Electrically conductive rigid polyurethane foam

• US 4,505,973 A
• Filed: 12/08/1983
• Issued: 03/19/1985
• Est. Priority Date: 12/08/1983
• Status: Expired due to Fees

• Current Assignee: The United States of America As Represented By The Secretary of Agriculture
• Original Assignee: United States Department of Energy
• Inventors: Neet, Thomas E., Spieker, David A.
• Primary Examiner(s): Cockeram, Herbert S.
• Application Number:
  US06/559,502
• Time in Patent Office: 467 Days
• Field of Search: 252/511, 521/99, 428/68, 428/76, 428/304.4, 428/314.4, 428/317.9
• US Class Current: 428/317.9
• CPC Class Codes: C08K 3/04 Carbon
• CPC Class Codes: C08L 75/04 Polyurethanes
• CPC Class Codes: H01B 1/24 the conductive material comprising carbon-silicon compounds, carbon or silicon
• CPC Class Codes: Y10T 428/23 Sheet including cover or casing
• CPC Class Codes: Y10T 428/239 Complete cover or casing
• CPC Class Codes: Y10T 428/249953 Composite having voids in a component [e.g., porous, cellular, etc.]
• CPC Class Codes: Y10T 428/249976 Voids specified as closed
• CPC Class Codes: Y10T 428/249986 Void-containing component contains also a solid fiber or solid particle

Abstract

A rigid, polyurethane foam comprises about 2-10 weight percent, based on the total foam weight, of a carbon black which is CONDUCTEX CC-40-220 or CONDUCTEX SC, whereby the rigid polyurethane foam is electrically conductive and has essentially the same mechanical properties as the same foam without carbon black added.

Claims

1. In a rigid, polyurethane foam, the improvement wherein the foam further comprises about 2-10 weight percent, based on the total foam weight, of a carbon black which has a ratio of nitrogen-determined surface area to CTAB-determined surface area of about 1.5-3 and a particle size distribution wherein at least 90 weight percent of the particles are of a size of 10-30 μ

m, whereby the rigid polyurethane foam is electrically conductive and has essentially the same mechanical properties as the same foam without carbon black added and wherein the rigid polyurethane foam has a density of greater than about 10 lb/ft³.

2. A rigid polyurethane foam of claim 1, wherein the amount of carbon black is about 5 weight percent.

3. A rigid polyurethane foam of claim 1, wherein the carbon black has a nitrogen to CTAB surface area ratio of about 2.1, and a particle diameter of 18 μ

m.

4. A rigid polyurethane foam of claim 2, wherein the carbon black has a nitrogen to CTAB surface area ratio of about 2.1, and a particle diameter of 18 μ

m.

5. A rigid polyurethane foam of claim 1, wherein the foam has a density of about 10-35 lb/ft³.

6. A rigid polyurethane foam of claim 1, wherein said ratio of surface areas is 1.5-2.

7. A rigid polyurethane foam of claim 1, wherein at least 90 weight percent of said particles are of a size of 10-20 μ

m.

8. A rigid polyurethane foam of claim 2, wherein said ratio of surface areas is 1.5-2.

9. A rigid polyurethane foam of claim 2, wherein at least 90 weight percent of said particles are of a size of 10-20 μ

m.

10. A rigid polyurethane foam of claim 6, wherein at least 90 weight percent of said particles are of a size of 10-20 μ

m.

11. A rigid polyurethane foam of claim 1, which has been prepared by mixing a portion of the total amount of carbon black to be included in the polyurethane, with the isocyanate component used to prepare the polyurethane, mixing the remaining portion of the total amount of carbon black with the resin prepolymer component used to prepare the polyurethane, and then reacting the two components to prepare a rigid polyurethane foam.

12. In an electrical component surrounded by a rigid polyurethane foam, the improvement wherein said foam is the electrically conductive rigid polyurethane foam of claim 1.

13. A method of protecting an electrical component from the effects of static charge buildup, comprising surrounding the electrical component with the rigid polyurethane foam of claim 1.