Composite containing polyolefin fiber and polyolefin polymer matrix

• US 4,501,856 A
• Filed: 03/19/1982
• Issued: 02/26/1985
• Est. Priority Date: 03/19/1982
• Status: Expired due to Term

• Current Assignee: Allied Chemical Corporation (Honeywell International Inc.)
• Original Assignee: Allied Corp. (Honeywell International Inc.)
• Inventors: Kavesh, Sheldon, Palley, Igor, Harpell, Gary A., Prevorsek, Dusan C.
• Primary Examiner(s): SECCURO JR, CARMAN J
• Application Number:
  US06/359,974
• Time in Patent Office: 1,075 Days
• Field of Search: 525/240
• US Class Current: 525/240
• CPC Class Codes: C08J 2323/02 not modified by chemical after treatment
• CPC Class Codes: C08J 5/04 Reinforcing macromolecular compounds with loose or coherent fibrous material
• CPC Class Codes: C08L 23/02 not modified by chemical after-treatment
• CPC Class Codes: Y10S 428/911 Penetration resistant layer
• CPC Class Codes: Y10T 428/249947 Polymeric fiber

Abstract

A composite containing a network of ultrahigh molecular weight polyethylene or polypropylene fibers of high tenacity and modulus and a matrix which has ethylene or propylene crystallinity, e.g. polyethylene, polypropylene or copolymers. The composite can be formed by heating the matrix to its melting or sticking temperature around the fibers. The composite retains a high proportion of the tenacity of the fiber.

Claims

1. A composite structure comprising:

(a) a network of polyolefin fibers selected from the group consisting of polyethylene and polypropylene fibers having a weight average molecular weight of at least about 500,000, a tenacity of at least about 15 g/denier and a main melting point of at least about 140°

C. for polyethylene fiber, and a tenacity of at least about 11 g/denier and a main melting point of at least about 168°

C. for polypropylene fiber; and

(b) a matrix comprising a polymer having polyethylene or polypropylene crystallinity with a melting or sticking point at least 3°

C. lower than the melting point of the polyolefin fiber;

said composite structure having a tenacity at least 75% of the volume average tenacity of the polyolefin fiber network and the polymer matrix.

2. The composite structure of claim 1 comprising between about 5 and about 99 weight % polyolefin fiber network and between about 1 and about 95 weight % polymer matrix.

3. The composite structure of claim 1 or 2 wherein said polyolefin fiber is polyethylene fiber.

4. The composite structure of claim 3 wherein said polymer matrix is an ethylene copolymer.

5. The composite structure of claim 3 wherein said polymer matrix is polyethylene polymer.

6. The composite structure of claim 5 wherein said polyethylene polymer has a specific gravity of 0.90-0.94.

7. The composite structure of claim 5 wherein said polyethylene polymer has a specific gravity of 0.94-0.98.

8. The composite structure of claim 5 wherein said polyethylene fiber has a main melting point at 10°

C./min between about 140°

C. and about 151°

C. and said polyethylene polymer has a melting point between about 108°

C. and about 126°

C.

9. The composite structure of claim 5 wherein said polyethylene polymer has a main melting point at 10°

C./min between about 126°

C. and about 136°

C.

10. The composite structure of claim 5 having a tensile strength at least 90% of the volume average tenacity of the polyethylene fiber network and the polyethylene polymer matrix.

11. The composite structure of claim 5 wherein said polyethylene fiber has a weight average molecular weight of at least about 1,000,000 a tenacity of at least about 25 g/denier and a tensile modulus of at least about 750 g/ denier.

12. The composite structure of claim 11 wherein said polyethylene fiber has a tenacity of at least about 30 g/denier and a tensile modulus of at least about 1000 g/denier.

13. The composite structure of claim 1 having about 0.1 to about 99 volume percent fiber network and about 99.9 to about 1 volume percent polymer matrix.

14. The composite structure of claim 13 having about 1 to about 95 volume percent fiber network.

15. The composite structure of claim 14 having about 40 to about 90 volume percent fiber network.