Sandwich glasses

• US 4,511,627 A
• Filed: 10/07/1982
• Issued: 04/16/1985
• Est. Priority Date: 10/07/1981
• Status: Expired due to Term

• Current Assignee: Bridgestone Tire Company Limited (Bridgestone Corporation)
• Original Assignee: Bridgestone Tire Company Limited (Bridgestone Corporation)
• Inventors: Tanuma, Itsuo, Naito, Kazuo, Fukuura, Yukio, Takeichi, Hideo, Ohyachi, Tomio
• Primary Examiner(s): Robinson, Ellis P.
• Application Number:
  US06/433,336
• Time in Patent Office: 922 Days
• Field of Search: 428/442, 428/429, 428/447, 428/522
• US Class Current: 428/429
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10688 Adjustment of the adherence to the glass layers
• CPC Class Codes: B32B 17/10697 being cross-linked
• CPC Class Codes: B32B 17/10788 containing ethylene vinylacetate
• CPC Class Codes: B32B 17/10853 the membrane being bag-shaped
• CPC Class Codes: C08L 2666/34 Oxygen-containing compounds, including ammonium and metal salts
• CPC Class Codes: C09J 123/08 Copolymers of ethene C09J123/16 takes precedence
• CPC Class Codes: Y10T 428/31612 As silicone, silane or siloxane
• CPC Class Codes: Y10T 428/31649 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer

Abstract

A sandwich glass comprising glass plates and an intermediate layer interposed therebetween is disclosed. The intermediate layer is formed by crosslinking or photocrosslinking a resin composition comprising an ethylenevinyl acetate copolymer and an organic peroxide or a photosensitizer under heating of the resin composition above the melting point of the copolymer.

Claims

1. A sandwich glass comprising glass plates and an intermediate layer interposed therebetween, said intermediate layer being formed by crosslinking a resin composition comprising:

(a) an ethylene-vinyl acetate copolymer having a vinyl acetate content of 15%-50% by weight,

(b) an organic peroxide selected from at least one member of the group consisting of 2-5-, dimethyl-2, 5-di(t-butylperoxy)hexane-3, t-butylcymyl peroxide, 2,5-dimethyl-2, 5-di(t-butylperoxy)hexane, dicumyl peroxide, α

,α

'"'"'bis(t-butylperoxyisopropyl)benzene, n-butyl-4,4-bis(t-butylperoxy)valerate, 2,2-bis(t-butylperoxy)butane, 1,1-bis(t-butylperoxy)cyclohexane, 1,1-bis(t-butylperoxy)3,3,5-trimethyl cyclohexane and t-butylperoxy benzoate, and

(c) a curing assistant selected from at least one member of the group consisting of acryloyloxy group-containing compounds, methacryloyloxy group-containing compounds, allyl group-containing compounds and vinyl group-containing compounds wherein said curing assistant is not a silane compound, at a temperature above the melting point of the copolymer.

3. A sandwich glass according to claim 1, wherein said organic peroxide is added in an amount of not more than 5 parts by weight based on 100 parts by weight of the ethylene-vinyl acetate copolymer.

4. A sandwich glass according to claim 1, wherein said resin composition further contains 0.5-30 parts by weight of a plasticizer selected from high-purity paraffinic oil, naphthenic oil, phthalate ester, adipate ester, sebacate ester, thioglycol, dibenzyl ether, tricresyl phosphate, dioctyl maleate and epoxy plasticizer.

5. A sandwich glass according to claim 1, wherein said curing assistant is contained in an amount of not more than 50% by weight in said resin composition.

6. A sandwich glass according to claim 1, wherein said resin composition contains not more than 5% by weight of a silane coupling agent.

2. A sandwich glass comprising glass plates and an intermediate layer interposed therebetween, said intermediate layer being formed by photocrosslinking a resin composition comprising:

(a) an ethylene-vinyl acetate copolymer having a vinyl acetate content of 15-50% by weight,

(b) a photosensitizer, and

(c) a curing assistant selected from at least one member of the group consisting of acryloyloxy group-containing compounds, methacryloyloxy group-containing compounds, allyl group-containing compounds and vinyl group-containing compounds wherein said curing assistant is not a silane compound,

under light irradiation during or after heating said resin composition at a temperature above the melting point of the copolymer.

7. A sandwich glass according to claim 2, wherein said photosensitizer is at least one substance selected from benzoin, benzophenone, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzoin isobutyl ether, dibenzyl, 5-nitro acetonaphthene, hexachloro cyclopentadiene, p-nitrodiphenyl, p-nitroaniline, 2,4,6-trinitroaniline, 1,2-benzanthraquinone and 3-methyl-1,3-diaza-1,9-benzanthrone.

8. A sandwich glass according to claim 2, wherein said photosensitizer is added in an amount of not more than 5 parts by weight based on 100 parts by weight of the ethylene-vinyl acetate copolymer.

9. A sandwich glass according to claim 2, wherein said resin composition further contains 0.5-30 parts by weight of a plasticizer selected from high-purity paraffinic oil, naphthenic oil, phthalate ester, adipate ester, sebacate ester, thioglycol, dibenzyl ether, tricresyl phosphate, dioctyl maleate and epoxy plasticizer.

10. A sandwich glass according to claim 2, wherein said curing assistant is contained in an amount of not more than 50% by weight in said resin composition.

11. A sandwich glass according to claim 2, wherein said resin composition contains not more than 5% by weight of a silane coupling agent.