Instrument for use with an electrochemical cell

• US 4,498,039 A
• Filed: 06/18/1979
• Issued: 02/05/1985
• Est. Priority Date: 06/18/1979
• Status: Expired due to Term

• Current Assignee: International Business Machines Corporation
• Original Assignee: International Business Machines Corporation
• Inventors: Kanazawa, Kay K., Galwey, Ronald K.
• Primary Examiner(s): Beha, Jr., William H.
• Assistant Examiner(s): STERRETT, JEFFREY L
• Application Number:
  US06/049,525
• Time in Patent Office: 2,059 Days
• Field of Search: 204/195 F, 204/228, 204/406, 204/412, 204/435, 323/4, 323/19, 323/40, 323/234, 323/265, 323/270, 323/273, 323/280, 330/260
• US Class Current: 323/234
• CPC Class Codes: G01N 27/416 Systems G01N27/27 takes precedence
• CPC Class Codes: G01R 19/0084 measuring voltage only all subgroups of G01R19/00 take precedence

Abstract

An improved instrument for use with an electrochemical cell that provides a system having enhanced stability and increased bandwidth. The instrument includes a voltage to current converter which drives the cell. The current output of the voltage to current converter is linearly proportional to the differential voltage input. The voltage to current converter drives the cell in both the potentiostatic mode and in the galvanostatic mode of operation.

Claims

1. An instrument for use with an electrochemical cell having a counter electrode, a reference electrode and a grounded working electrode, said instrument operating in a potentiostatic mode and comprising:

a voltage to current converter having an inverting input connected to the reference electrode, a non-inverting input and an output, said output connected to the counter electrode, said converter having a current output that is linearly proportional to the difference between the voltages at said non-inverting input and said inverting input.

2. An instrument for use with an electrochemical cell having a counter electrode, a reference electrode and a grounded working electrode, said instrument operating in a potentiostatic mode and comprising:

a terminal;

differential amplifier means having an inverting input connected to said terminal, a non-inverting input connected to an external voltage source and an output;

a voltage to current converter having an input connected to said amplifier means output and an output connected to the counter electrode, said converter having a current output that is linearly proportional to the voltage input; and

buffer amplifier means having a non-inverting input connected to the reference electrode, an inverting input connected to said terminal and an output connected to said terminal.

3. An instrument for use with an electrochemical cell having a counter electrode, a reference electrode and a grounded working electrode, said instrument operating in either a galvanostatic mode or a potentiostatic mode and comprising:

a terminal connected to an external voltmeter;

differential amplifier means having an inverting input, a non-inverting input connected to an external voltage source and an output;

a voltage to current converter having an input connected to said amplifier means output and an output connected to the counter electrode, said converter having a current output that is linearly proportional to the voltage input;

buffer amplifier means having a non-inverting input connected to the reference electrode, an inverting input connected to said terminal and an output connected to said terminal; and

switch means that is connected between said differential amplifier means inverting input, said terminal and ground wherein said inverting input is connected to said terminal when operating in a potentiostatic mode and wherein said inverting input is connected to ground when operating in a galvanostatic mode.