Extruded carpet backing with resin and elastomer components

• US 4,508,771 A
• Filed: 11/19/1979
• Issued: 04/02/1985
• Est. Priority Date: 11/19/1979
• Status: Expired due to Term

• Current Assignee: Advanced Elastomer Systems, L.P. (Exxon Mobil Corporation)
• Original Assignee: Collins & Aikman Holdings SA de CV, Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Puydak, Robert C., Peoples, Clarence Jr., Jansen, Deborah S.
• Primary Examiner(s): McCamish, Marion E.
• Application Number:
  US06/095,565
• Time in Patent Office: 1,961 Days
• Field of Search: 428/95, 428/96, 428/97, 156/72
• US Class Current: 428/95
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/28 Non-macromolecular organic substances
• CPC Class Codes: C08L 2666/54 Inorganic substances
• CPC Class Codes: C09D 123/08 Copolymers of ethene C09D123/16 takes precedence
• CPC Class Codes: Y10T 428/23979 Particular backing structure or composition
• CPC Class Codes: Y10T 428/23986 With coating, impregnation, or bond
• CPC Class Codes: Y10T 428/23993 Composition of pile or adhesive

Abstract

Highly flexible compositions of matter useful in the preparation of carpet backing are disclosed comprising thermoplastic resin compositions including copolymers of ethylene and unsaturated esters of lower carboxylic acids, such as vinyl esters and/or lower alkyl acrylates, in admixture with olefinic elastomers and substantial amounts of filler. The preferred thermoplastic resins employed include the copolymers of ethylene and vinyl acetate, and the preferred olefinic elastomers disclosed are ethylene copolymer elastomers, such as copolymers of ethylene and propylene, as well as terpolymers of ethylene, propylene and a diene, and the compositions preferably include a stearate or stearic acid and a hydrocarbon oil component. Carpet constructions are also disclosed comprising a plurality of carpet fibers and a thermoplastic barrier coating comprising the above combination of a thermoplastic resin, an olefinic elastomer and a substantial portion of filler material. Preferably a thermoplastic adhesive pre-coat layer is employed to bind the fibers together, and this is employed with a tufted carpet to adhere the carpet tufts to a woven or non-woven carpet scrim. These carpet constructions are preferably utilized in automotive carpeting applications. Methods for preparing said carpet constructions are also disclosed, comprising preparing the above thermoplastic barrier coating, applying (preferably by extrusion) an adhesive precoat to the surface of the carpet fibers so as to bind the fibers securely together, and applying the barrier coating so as to provide a strong and highly flexible carpet construction.

Claims

1. A composition of matter useful in the preparation of a thermoplastic acoustical and thermal barrier for carpet backing having improved flexibility as measured with the Tinius Olsen stiffness test, such composition being extrudable and comprising from 10 up to about 25 weight percent of a thermoplastic resin component comprising a copolymer of ethylene and an unsaturated ester of a lower carboxylic acid, from about 4 to about 15 weight percent of an olefinic elastomer component, and from about 60 to about 85 weight percent of a filler component.

2. The composition of matter of claim 1 wherein said olefinic elastomer component comprises an ethylene copolymer elastomer.

3. The composition of matter of claim 2, wherein said olefinic elastomer component comprises a copolymer of ethylene and propylene.

4. The composition of matter of claim 2, wherein said olefinic elastomer component comprises a terpolymer of ethylene, propylene and a non-conjugated diene.

5. The composition of matter of claim 1 wherein said olefinic elastomer component is selected from the group consisting of polyisobutylene, and isoprene copolymer elastomers.

6. The composition of matter of claim 1, including from about 4 to about 10 weight percent of said olefinic elastomer component, from about 15 to about 25 weight percent of said thermoplastic resin component, and from about 60 to about 75 weight percent of said filler component.

7. The composition of matter of claim 1, wherein said filler component comprises an inorganic filler selected from the group consisting of barium sulphate, and calcium carbonate.

8. The composition of matter of claim 1, wherein said unsaturated ester of a lower carboxylic acid is selected from the group consisting of vinyl esters and alkyl acrylates.

9. The composition of matter of claim 8, wherein said vinyl ester comprises vinyl acetate.

10. The composition of matter of claim 1, wherein said thermoplastic resin component comprises a copolymer of ethylene and vinyl acetate including from about 8 to about 30 weight percent of said vinyl acetate.

11. The composition of matter of claim 1, wherein said thermoplastic resin component has a melt index of between about 2.5 and about 50.

12. The composition of matter of claim 11, wherein said thermoplastic resin component comprises a mixture of copolymers of ethylene and unsaturated esters of lower carboxylic acids.

13. The composition of matter of claim 12, wherein said mixture of copolymers comprises a first copolymer having a melt index of between about 1.5 and about 2.5 and a second copolymer having a melt index of between about 150 and about 160.

14. The composition of matter of claim 1, including an additive selected from the group consisting of stearic acid and stearates.

