Anode for electrolytic processes

• US 4,511,442 A
• Filed: 05/15/1984
• Issued: 04/16/1985
• Est. Priority Date: 03/26/1982
• Status: Expired due to Term

• Current Assignee: Oronzio de NORA Impianti Elettrochimici SPA (Industrie De Nora S.p.A)
• Original Assignee: Oronzio de NORA Impianti Elettrochimici SPA (Industrie De Nora S.p.A)
• Inventors: Pellegri, Alberto
• Primary Examiner(s): Andrews, R. L.
• Application Number:
  US06/609,536
• Time in Patent Office: 336 Days
• Field of Search: 204/98, 204/128, 204/129, 204/294
• US Class Current: 205/501
• CPC Class Codes: C25B 11/043 Carbon, e.g. diamond or graphene
• CPC Class Codes: C25B 11/069 consisting of at least one single element and at least one compound; consisting of two or more compounds
• CPC Class Codes: C25B 11/095 at least one of the compounds being organic

Abstract

Anodes having a substantially impermeable coating or surface, obtained by moulding under pressure and heat an electrocatalytic layer consisting of a mixture of powders of an electrocatalytic material and inert thermoplastic resin on a conductive body or substrate, consisting of a mixture of powders of graphite and inert resin, resist surprisingly well to the electrochemical attack and offer significant advantages over the much more expensive activated titanium anodes.

Claims

1. Dimensionally stable anode for electrochemical reactions characterized in that it comprises an electroconducting body impermeable to aqueous electrolytes and to gases constituted by a thermoformed mixture of graphite particles and inert thermoplastic resin powders having on at least one side thereof an electrocatalytic layer impermeable to aqueous electrolytes and gases consisting of a mixture of inert resin and particles of an oxide of at least one of the metals belonging to the group of ruthenium, iridium, platinum, palladium, rhodium, manganese, cobalt, lead, iron, tin, and nickel, the inert thermoplastic resin of the electroconducting layer forming a homogeneous matrix through the cross-section of the anode whereby the graphite particles of the electroconducting body and the particles of an oxide of the electrocatalytic layer are each fused in a continuous resin matrix, and wherein said thermoplastic resin is capable of being fused to produce a substantially impervious body.

2. Anode of claim 1 characterized in that any surface of the conducting body which is not covered by the electrocatalytic layer which is impermeable to aqueous electrolytes and gases is coated by an impervious and insulating layer of resin.

3. Anode of claim 1 characterized in that the quantity of resin contained in the mixtures is comprised between about 15 and about 40% by weight.

4. Anode of claim 1 characterized in that the average diameter of the graphite particles is lower than 100×

10^-6 millimeters.

14. The anode of claim 1 wherein the quantity of resin in the mixtures is no greater than 25% by weight.

5. An electrolytic cell electrode which comprises a carbon substrate having an electroconductive active substantially impermeable surface portion comprising electroconductive particles having a lower oxygen overvoltage than carbon bonded together by a fused thermoplastic inert fluorocarbon polymer capable of being fused to produce a substantially impervious body.

6. The electrode of claim 5 wherein the carbon substrate comprises carbon particles which are bonded together by an inert fused thermoplastic fluorocarbon polymer.

7. The electrode of claim 6 wherein the melting or softening point of the polymer of the substrate is substantially the same as that of the surface polymer.

8. A method of electrolyzing an aqueous solution which comprises conducting the electrolysis with at least one electrode comprising an electroconductive carbon substrate having an electroconductive substantially impervious surface comprising electroconductive particles having a lower oxygen overvoltage than carbon bonded together by a fused thermoplastic and inert fluorocarbon polymer capable of being fused to produce a substantially impervious body.

9. The method of claim 8 wherein the carbon substrate comprises carbon particles which are bonded together by a fused and inert fusible fluorocarbon polymer.

10. The method of claim 9 wherein the aqueous solution is acidic and the electrode is an anode.

11. The method of any of claims 8, 9 or 10 wherein the aqueous solution is a solution of a chloride salt and the electrode is an anode.

12. The method of any of claim 8, 9 or 10 wherein the aqueous solution is a salt of a metal which can be electrodeposited and the electrode is an anode.

13. A method of electrolyzing an aqueous electrolyte which comprises conducting the electrolysis in a cell having an anode which is impermeable to aqueous electrolytes and to gases and which comprises an electroconductive substrate comprising electroconductive particles bonded together by a fused thermoplastic resin resistant to the electrolysis and an electroconductive surface layer impermeable to aqueous electrolytes and gases comprising electroconductive particles of oxygen or chlorine overvoltage lower than the particles of the base bonded together by a fused thermoplastic resin resistant to said electrolysis, the volume ratio of resin to conductor being higher in the surface layer than in the substrate and wherein said thermoplastic resin is capable of being fused to produce a substantially impervious body.