Gunpowder substituted composition and method

• US 4,497,676 A
• Filed: 11/01/1982
• Issued: 02/05/1985
• Est. Priority Date: 11/01/1982
• Status: Expired due to Term

• Current Assignee: Anthony Cioffe, Assigns Fifty-One Percent To ESK Investment Group, Golden Powder of Texas Incorporated Sanger Harris Office Tower
• Original Assignee: Assigns Fifty-One Percent To ESK Investment Group
• Inventors: Kurtz, Earl F.
• Primary Examiner(s): Lechert, Jr., Stephen J.
• Application Number:
  US06/437,965
• Time in Patent Office: 827 Days
• Field of Search: 149/2, 149/46, 149/61, 149/21, 149/109.6, 149/45, 102/431, 102/DIG. 700, 264/3 R, 264/3 C
• US Class Current: 149/2
• CPC Class Codes: C06B 21/0041 by compression
• CPC Class Codes: C06B 31/00 Compositions containing an inorganic nitrogen-oxygen salt
• CPC Class Codes: F42B 5/192 Cartridge cases characterised by the material of the casing wall cartridge bags F42B5/38
• CPC Class Codes: Y10S 102/70 Combustilbe cartridge

Abstract

A gunpowder substitute which is capable of also being molded into a consumable cartridge or cartridge case comprising between 50% to 75% by weight of an inorganic nitrate and between 25% to 50% by weight of an organic acid including ascorbic acid, erythorbic acid and mixtures thereof.

Claims

1. A consumable cartridge comprising:

(a) a primer; and

(b) a projectile; and

(c) a molded cartridge case containing means for receiving said primer and means for receiving said projectile in association therewith for use in a firearm, said molded cartridge case comprising a composition made from an inorganic nitrate oxidizer and an organic acid selected from the group consisting of erythorbic acid, ascorbic acid, and mixtures thereof.

2. The consumable cartridge of claim 1 wherein the inorganic nitrate and organic acid are present in the molded cartridge in amounts, which when compared to the total weight of these two constituents, the nitrate comprises from about 50% to about 75% by weight and the acid comprises from about 25% to 50% by weight, before the cartridge is molded.

3. The consumable cartridge of claim 2 wherein the inorganic nitrate is potassium nitrate.

4. The consumable cartridge case comprising:

a molded cartridge case containing means for receiving a primer and means for receiving a projectile in association therewith suitable for use in a firearm, said molded cartridge case having a generally cylindrical shape and containing a composition prepared from a mixture of an inorganic nitrate oxidizer selected from the group consisting of potassium nitrate, ammonium nitrate and mixtures thereof, and an organic acid selected from the group consisting of erythorbic acid, ascorbic acid and mixtures thereof.

5. The consumable cartridge case of claim 4 wherein the inorganic nitrate and acid are present in the molded cartridge case in amounts which when compared to the total weight of these two constituents, the nitrate comprises from about 50% to 75% by weight and the acid comprises from about 25% to 50% by weight.

6. A method of making a consumable cartridge comprising the steps of (1) forming a slurry and solution of an oxidizer and an organic acid;

(2) drying the slurry and solution mixture at a temperature below about 175°

F. (79°

C.); and

(3) compacting the dried mixture in a mold to a preselected shape using between 10,000 lbs. per square inch and 14,000 lbs. per square inch to form the finished shape.

7. The method of claim 6 wherein said step of compacting includes heating the mixture while compacting to a temperature less than 175°

F. (79°

C.).

8. The method of claim 7 wherein the oxidizer is potassium nitrate and the acid is erythorbic acid, ascorbic acid or mixtures thereof.

9. The method of claim 8 wherein the slurry and solution includes cellulosic fibers.

10. A method of making a consumable cartridge case comprising the steps of (1) forming a slurry and solution of an oxidizer and an organic acid;

(2) drying the slurry and solution mixture at a temperature below about 175°

F. (79°

C.); and

(3) compacting the dried mixture in a mold to a preselected generally hollow cylindrical shape using between 10,000 lbs. per square inch and 14,000 lbs. per square inch to form the finished shape.

11. The method of claim 10 wherein said step of compacting includes heating the mixture while compacting to a temperature less than 175°

79°

C.).

12. The method of claim 11 wherein the oxidizer is potassium nitrate and the acid is erythorbic acid, ascorbic acid or mixtures thereof.

13. The method of claim 12 wherein the slurry and solution includes cellulosic fibers.

14. A gunpowder substitute comprising:

a dry mixture of an inorganic nitrate oxidizer and an organic acid including erythorbic or ascorbic acid.

15. The gunpowder substitute of claim 14 wherein the inorganic nitrate and acid are present in amounts when compared to the total weight of these two constituents, the nitrate comprises from about 50% to 75% by weight and the acid comprises from about 25% to 50% by weight.

16. The gunpowder substitute of claim 15 wherein the inorganic nitrate is potassium nitrate, ammonium nitrate and mixtures thereof.

17. The gunpowder substitute of claim 16 wherein the organic acid is ascorbic acid, erythorbic acid and mixtures thereof.

18. A method of making a gunpowder substitute comprising the steps of (1) forming a slurry and solution of an oxidizer and an organic acid;

(2) drying the slurry and solution mixture at a temperature below about 175°

F. (79°

C.); and

(3) dry mixing the dried mixture.

19. The method of claim 18 wherein the oxidizer is potassium nitrate and the acid is erythorbic acid, ascorbic acid or mixtures thereof.

20. The method of claim 19 wherein the slurry and solution includes cellulosic fibers.