15. The composition of matter of claim 14, including from about 0.25 to about 20 weight percent of said additive.

16. The composition of matter of claim 1, including a hydrocarbon oil.

17. The composition of matter of claim 16 wherein said hydrocarbon oil component is selected from the group consisting of paraffinic and naphthenic oils.

18. The composition of matter of claim 16 comprising between about 2 and about 10 weight percent of said hydrocarbon oil component.

19. A composition of matter useful in the preparation of a thermoplastic acoustical and thermal barrier for carpet backing having improved flexibility as measured with the Tinius Olsen stiffness test, such composition being extrudable and comprising from about 4 to about 15 weight percent of an olefinic elastomer component, from about 60 to about 85 weight percent of a filler component, and a thermoplastic resin component comprising a copolymer of ethylene and an unsaturated ester of a lower carboxylic acid.

20. The composition of matter of claim 19 wherein said olefinic elastomer component comprises an ethylene copolymer elastomer.

21. The composition of matter of claim 20, wherein said olefinic elastomer component comprises a copolymer of ethylene and propylene.

22. The composition of matter of claim 19, wherein said filler component comprises an inorganic filler selected from the group consisting of barium sulphate, and calcium carbonate.

23. The composition of matter of claim 19, including an additive selected from the group consisting of stearic acid and stearates.

24. The composition of matter of claim 19, including a hydrocarbon oil.

25. The composition of matter of claim 24 wherein said hydrocarbon oil component is selected from the group consisting of paraffinic and naphthenic oils.

26. The composition of matter of claim 24 comprising between about 2 and about 10 weight percent of said hydrocarbon oil component.

27. A thermoplastic composition useful as a backing material for carpeting, said thermoplastic composition consisting of by weight:

(a) About 10-25 percent of an ethylene containing polymer which is an ethylene/monounsaturated ester copolymer having a melt index of about 2.5 to 50

(b) About 4-15 percent of a non-vulcanized elastomer having a Mooney viscosity of about 25-80, which is a polyisobutylene, butyl rubber, a copolymer of ethylene and propylene or a terpolymer of ethylene, propylene and a minor amount of a diene monomer or mixtures thereof, and the diene is selected from the class consisting of 1,4-hexadiene, dicyclopenatdiene, methylenenorbornene, ethylenenorbornene, tetrahydroindene, 5-methylene-2-norbornene, 5-ethylidene norbornene, and 4-7-8-9-tetrahydroindene,

(c) About 60-85 percent of an inert mineral filler, and

(d) About 1-15 percent of a plasticizer for the ethylene containing polymer comprising a hydrocarbon oil.

28. A composition as claimed in claim 27 wherein said filler is calcium carbonate or barium sulfate.

29. A composition as claimed in claim 27 wherein said ethylene containing polymer is an ethylene/mono-unsaturated ester copolymer.

30. A composition as claimed in claim 29 in which the ethylene/mono-unsaturated ester copolymer is selected from the group consisting of vinyl esters and alkyl acrylates.

31. A composition as claimed in claim 30 wherein said ethylene/mono-unsaturated ester copolymer contains 70-92 percent ethylene and 30-8 percent of a comonomer selected from the group consisting of alkyl acrylate and vinyl acetate.

32. The composition as claimed in claim 27 wherein said plasticizer is a hydrocarbon oil.

33. A carpet construction comprising a plurality of carpet fibers, and an extrudable thermoplastic acoustical and thermal barrier comprising from 10 up to about 25 weight percent of a thermoplastic resin component comprising a copolymer of ethylene and an unsaturated ester of a lower carboxylic acid, from about 4 to about 15 weight percent of an olefinic elastomer component, and from about 60 to about 85 weight percent of a filler component.

34. The carpet construction of claim 33 wherein said plurality of fibers are in the form of carpet tufts, and including scrim means for retaining said carpet tufts.

35. The carpet construction of claim 33 including a thermoplastic adhesive pre-coat to securely bind said fibers.

36. The carpet construction of claim 35 wherein said thermoplastic adhesive pre-coat has a melt viscosity at 375°

F. of about 4,000 to about 35,000 CPS.

37. The carpet construction of claim 36 wherein said thermoplastic adhesive pre-coat comprises a copolymer of ethylene with a vinyl ester of a lower aliphatic carboxylic acid.

38. The carpet construction of claim 33, including a textile pad affixed to said thermoplastic barrier coating.

39. The carpet construction of claim 33, wherein said thermoplastic resin component comprises a copolymer of ethylene and vinyl acetate.

40. The carpet construction of claim 39, wherein said copolymer of ethylene and vinyl acetate comprises between about 8 and about 30 weight percent of said vinyl acetate.

41. The carpet construction of claim 33 comprising between about 15 and about 25 weight percent of said thermoplastic resin component, from about 4 to about 10 weight percent of said olefinic elastomer component, and from about 60 to about 75 weight percent of said filler component.

42. The carpet construction of claim 33, wherein said olefinic elastomer component comprises an ethylene copolymer elastomer.

43. The carpet construction of claim 42 wherein said ethylene copolymer elastomer comprises a copolymer of ethylene and propylene.

