Gas sensor and method of using same

• US 4,508,598 A
• Filed: 09/30/1982
• Issued: 04/02/1985
• Est. Priority Date: 05/11/1982
• Status: Expired due to Term

• Current Assignee: Giner Electrochemical Systems, LLC (Ener1, Inc.)
• Original Assignee: Giner, Inc.
• Inventors: Giner, Jose D.
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): Boggs, Jr., B. J.
• Application Number:
  US06/430,688
• Time in Patent Office: 915 Days
• Field of Search: 204/1 T, 204/1 K, 204/1 P, 204/1 Y, 204/400, 204/402, 204/406, 204/407, 204/412, 204/431, 204/433, 204/1 F, 204/1 N, 128/635
• US Class Current: 205/782.5
• CPC Class Codes: G01N 27/49 Systems involving the determination of the current at a single specific value, or small range of values, of applied voltage for producing selective measurement of one or more particular ionic species

Abstract

An electrochemical sensor capable of determining the partial pressure of various gases (e.g., CO, CO₂, H₂ S, alcohol vapors, hydrocarbons, NO_x, etc.) and, optionally, substantially concurrently, but independently, oxygen content in gases and liquids. The sensor measures the amount of chemisorbent species formed either electrochemically by partial reduction (such as "Reduced-CO₂ " in the case of CO₂) or partial oxidation (in the case of alcohol) or non-electrochemically via specific adsorption (in the case of CO and hydrocarbons) on platinum or other metals. The charge required to oxidize this chemisorbed species is proportional to the amount of adsorbate on the electrode surface which is made a reproducible and reliable function of the partial pressure of the gas to be measured. By the proper selection of the sensor construction and electrical parameters, high sensitivity, fast response time, and high selectivity can be obtained.

Claims

1. Method of quantitatively determining gas concentration in a fluid by (A) transforming gas from the fluid onto an electrode surface in contact with electrolyte as an adsorbed species;

and (B) electrochemically determining quantitatively the amount of said adsorbed species.

2. The method of claim 1 wherein the electrode includes a platinum group metal or gold.

3. The method of claim 2 including an electrode cleaning step.

4. The method of claim 2 wherein steps (A) and (B) are potentiostatically controlled and the current flowing during step (B) is integrated.

5. The method of claim 4 including step (C) for substantially concurrently and independently measuring the oxygen content of the fluid.

6. The method of claim 1 wherein steps (A) and (B) are potentiostatically and galvanostatically controlled, respectively, and the current of step (B) is integrated.

7. The method of claim 6 including a step (C) for substantially concurrently and independently measuring the oxygen content of the fluid.

8. The method of claim 2 wherein steps (A) and (B) are galvanostatically controlled.

9. The method of claim 8 including a step (C) for substantially concurrently and independently measuring the oxygen content.

10. The method of claim 2 wherein step (A) occurs at controlled potential and step (B) occurs at open circuit potential, and the open circuit potential is measured and related to amount of the adsorbed species formed.

11. The method of claim 2 wherein step (A) occurs at constant current and step (B) occurs at open circuit potential, and the open circuit potential is measured and related to amount of adsorbed species formed.

12. Method of claim 1 wherein the amount of gas transformed into the adsorbed species is determined by the diffusion of gas from the fluid bulk to the electrode surface.

13. The method of claim 12 wherein the diffusion is controlled by using an adsorption step of predetermined duration.

14. The method of claim 1 wherein said gas is carbon dioxide.

15. The method of claim 1 wherein said gas is carbon monoxide.

16. The method of claim 1 wherein said gas is hydrogen sulfide.

17. The method of claim 12 wherein said diffusion of gas from the fluid bulk to the electrode surface is through a hydrophobic membrane.