Controlled fade effervescing cleanser

• US 4,499,001 A
• Filed: 03/02/1984
• Issued: 02/12/1985
• Est. Priority Date: 04/03/1981
• Status: Expired due to Fees

• Current Assignee: Warner-Lambert Company (Pfizer Inc.)
• Original Assignee: Warner-Lambert Company (Pfizer Inc.)
• Inventors: Eoga, Anthony B. J.
• Primary Examiner(s): Albrecht, Dennis L.
• Application Number:
  US06/585,654
• Time in Patent Office: 347 Days
• Field of Search: 252/95, 252/99, 252/103, 252/186.43, 252/350, 252/174, 252/102
• US Class Current: 510/100
• CPC Class Codes: A61K 2800/222 Effervescent
• CPC Class Codes: A61K 8/22 Peroxides; Oxygen; Ozone
• CPC Class Codes: A61K 8/23 Sulfur; Selenium; Tellurium; Compounds thereof
• CPC Class Codes: A61Q 11/02 Preparations for deodorising, bleaching or disinfecting dentures
• CPC Class Codes: C11D 3/0052 Gas evolving or heat producing compositions
• CPC Class Codes: C11D 3/046 Salts
• CPC Class Codes: C11D 3/3932 Inorganic compounds or complexes
• CPC Class Codes: C11D 3/40 Dyes ; Pigments

Abstract

A cleansing composition is disclosed with household and personal care applications and comprises a monopersulfate oxidizing agent and a halide bleaching promoter, to which is added an effervescence promoting compound comprising a perborate salt. The resulting composition is operable and capable of effervescing at an alkaline pH, at which it is also a more effective cleanser.

In a further embodiment, the above cleansing composition may include a colorant and a fade control agent comprising a compound providing a soluble halide ion for applications where it is desirable that the color provided by the colorant will fade within a given period of time. Small quantities of the fade control compound are effective, and do not disturb the desired initial color intensity of the solution provided by the colorant.

Claims

1. An effervescent cleansing composition comprising:

(a) an oxidizing agent comprising a monopersulfate salt in an amount of from 35 to 60% by weight;

(b) a bleaching promoter comprising an alkali metal or alkaline earth metal chloride in an amount of 10% to 20% by weight;

(c) an effervescence promoting compound comprising a perborate salt, in an amount of from 0.5% to 20% by weight;

(d) sodium carbonate in an amount of from 20% to 40% by weight;

(e) sodium hydroxide in an amount of up to about 0.5% by weight;

(f) a colorant, comprising at least one food, drug and cosmetic grade, or drug and cosmetic grade dye or lake, in an amount of from about 0.15% to 0.5% by weight; and

,

(g) a fade control agent comprising a compound selected from the group consisting of alkali metal bromides, alkali metal iodides and mixtures thereof, in an amount of from 0.04% to 0.3% by weight to control the time in which the colorant disappears.

2. The composition of claim 1 wherein said fade control agent is present in an amount of from 0.04 to 0.18% by weight.

3. The composition of claim 1 wherein said fade control agent is selected from the group consisting of potassium bromide, potassium iodide and mixtures thereof.

4. The composition of claim 1 further including at least one material selected from the group consisting of builders, detergents, lubricants, sequestrants, perfumes, flavorings, excipients, tableting agents, disintegrants and mixtures thereof.

5. The composition of claim 4 wherein said builders include sodium carbonate and trisodium phosphate, and said sequestrants comprise ethylene diamine tetraacetic acid and its alkali metal salts.

6. The composition of claim 5 whrein said builders are present in an amount of up to 40% by weight, and said sequestrant is present in an amount of from 0.3 to 3.5% by weight.

7. A tablet useful as a denture cleanser comprising the composition of claim 4.

8. The tablet useful as a denture cleanser comprising the composition of claims 2, 5 or 6.

9. An effervescent cleansing composition consisting essentially of:

(a) an oxidizing agent comprising a monopersulfate salt in an amount of from 35% to 60% by weight;

(b) a bleaching promoter selected from the group consisting of alkali metal and alkaline earth metal chlorides, said bleaching promoter present in an amount of up to about 20% by weight;

(c) an effervescence promoting compound comprising a perborate salt, present in an amount of from 0.5 to 20% by weight;

(d) a colorant comprising at least one food, drug and cosmetic grade dye or lake, in an amount of from about 0.15 to 0.5% by weight;

(e) a fade control agent selected from the group consisting of the alkali metal bromides, alkali metal iodides, and mixtures thereof, in an amount of from 0.04 to 0.3% by weight; and

(f) said effervescence cleansing composition effervescing at an alkaline pH when placed in solution.

10. The composition of claim 9 wherein said fade control agent is selected from the group consisting of potassium bromide, potassium iodine and mixtures thereof.

11. The composition of claim 9 wherein said fade control agent is present in an amount of from about 0.04 to 0.18% by weight.

12. The composition of claim 10 wherein said fade control agent is present in an amount of from about 0.04 to 0.18% by weight.

13. The composition of claim 9 further including at least one material selected from the following:

builders, sequestrants, detergents, perfumes, flavorings, exipients, pH stabilizers, tableting agents, disintegrants, and mixtures thereof.

14. The composition of claim 13 wherein said builders are selected from the group consisting of alkali metal carbonates, alkali metal phosphates, and mixtures thereof;

said sequestrants comprise polyfunctional organic acids and their alkali metal salts; and

said pH stabilizers comprise sodium hydroxide.

15. The composition of claim 14 wherein said builders are selected from the group consisting of sodium carbonate, trisodium phosphate and mixtures thereof, and are present in a total amount ranging from 20 to 40% by weight;

said sequestrants comprise the alkali metal salts of ethylenediamine tetraacetic acid in an amount of from 0.3 to 3.5% by weight; and

said colorants are selected from food, drug and cosmetic grade dyes or lakes having the individual colors blue, red and green, and mixtures thereof.

16. A tablet useful as a denture cleanser comprising the composition of either of claims 9, 10, 11 or 12.