44. The carpet construction of claim 33 wherein said copolymer of ethylene and propylene comprises between about 55 and about 70 weight percent ethylene.

45. The carpet construction of claim 33 wherein said thermoplastic barrier coating includes up to about 20 weight percent of scrim scrap carpet composition therein.

46. The carpet construction of claim 33, wherein said thermoplastic barrier coating includes between about 0.25 and about 2.0 weight percent of an additive selected from the group consisting of stearic acid and stearates.

47. The carpet construction of claim 33, wherein said thermoplastic barrier coating includes between about 2 and about 10 weight percent of a hydrocarbon oil component.

48. A tufted automotive carpet comprising a base fabric stitched with erect loops of yarn to form tufts on the top side of the base fabric and a thermoplastic backing composition on the bottom side of said base fabric, said composition comprising by weight:

(a) About 10-25 percent of an ethylene containing polymer comprising an ethylene/mono-unsaturated ester copolymer,

(b) About 4-15 percent of a non-vulcanized elastomeric resin,

(c) About 60-85 percent of an inert mineral filler, and

(d) About 2-10 percent of a plasticizer.

50. A tufted automotive carpet as claimed in claims 48 or 49 wherein said non-vulcanized elastomeric resin is a copolymer of ethylene and propylene or a terpolymer of ethylene, propylene and a minor amount of diene or other termonomer, said mono-saturated ester being selected from the group consisting of vinyl esters and alkyl acrylates.

51. A tufted automotive carpet as claimed in claims 48 or 49 wherein there is a layer of precoat composition between said thermoplastic backing composition and said base fabric, the precoat composition having a lower viscosity than said backing composition and containing a copolymer of ethylene and a vinyl ester of a lower aliphatic carboxylic acid.

49. A tufted automotive carpet comprising a base fabric stitched with erect loops of yarn to form tufts on the top side of the base fabric and a thermoplastic backing composition on the bottom side of said base fabric, said composition comprising by weight:

(a) About 10-25 percent of an ethylene containing polymer comprising an ethylene/mono-unsaturated ester copolymer,

(b) About 4-10 percent of a non-vulcanized elastomeric resin,

(c) About 60-85 percent of an inert mineral filler, and

(d) About 2-10 percent of a plasticizer.

52. A method for producing a carpet construction comprising providing a plurality of carpet fibers, preparing a thermoplastic barrier comprising from 10 up to about 25 weight percent of a thermoplastic resin component comprising a copolymer of ethylene and an unsaturated ester of a lower carboxylic acid, from about 4 to about 15 weight percent of an olefinic elastomer component, and from about 60 to about 85 weight percent of a filler component, and extruding said thermoplastic barrier for application onto said carpet fibers so as to securely bind said carpet fibers together and to provide an acoustical and thermal barrier therefore.

53. The method of claim 52 including providing said carpet fibers in the form of carpet tufts, and affixing said carpet tufts to a carpet scrim prior to applying said thermoplastic barrier coating thereto.

54. The method of claim 53 including applying a thermoplastic adhesive pre-coat to said carpet fibers prior to applying said thermoplastic barrier coating thereto.

55. The method of claim 53 wherein said thermoplastic adhesive pre-coat comprises a copolymer of ethylene with a vinyl ester of a lower aliphatic carboxylic acid.

56. The method of claim 52 including applying a textile pad to the surface of said thermoplastic barrier coating opposite from said carpet fibers.

57. The method of claim 56 including molding said carpet construction including said textile pad into a desired shape by the application of heat and pressure thereto.

58. The method of claim 57 wherein said molding is carried out at a temperature of between about 45°

and 150°

C.

59. The method of claim 52 wherein said thermoplastic barrier includes a hydrocarbon oil.

60. The method of claim 59 wherein said hydrocarbon oil is selected from the group consisting of paraffinic and naphthenic oils.

61. The method of claim 59 wherein said hydrocarbon oil is present in an amount of from about 2 to about 10 weight percent.

62. In a process for preparing a molded automotive carpet comprising forming a tufted structure of a base fabric stitched with closely spaced tufts of yarn, applying a thermoplastic composition to the bottom side of the tufted structure and molding the resulting product to the desired contour, the improvement of using a thermoplastic composition comprising by weight:

(a) About 10-25 percent of an ethylene containing polymer comprising an ethylene/mono-unsaturated ester copolymer,

(b) About 4-15 percent of a non-vulcanized elastomeric resin,

(c) About 60-85 percent of an inert mineral filler, and

(d) About 2-10 percent of a plasticizer.

63. In a process for preparing a molded automotive carpet comprising forming a tufted structure of a base fabric stitched with closely spaced tufts of yarn, applying a thermoplastic composition to the bottom side of the tufted structure and molding the resulting product to the desired contour, the improvement of using a thermoplastic composition comprising by weight:

(a) About 10-25 percent of an ethylene containing polymer comprising an ethylene/mono-unsaturated ester copolymer,

(b) About 4-10 percent of a non-vulcanized elastomeric resin,

(c) About 60-85 percent of an inert mineral filler, and

(d) About 2-10 percent of a plasticizer.