Radiation-curable coatings containing reactive pigment dispersants

• US 4,496,686 A
• Filed: 05/07/1984
• Issued: 01/29/1985
• Est. Priority Date: 05/07/1984
• Status: Expired due to Term

• Current Assignee: DSM B.V.
• Original Assignee: DeSoto, Inc. (Overstock.com Incorporated)
• Inventors: Ansel, Robert E.
• Primary Examiner(s): Lilling, Herbert J.
• Application Number:
  US06/607,790
• Time in Patent Office: 267 Days
• Field of Search: 524/785, 524/847, 524/850, 524/854, 524/873, 524/874, 524/780, 523/181, 204/159.22, 526/301, 526/318, 526/314
• US Class Current: 524/850
• CPC Class Codes: C08F 299/024 the unsaturation being in acrylic or methacrylic groups
• CPC Class Codes: C08F 299/065 from polyurethanes with side or terminal unsaturations
• CPC Class Codes: C08G 18/44 Polycarbonates
• CPC Class Codes: C08G 18/672 Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
• CPC Class Codes: G11B 5/7026 Radiation curable polymers

Abstract

Liquid coating compositions adapted to be cured by exposure to penetrating radiation are disclosed in which a liquid vehicle of coating viscosity having an ethylenically unsaturated portion comprising one or more polyethylenically unsaturated materials adapted to cure on radiation exposure, pigment dispersed in the vehicle, and an ethylenically unsaturated radiation-curable dispersant containing a carboxyl group for wetting the pigment and assisting in the stable dipsersion of the pigment in the vehicle. This dispersant is a half amide or half ester of an ethylenically unsaturated polycarboxylic acid anhydride, such as maleic anhydride, with an organic compound having a molecular weight of from 100 to 4000 and which contains a single hydroxy group or a single amino group as the sole reactive group thereof.

Claims

1. A liquid coating composition adapted to be cured by exposure to ionizing radiation comprising, a liquid vehicle of coating viscosity having an ethylenically unsaturated portion comprising one or more polyethylenically unsaturated materials adapted to cure on radiation exposure, pigment dispersed in said vehicle, and an ethylenically unsaturated radiation-curable dispersant containing a carboxy group for wetting said pigment and assisting in the stable dispersion of said pigment in said vehicle, said dispersant being a half amide or half ester of an ethylenically unsaturated polycarboxylic acid anhydride with an organic compound having a molecular weight of from 100 to 4000 and which contains a single hydroxy group or a single amino group as the sole reactive group thereof.

2. A liquid coating composition as recited in claim 1 in which said polyethylenically unsaturated material comprises a polyether, and said organic compound is a polyether.

3. A liquid coating composition as recited in claim 1 in which said ethylenically unsaturated polycarboxylic acid anhydride is maleic anhydride.

4. A liquid coating composition as recited in claim 1 in which said polyethylenically unsaturated material comprise oligomers having a molecular weight of from 500 to 20,000 and providing from 2-10 hydroxy groups per molecule.

5. A liquid coating composition as recited in claim 4 in which said oligomers comprise polyether groups held together by from 4-20 urethane groups per molecule.

6. A liquid coating composition as recited in claim 4 in which said oligomers comprise hydroxy-functional diethylenically unsaturated polyurethanes.

7. A liquid coating composition as recited in claim 1 in which said polyethylenically unsaturated material comprise polyacrylates and polymethacrylates of polyhydric alcohols having from 2-4 hydroxy groups per molecule.

8. A liquid coating composition as recited in claim 1 in which at least 30% of the ethylenically unsaturated portion of the coating composition is constituted by said polyethylenically unsaturated material.

9. A liquid coating composition as recited in claim 8 in which the viscosity of the coating composition is reduced by having of at least 10% of the ethylenically unsaturated portion of the coating composition constituted by monoethylenically unsaturated liquid.

10. A liquid coating composition as recited in claim 1 containing pigment in a pigment to binder weight ratio in excess of 1:

1 and inert volatile organic solvent in an amount to reduce the total solids content of the pigmented coating composition to the range of from 25% to 60%.

11. A liquid coating composition as recited in claim 9 containing pigment in a pigment to binder weight ratio in excess of 1:

1 and inert volatile organic solvent in an amount to reduce the total solids content of the pigmented coating composition to the range of from 25% to 60%.

12. A liquid coating composition as recited in claim 1 containing pigment in a pigment to binder weight ratio in excess of 0.5:

1 and from 0.25% to 7% of said dispersant.