Process for the elimination of hydrogen sulfide or iron sulfide from an aqueous system

• US 4,501,668 A
• Filed: 12/06/1983
• Issued: 02/26/1985
• Est. Priority Date: 12/07/1982
• Status: Expired due to Fees

• Current Assignee: Degussa AG (Rag-Stiftung)
• Original Assignee: Degussa AG (Rag-Stiftung)
• Inventors: Merk, Wolfgang, Rink, Karl-Heinz
• Primary Examiner(s): HRUSKOCI, PETER A
• Application Number:
  US06/558,534
• Time in Patent Office: 448 Days
• Field of Search: 210/698, 210/631, 210/718, 210/732, 210/749, 210/750, 210/764, 210/916, 252/180, 252/388, 252/8.55 E, 422/5, 422/14, 423/243, 423/560, 423/563, 526/315
• US Class Current: 210/749
• CPC Class Codes: C02F 1/50 by addition or application of a germicide or by oligodynamic treatment C02F1/4606, C02F1/467, C02F1/76 take precedence
• CPC Class Codes: C02F 5/10 using organic substances
• CPC Class Codes: C09K 8/54 Compositions for in situ inhibition of corrosion in boreholes or wells
• CPC Class Codes: C23F 11/173 Macromolecular compounds
• CPC Class Codes: Y10S 210/916 Odor, e.g. including control or abatement
• CPC Class Codes: Y10S 507/939 Corrosion inhibitor

Abstract

There are employed water soluble low molecular weight polycondensation products produced by the condensation of acrolein and formaldehyde in a molar ratio between 1:1 and 1:10 in aqueous or aqueous-organic medium in the presence of a basic catalyst for the elimination of hydrogen sulfide and iron sulfide present in aqueous systems. The condensation reaction can also be carried out in the additional presence of water soluble monohydric or polyhydric alcohols and/or acid amides.

Claims

1. A process for the elimination of hydrogen sulfide, iron sulfide or a mixture of iron sulfide and hydrogen sulfide from an aqueous system comprising adding to the system an effective amount of a water soluble low molecular weight condensation product of acrolein and formaldehyde in the molar ratio of 1:

1 to 1;

10, said condensation product having been produced in the presence of a basic catalyst, to react with said hydrogen sulfide, said iron sulfide, or said mixture, and form an odor free aqueous solution.

2. A process according to claim 1 wherein the acrolein-formaldehyde condensation product is made from reactants consisting essentially of acrolein and formaldehyde.

3. A process according to claim 1 wherein the acrolein-formaldehyde condensation product is made from reactants consisting essentially of (1) acrolein, (2) formaldehyde and (3) an alcohol or an acid amide.

4. A process according to claim 3 wherein reactant (3) is a monohydric or polyhydric alcohol.

5. A process according to claim 4 wherein reactant 3 is allyl alcohol.

6. A process according to claim 3 wherein reactant 3 is a carboxylic acid amide.

7. A process according to claim 6 wherein the amide is formamide.

8. A process according to claim 1 wherein the molar ratio of acrolein to formaldehyde is from 1:

2 to 1;

4.

9. A process according to claim 8 wherein the molar ratio of acrolein to formaldehyde is 1:

4.

10. A process according to claim 9 wherein there is added between 5 and 500 ppm of the condensate to the aqueous system.

11. A process according to claim 8 wherein there is added between 5 and 500 ppm of the condensate to the aqueous system.

12. A process according to claim 1 wherein there is added between 1 and 2000 ppm of the condensate to the aqueous system.

13. A process according to claim 12 wherein there is added between 5 and 2000 ppm of the condensate to the aqueous system.

14. A process according to claim 13 wherein there is added between 5 and 500 ppm of the condensate to the aqueous system.

15. A process according to claim 13 wherein there is added between 1000 and 2000 ppm of the condensate to the aqueous system.

16. A process according to claim 15 including the further step of reducing the concentration of the condensate in the aqueous system to 5 to 500 ppm after an initial reduction in the amount of hydrogen sulfide present in the aqueous system.

17. A process according to claim 1 wherein the aqueous system is free from iron sulfide.

18. A process according to claim 1 wherein the aqueous system contains iron sulfide.