Metal-clad laminate and process for producing the same

• US 4,499,145 A
• Filed: 03/29/1983
• Issued: 02/12/1985
• Est. Priority Date: 04/19/1982
• Status: Expired due to Fees

• Current Assignee: Sumitomo Bakelite Company Limited
• Original Assignee: Sumitomo Bakelite Company Limited
• Inventors: Suzuki, Shigeru, Yanagida, Tomomi, Ajiki, Mitunori
• Primary Examiner(s): Ives, Patricia C.
• Application Number:
  US06/480,034
• Time in Patent Office: 686 Days
• Field of Search: 525/288, 525/342, 525/63, 525/64, 525/69, 428/418, 428/457, 428/901, 428/202, 428/209, 428/210, 428/336, 428/447, 428/910, 428/464, 428/419, 428/452, 428/513, 428/473.5, 428/521, 428/531, 156/330, 156/307.3, 156/332
• US Class Current: 428/418
• CPC Class Codes: B32B 15/08 of synthetic resin
• CPC Class Codes: B32B 15/085 comprising polyolefins
• CPC Class Codes: B32B 2305/18 Fabrics, textiles
• CPC Class Codes: B32B 2307/206 Insulating
• CPC Class Codes: B32B 2311/00 Metals, their alloys or their compounds
• CPC Class Codes: B32B 2317/12 Paper, e.g. cardboard
• CPC Class Codes: B32B 2323/04 Polyethylene
• CPC Class Codes: B32B 2371/00 Polyethers, e.g. PEEK, i.e. polyether-etherketone; PEK, i.e. polyetherketone
• CPC Class Codes: B32B 2457/00 Electrical equipment
• CPC Class Codes: B32B 27/10 of paper or cardboard
• CPC Class Codes: B32B 27/12 next to a fibrous or filamentary layer
• CPC Class Codes: B32B 27/285 comprising polyethers
• CPC Class Codes: B32B 27/286 comprising polysulphones; polysulfides
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 5/02 characterised by structural features of a fibrous or filamentary layer layer formed of metallic wires B32B15/02; layer formed of natural mineral fibres B32B19/02; layer formed of wood fibres B32B21/02
• CPC Class Codes: H05K 1/036 Multilayers with layers of different types
• CPC Class Codes: H05K 2201/0129 Thermoplastic polymer, e.g. auto-adhesive layer; Shaping of thermoplastic polymer
• CPC Class Codes: H05K 2201/0158 Polyalkene or polyolefin, e.g. polyethylene [PE], polypropylene [PP]
• CPC Class Codes: H05K 2201/0162 Silicon containing polymer, e.g. silicone
• CPC Class Codes: H05K 2201/0284 Paper, e.g. as reinforcement paper sheet substrates H05K1/0386
• CPC Class Codes: H05K 2201/0293 : Non-woven fibrous reinforcement
• CPC Class Codes: Y10S 428/901 : Printed circuit
• CPC Class Codes: Y10S 428/91 : Product with molecular orientation
• CPC Class Codes: Y10T 428/31529 : Next to metal
• CPC Class Codes: Y10T 428/31533 : Of polythioether
• CPC Class Codes: Y10T 428/31663 : As siloxane, silicone or silane
• CPC Class Codes: Y10T 428/31678 : Of metal
• CPC Class Codes: Y10T 428/31703 : Next to cellulosic
• CPC Class Codes: Y10T 428/31721 : Of polyimide
• CPC Class Codes: Y10T 428/31902 : Monoethylenically unsaturated
• CPC Class Codes: Y10T 428/31931 : Polyene monomer-containing
• CPC Class Codes: Y10T 428/31967 : Phenoplast

Abstract

A metal-clad laminate comprising a base plate composed of a plurality of electrically insulating material layers and a metal foil or foils laminated on one side or both sides of the base plate, characterized in that to at least the metal foil or foils is laminated an electrically insulating material layer composed of a silane-modified polyethylene resin sheet, that to the silane-modified polyethylene resin is laminated an electrically insulating material layer made of a paper or cloth containing an epoxy resin and/or a silanol condensation catalyst, and that the layer made of a paper or cloth contains 5 to 35% by weight of an epoxy resin and/or that to the layer made of a paper or cloth is laminated an electrically insulating material layer other than the above-mentioned two layers. Said metal-clad laminate has excellent characteristics such as low, ε, low tan δ and excellent moisture-resistant insulating property.

Claims

1. A metal-clad laminate comprising:

a base plate; and

a layer of metal foil on at least one side of said base plate;

said base plate including, in order, a first electrically insulating material layer composed of a cross-linked silane-modified polyethylene resin laminated to a layer of said metal foil, and a second electrically insulating material layer made of paper or cloth containing an epoxy resin, a silanol condensation catalyst or a mixture of said epoxy resin and said silanol condensation catalyst laminated to said first electrically insulating layer.

2. A metal-clad laminate according to claim 1, wherein the paper or cloth layer contains a silanol condensation catalyst.

3. A metal-clad laminate according to claim 2, wherein the silanol condensation catalyst is an organic tin compound.

4. A metal-clad laminate according to claim 3, wherein the silanol condensation catalyst is at least one member selected from dioctyltin malate, monobutyltin oxide, dibutyltin dilaurate, dibutyltin chloride and dibutyltin diacetate.

5. A metal-clad laminate according to claim 2, wherein the amount of the silanol condensation catalyst is 3 to 10% by weight based on the weight of the epoxy resin when the epoxy resin content of the paper or cloth layer is 15% by weight of more, and it is 0.5 to 2% by weight based on the weight of the paper or cloth in the layer when the epoxy resin content is less than 15% by weight.

6. A metal-clad laminate according to claim 1, wherein the paper or cloth layer contains an epoxy resin.

7. A metal-clad laminate according to claim 6, wherein the amount of the epoxy resin contained in the paper or cloth layer is 5 to 35% by weight based on the weight of the paper or cloth plus any other constituents of the layer.

8. A metal-clad laminate according to claim 6, wherein the amount of the epoxy resin contained in the paper or cloth layer is 10 to 30% by weight based on the weight of the paper or cloth plus any other constituents of the layer.

9. A metal-clad laminate according to claim 6, further comprising a third electrically insulating layer laminated to the paper or cloth, said third electrically insulating layer comprising a thermoplastic resin having a heat deformation temperature of 130°

C. or higher.

10. A metal-clad laminate according to claim 9, wherein the thermoplastic resin of said third electrically insulating layer is a polyethersulfone, a polysulfone, a polyphenylene sulfide, a polyetheretherketone, a polyphenylene oxide or a polyetherimide.

11. A metal-clad laminate according to claim 1, comprising layers laminated in the order of the metal foil, the cross-linked silane-modified polyethylene resin layer, the paper or cloth, a third cross-linked silane-modified polyethylene resin layer and a second layer of metal foil.

12. A metal-clad laminate according to claim 1, which has a metal foil on only one surface laminated to the base plate and has an electrically insulating layer made of a cross-linked silane-modified polyethylene resin on the other surface.

13. A process for producing a metal-clad laminate of claim 1, characterized by laminating a metal oil and at least the following electrically insulating materials and integrally forming them into one body by heating and pressing:

(a) a crosslinkable, silane-modified polyethylene sheet, and

(b) a paper or cloth containing an epoxy resin, a silanol condensation catalyst or a mixture thereof.

14. A process according to claim 13 , wherein the paper or cloth contains an epoxy resin and said epoxy resin comprises 10 to 40% by weight of a novolak type epoxy resin based on the total weight of the epoxy resin.