Encapsulated phase change thermal energy _storage materials

• US 4,504,402 A
• Filed: 05/14/1984
• Issued: 03/12/1985
• Est. Priority Date: 06/13/1983
• Status: Expired due to Term

• Current Assignee: Elf Atochem North America, Inc. (Totalenergies Se)
• Original Assignee: Pennwalt Corporation (Arkema)
• Inventors: Chen, Johnson C. H., Eichelberger, John L.
• Primary Examiner(s): Lusignan, Michael R.
• Application Number:
  US06/609,665
• Time in Patent Office: 302 Days
• Field of Search: 252/70, 427/3, 427/213, 427/214, 427/221, 428/403, 428/407, 428/304.4, 428/221, 428/402.24, 523/200, 523/207, 523/211, 523/210, 264/7, 165/53, 165/104.17
• US Class Current: 252/70
• CPC Class Codes: C09K 5/063 Materials absorbing or liberating heat during crystallisation; Heat storage materials
• CPC Class Codes: E04C 2/52 with special adaptations for auxiliary purposes, e.g. serving for locating conduits E04C2/54 takes precedence; block-shaped elements therefor E04C1/39; floor structures incorporating ducts E04B5/48
• CPC Class Codes: F24S 60/10 using latent heat
• CPC Class Codes: F28D 20/023 the latent heat storage material being enclosed in granular particles or dispersed in a porous, fibrous or cellular structure
• CPC Class Codes: Y02B 10/20 Solar thermal
• CPC Class Codes: Y02E 10/40 Solar thermal energy, e.g. solar towers
• CPC Class Codes: Y02E 60/14 Thermal energy storage
• CPC Class Codes: Y10T 428/2989 Microcapsule with solid core [includes liposome]
• CPC Class Codes: Y10T 428/2991 Coated
• CPC Class Codes: Y10T 428/2998 including synthetic resin or polymer

Abstract

A thermal energy storage composite pellet-shaped product of about 1/8 inch to 1 inch in size, formed of an outer seamless shell member which defines a cavity that permanently encases a phase-change composition, the composition being present in a quantity such that the total volume of the composition, whether in its solid form, liquid form, or both forms as in its transition state, never exceeds the volume of the cavity; and a process for making the product which includes using the phase-change composition in a compacted powder form as cast about which the shell member is formed by roll-coating steps.

Claims

1. A thermal energy storage composite product capable of incorporation within rigid building construction components without causing fracture or damage to the components or product after the product undergoes repeated thermal change cycles, said product comprising:

(a) an outer shell member having a longest dimension of from about 1/8 inch to about 1 inch and having interior surfaces defining only a single internal cavity that is adapted to permanently encase a thermal energy storage phase-change composition, said shell being comprised of at least one seamless layer of a wall-forming material that is substantially impermeable to and non-reactive with said phase-change composition or water, the total volume of the wall-forming material being from about 5% to 30% of the volume of said cavity; and

(b) a thermal energy storage phase-change composition permanently disposed within the single cavity of the shell, said phase-change composition being capable of exisiting in solid form, a melted liquid form, or a transition state that includes both the liquid and the solid forms, the composition being present in a quantity such that the total volume of composition whether in the solid form, the liquid form, or the transition state does not exceed the volume of the cavity.

2. The composite product as defined in claim 1 wherein the shell member of (a) is comprised of multiple seamless coatings of the wall-forming material.

3. The composite product as defined in claim 1 wherein the outer shell member of (a) has convex shaped outer surfaces with rounded edges.

4. The composite product as defined in claim 1 wherein the wall-forming material of (a) is a material selected from the group consisting of a copolymer latex of butadiene-acrylonitrile, a copolymer of vinylidene chloride-acrylic, resinous latexes, rubber latexes, epoxy polymers, polyurethane polymers, acrylic polymers, cellulose acetate and polyamides.

5. The composite product as defined in claim 1 wherein the interior surfaces of shell member of (a) are coated with a primer substance.

6. The product as defined in claim 5 wherein the primer coating is a water-resistant primer substance.

7. The product as defined in claim 6 wherein the water-resistant primer coating is comprised of asphalt or acrylic polymer.

8. The product as defined in claim 5 wherein the primer coating is present in a volumetric amount that is less than about 5% of the volume of the cavity.

9. The product as defined in claim 2 wherein mica is dispersed onto at least one of the coatings comprising the shell member.

10. The product as defined in claim 1 wherein the thermal energy phase-change composition of (b) has a liquid density that is at least 85% but less than 100% of the solid density of the composition.

11. The product as defined in claim 1 wherein the thermal energy phase-change composition of (b) has a phase change transition temperature within the range of about 7°

C. to about 90°

C.

12. The product as defined in claim 1 wherein the thermal energy phase-change composition of (b) is selected from the group consisting of a Glauber salt eutectic mixture, sodium hydroxide, polyethylene, sodium sulfate decahydrate, sodium thiosulfate pentahydrate, calcium chloride hexahydrate, magnesium nitrate hexahydrate, the eutectic of magnesium nitrate hexahydrate and ammonium nitrate, potassium fluoride tetrahydrate, sodium acetate trihydrate, stearic acid, the eutectic of naphthalene and benzoic acid and paraffinic hydrocarbons.