Ion concentration monitor

• US 4,506,226 A
• Filed: 05/19/1982
• Issued: 03/19/1985
• Est. Priority Date: 05/19/1982
• Status: Expired due to Fees

• Current Assignee: Lockheed Martin Space Operations Company (Martin Marietta Corporation)
• Original Assignee: Lockheed Missiles and Space Co Inc (Martin Marietta Corporation)
• Inventors: Luce, Robert S., Quinn, Ross A.
• Primary Examiner(s): Tokar, Michael J.
• Assistant Examiner(s): O'Shea, Kevin D.
• Application Number:
  US06/379,650
• Time in Patent Office: 1,035 Days
• Field of Search: 324/438, 324/450, 324/459, 324/425, 324/434, 324/444, 324/449, 324/71.1, 324/439, 204/406, 204/412, 204/416
• US Class Current: 324/459
• CPC Class Codes: G01N 27/27 Association of two or more measuring systems or cells, each measuring a different parameter, where the measurement results may be either used independently, the systems or cells being physically associated, or combined to produce a value for a further parameter

Abstract

An apparatus for monitoring ion concentrations in an aqueous solution comprises a plurality of electrodes insertable into the solution. At least two of the electrodes are ion-selective for particular ions. Each ion-selective electrode is electrically connected to a corresponding impedance buffer, which generates a low-impedance output signal having the same voltage as the electode. A plurality of operational amplifiers in full differential configuration is provided, each operational amplifier receiving a particular pair of output signals generated by the impedance buffers. Each differential amplifier generates an output signal indicating the potential difference between the impedance buffer output signals received as inputs by the differential amplifier.

Claims

1. An apparatus for simultaneously monitoring ion concentrations for a plurality of different ions in an aqueous solution, said apparatus comprising:

(a) at least three electrodes insertable into said solution, at least two of said electrodes being ion-selective for particular ions;

(b) at least three electrical impedance bufers, each one of said electrodes being electrically connected to a corresponding one of said electrical impedance buffers, each electrical impedance buffer generating an electrical signal indicative of electrical potential on the electrode to which the corresponding impedance buffer is connected; and

(c) a plurality of operational amplifiers disposed in full differential configuration, each differential operational amplifier being connected to receive inputs from a corresponding pair of said impedance buffers, each differential operational amplifier generating a signal indicative of electrical potential difference between a corresponding pair of said electrodes so that the electical potential difference between any pair of ion-selective electrodes can be monitored, all of said differential operational amplifiers generating said signals simultaneously.

2. The ion concentration monitoring apparatus of claim 1 wherein one of said electrodes is a reference junction electrode.

3. The ion concentration monitoring apparatus of claim 1 wherein each of said fimpedance buffers is configured as a high-input impedance, unity gain voltage follower.

4. The ion concentration monitoring apparatus of claim 1 wherein each of said differential operational amplifiers is configured by means of external resistors as a full differential, unity gain amplifier.

5. The ion concentration monitoring apparatus of claim 1 wherein a corresponding isolation amplifier module is electrically connected between each impedance buffer and the differential operational amplifiers receiving the output of the impedance buffer.

6. The ion concentration monitoring apparatus of claim 1 further comprising a chemically inert metallic structure insertable into said solution and connectable to signal ground.