Filter sheet material

• US 4,510,193 A
• Filed: 05/20/1983
• Issued: 04/09/1985
• Est. Priority Date: 02/09/1983
• Status: Expired due to Term

• Current Assignee: Ernest D.E. Ruiter, Hasso Von Blucher, Hubert Blucher
• Original Assignee: Ernest D.E. Ruiter, Hasso Von Blucher, Hubert Blucher
• Inventors: von Blucher, Hasso, de Ruiter, Ernest, Blucher, Hubert
• Primary Examiner(s): Herbert, Thomas J.
• Application Number:
  US06/496,742
• Time in Patent Office: 690 Days
• Field of Search: 428/196, 428/198, 428/144, 428/244, 428/215, 428/290, 428/341, 428/911
• US Class Current: 428/196
• CPC Class Codes: A62D 5/00 Composition of materials for coverings or clothing affording protection against harmful chemical agents
• CPC Class Codes: B01D 2239/0407 comprising particulate additives, e.g. adsorbents
• CPC Class Codes: B01D 2239/0457 Specific fire retardant or heat resistant properties
• CPC Class Codes: B01D 2239/0464 Impregnants
• CPC Class Codes: B01D 2239/0478 on a layer of the filter
• CPC Class Codes: B01D 2239/0492 on fibres
• CPC Class Codes: B01D 2239/065 More than one layer present in the filtering material
• CPC Class Codes: B01D 2239/1241 Particle diameter
• CPC Class Codes: B01D 2239/1291 Other parameters
• CPC Class Codes: B01D 39/083 of organic material
• CPC Class Codes: B01D 46/10 Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces
• CPC Class Codes: C01B 32/33 from distillation residues of coal or petroleum; from petroleum acid sludge
• CPC Class Codes: C01B 32/336 characterised by gaseous activating agents
• CPC Class Codes: C01B 32/384 Granulation
• CPC Class Codes: Y10S 428/911 Penetration resistant layer
• CPC Class Codes: Y10T 428/2481 including layer of mechanically interengaged strands, strand-portions or strand-like strips
• CPC Class Codes: Y10T 428/24826 Spot bonds connect components
• CPC Class Codes: Y10T 428/24967 Absolute thicknesses specified
• CPC Class Codes: Y10T 428/273 of coating

Abstract

A filter sheet material consisting of an air-permeable, pliable, especially textile support which is covered only partially with a uniformly distributed adhesive on which adsorber particles, especially active carbon beads, are fixed and the use of such filter materials containing active carbon as adsorbent for protective suits.

Claims

1. A filter sheet material comprising an air-permeable textile material, an adhesive uniformly covering about 20 to 80% of the surface of the textile, the applied adhesive having a height of about 0.05 to 0.5 mm and a diameter or width of about 0.1 to 5 mm, and about 10 to 250 g/m² of activated carbon adsorber particles anchored to the textile by the adhesive, the carbon particles having an internal surface of at least about 600 m² /g and a diameter of at least about 0.1 mm.

2. A filter sheet material according to claim 1, wherein the adhesive is polyurethane and is cross-linked after anchoring of the carbon particles.

3. A filter sheet material according to claim 1, wherein the adhesive is applied only to the fabric prominences.

4. A filter sheet material according to claim 1, wherein the adhesive is printed onto the support material.

5. A filter sheet material according to claim 1, wherein the adhesive is in dot form, the dots of adhesive having the shape of a hemisphere or the form of a cone.

6. A filter sheet material according to claim 1, wherein the adsorber beads are jacketed in a material that is permeable to chemical warfare agents and which protects the adsorbent agent against external influences.

7. A filter sheet material according to claim 1, including a flameproofing agent within the adhesive and thereby making entire filter sheet material resistant to flame.

8. A filter sheet material according to claim 1, including a blowing agent within the adhesive.

9. A filter sheet material according to claim 1, including encapsulated enzymes affixed on the applied adhesive.

10. A filter sheet material according to claim 1, including encapsulated enzymes adhered by an adhesive to the other side of the pliable support.

11. A protective garment formed at least in part of a filter sheet material in accordance with claim 1.

12. A filter sheet material according to claim 1, wherein the adsorber particles are active carbon beads of an internal surface of about 600 to 1500 m² /g and have a diameter of about 0.1 to 1 mm.

13. A filter sheet material according to claim 12, wherein the active carbon beads are obtained by heating an organic cation ion exchanger.

14. A filter sheet material according to claim 12, wherein the active carbon beads are made from bitumen.

15. A filter sheet material according to claim 14, wherein the bitumen is dispersed above its melting point in a liquid which is immiscible or only poorly miscible therewith, and then chilled, whereupon bitumen beads separate from the liquid, the beads are extracted with solvent for the removal of sticky components, impregnated with sulfuric acid, heated to at least 600°

C. to produce carbonized carbon beads, and then activating the beads in known manner.

16. A filter sheet material according to claim 14, wherein molten bitumen is sprayed in an inert gas to form droplets and heated at about 800°

to 1600°

C., whereupon carbonized carbon beads are obtained, and the beads are then activated in known manner.