Galvanized steel sheet protected by chromium and chromium oxide layers

• US 4,511,633 A
• Filed: 02/10/1984
• Issued: 04/16/1985
• Est. Priority Date: 03/21/1983
• Status: Expired due to Fees

• Current Assignee: Zincroksid SPA
• Original Assignee: Zincroksid SPA
• Inventors: Memmi, Massimo, Bruno, Roberto
• Primary Examiner(s): O'Keefe, Veronica
• Application Number:
  US06/579,079
• Time in Patent Office: 431 Days
• Field of Search: 428/659, 428/629, 428/666
• US Class Current: 428/666
• CPC Class Codes: C25D 11/38 Chromatising
• CPC Class Codes: Y10T 428/1259 Oxide
• CPC Class Codes: Y10T 428/12799 Next to Fe-base component [e.g., galvanized]
• CPC Class Codes: Y10T 428/12847 Cr-base component

Abstract

Steel sheet, especially suitable for car-body fabrication, galvanized and further protected by a layer of metallic chromium and hydrated oxides of chromium, electrolytically deposited. The improvement is that the metallic chromium is present in extremely fine particles that exert a very marked covering and protective effect on the underlying zinc. In this way, and with the help of the chromium oxides that further cover and protect the underlying layers, a product is obtained whose corrosion resistance is far superior to that of similar products.

Claims

1. Steel sheet, protected by a zinc coating overlaid with a protective layer of chromium and hydrated oxides of chromium, the chromium metal being in the form of particles having average dimensions of about 0.03 micron, while at least 40% by volume of the metallic chromium is in the form of particles measuring less than 0.02 micron.

2. Steel sheet as claimed in claim 1, in which the protective layer of metallic chromium and hydrated oxides of chromium has a total chromium content of between 0.2 and 1.0 g/m², the chromium metal accounting for between 80 and 90% of that figure, the remainder being chromium contained in the oxides.

3. Steel sheet as claimed in claim 2, in which the total chromium content of the protective layer is between 0.4 and 0.6 g/m².

4. Steel sheet as claimed in claim 1, in which the metallic chromium layer leaves uncovered areas averaging less than 0.02 micron in size, the total proportion of uncovered zinc being less than 0.1% of the total area.

5. Steel sheet as claimed in claim 1, in which the chromium-oxide layer is colloidal and non-crystalline and is insoluble in water and alkalis and only very slightly soluble in acids.

6. Steel sheet as claimed in claim 1, in which the maximum particle size of the chromium metal is about 0.07-0.08 micron.