrogen sulfide.

10. The process of claim 9 further characterized in that a reaction zone effluent stream comprising the aqueous carbonate solution and elemental sulfur is passed into the oxidation zone.

11. A gas treating process which comprises the steps of:

(a) contacting a feed gas stream which comprises a normally vaporous hydrocarbon, hydrogen sulfide, and carbon dioxide with a first liquid stream which comprises a lean aqueous carbonate solution containing thiosulfate ions in a first absorption zone operated under conditions which promote the selective removal of hydrogen sulfide from the feed gas stream and thereby producing a first vapor stream, which comprises the normally vaporous hydrocarbon, hydrogen sulfide, and carbon dioxide, and a second liquid stream comprising the aqueous carbonate solution and which is rich in hydrogen sulfide;

(b) contacting the first vapor stream with a third liquid stream which comprises a lean aqueous carbonate solution in a second absorption zone operated under conditions which effect the removal of hydrogen sulfide and carbon dioxide from the first vapor stream and thereby producing a treated gas stream, which is withdrawn from the process, and a fourth liquid stream comprising the aqueous carbonate solution and which is rich in hydrogen sulfide and carbon di- oxide;

(c) passing the second liquid stream through a reaction zone in which a reaction between hydrogen sulfide and a thiosulfate is catalytically promoted at conditions which result in the formation of sulfur;

(d) contacting at least major portions of the second liquid stream and the fourth liquid stream with an oxygen-containing gas stream in an oxidation zone in the presence of an oxidation catalyst under conditions which promote the oxidation of hydrogen sulfide to sulfur, including a temperature at which sulfur is present as a liquid, and effecting the production of a mixed phase stream comprising liquid sulfur, the aqueous carbonate solution and residual compounds present in the oxygen-containing gas stream;

(e) separating the mixed phase stream in a phase separation zone and thereby producing an effluent gas stream, a liquid phase sulfur stream which is withdrawn from the process, and a fifth liquid stream comprising the aqueous carbonate solution and which is rich in carbon dioxide; and

,

(f) releasing carbon dioxide from the fifth liquid stream in a stripping zone operated at stripping conditions and thereby producing a second vapor stream, which comprises carbon dioxide, and is withdrawn from the process, and a sixth liquid stream comprising an aqueous carbonate solution comprising thiosulfate ions which is lean in both hydrogen sulfide and carbon dioxide, and recycling at least a portion of the sixth liquid stream to the first and the second absorption zones as the first and the third liquid streams.

12. The process of claim 11 further characterized in that a fixed bed of an oxidation catalyst comprising an activated charcoal is present in the oxidation zone.

13. The process of claim 11 further characterized in that the reaction between hydrogen sulfide and the thiosulfate is catalyzed by catalyst comprising a metal phthalocyanine compound.

14. The process of claim 13 further characterized in that an oxidation catalyst comprising a metal phthalocyanine compound is present in the aqueous carbonate solution which circulates through the process.

15. The process of claim 14 further characterized in that a fixed bed of oxidation catalyst comprising a metal phthalocyanine is present within the oxidation zone.

16. The process of claim 13 further characterized in that the reaction zone is operated at a higher temperature than the oxidation zone.

17. The process of claim 16 further characterized in that the oxidation zone is operated at a temperature above about 120°

C.

18. The process of claim 17 further characterized in that the aqueous carbonate solution comprises a carbonate compound chosen from the group consisting of amaonia carbonate, sodium carbonate, and potassium carbonate.

19. The process of claim 18 further characterized in that the oxygen-containing gas stream passed into the oxidation zone comprises air.

20. The process of claim 11 further characterized in that a fixed bed of oxidation catalyst comprising a metal phthalocyanine compound is present within an upper portion of the second absorption zone, and in that an oxygen-containing vapor stream is passed into the second absorption zone at a point below the fixed bed of oxidation catalyst.