Open-cell/microporous molded article

• US 4,499,211 A
• Filed: 07/27/1982
• Issued: 02/12/1985
• Est. Priority Date: 07/28/1981
• Status: Expired due to Fees

• Current Assignee: Hoechst Aktiengesellschaft (Sanofi )
• Original Assignee: Hoechst Aktiengesellschaft (Sanofi )
• Inventors: Kuhls, Jurgen, Seifried, Walter, Walch, Axel, Michel, Wolfgang, Wildhardt, Jurgen
• Primary Examiner(s): Foelak, Morton
• Application Number:
  US06/402,266
• Time in Patent Office: 931 Days
• Field of Search: 210/500.2, 521/64, 521/61, 521/62, 521/145, 264/41
• US Class Current: 521/145
• CPC Class Codes: A61L 15/225 Mixtures of macromolecular compounds
• CPC Class Codes: A61L 15/425 Porous materials, e.g. foams or sponges
• CPC Class Codes: C08J 2201/0544 the non-solvent being aqueous
• CPC Class Codes: C08J 2327/12 containing fluorine atoms
• CPC Class Codes: C08J 2329/04 Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
• CPC Class Codes: C08J 9/28 by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
• CPC Class Codes: D01D 5/24 with a hollow structure; Spinnerette packs therefor D01D5/38 takes precedence; producing tubes of plastic material B29D; addition of agents forming hollow filaments D01F1/08
• CPC Class Codes: G01N 33/521 Single-layer analytical elements
• CPC Class Codes: G01N 33/545 Synthetic resin
• CPC Class Codes: G03C 1/795 the base being of macromolecular substances G03C1/775 takes precedence
• CPC Class Codes: G03G 7/0006 Cover layers for image-receiving members; Strippable coversheets
• CPC Class Codes: G03G 7/004 obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: G03G 7/006 Substrates for image-receiving members; Image-receiving members comprising only one layer
• CPC Class Codes: G03G 7/0073 Organic components thereof

Abstract

The present invention relates to molded articles of an open-cell structure, containing a copolymer which is comprised of copolymerized, fluorinated olefin, copolymerized vinyl acetate and optionally copolymerized olefin, the acetate groups of the copolymer being optionally saponified into OH groups. The molded articles possess an inherent latent structural convertibility and have effective pores of a diameter in the range from 0.002 to 10 μm. The invention further includes processes for the preparation of the specified molded articles and processes for converting their structure. The invention also relates to several uses of molded articles according to the invention.

Claims

1. A microporous molded article having an open-cell structure and comprising a thermoplastic material which possesses an inherent latent structural convertibility and includes effective pores of a diameter in the range from about 0.002 to 10 μ

m, said thermoplastic material comprising at least about 70 percent by weight of a terpolymer which is composed of from about 20 to 80 percent by weight, relative to the total weight of the terpolymer, of copolymerized fluorinated olefin selected from the group consisting of ethylene and propylene, up to about 40 percent by weight, relative to the total weight of the terpolymer, of copolymerized olefin selected from the group consisting of ethylene and propylene, and from about 80 to 20 percent by weight, relative to the total weight of the copolymer, of copolymerized vinyl acetate, with at least 5 percent of the total proportion of acetate groups contained in the copolymer being converted by saponification into OH groups after copolymerization of the specified comonomers to form the terpolymer.

2. A molded article according to claim 1, wherein said terpolymer comprises about 30 to 70 percent by weight, relative to its total weight, of copolymerized tetrafluoroethylene, from about up to 20 percent by weight of copolymerized ethylene, and from about 70 to 30 percent by weight, relative to the total weight of the terpolymer, of copolymerized vinyl acetate, with at least 5 percent of the acetate groups contained in the terpolymer being converted by saponification into OH groups after copolymerization of the specified comonomers to form the terpolymer.

3. A molded article according to claim 1 or 2, wherein more than about 80 percent of the acetate groups are converted by saponification into OH groups.

4. A molded article according to claim 1 or 2, which comprises the form of a film.

5. A molded article having an open-cell structure and comprising a thermoplastic material which possesses an inherent latent structural convertibility and includes effective pores of a diameter in the range from about 0.002 to 10 μ

m, said thermoplastic material comprising at least about 70 percent by weight of a copolymer which is composed of from about 20 to 80 percent by weight, relative to the total weight of the copolymer, of copolymerized perfluorinated olefin from the group consisting of ethylene and propylene, from about 0 to 40 percent by weight, relative to the total weight of the copolymer, of copolymerized olefin from the group consisting of ethylene and propylene and from about 80 and 20 percent by weight, relative to the total weight of the copolymer, of copolymerized vinyl acetate, with at least 5 percent of the total proportion of acetate groups contained in the copolymer being converted by saponification into OH groups after copolymerization of the specified comonomers to form the copolymer.