Method and means for stepwise charge control of electrochromic layers

• US 4,512,637 A
• Filed: 10/22/1982
• Issued: 04/23/1985
• Est. Priority Date: 10/29/1981
• Status: Expired due to Fees

• Current Assignee: Carl-Zeiss-Stiftung
• Original Assignee: Carl-Zeiss-Stiftung
• Inventors: Ballmer, Horst
• Primary Examiner(s): Corbin, John K.
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US06/436,173
• Time in Patent Office: 914 Days
• Field of Search: 350/357, 340/785, 340/763
• US Class Current: 359/275
• CPC Class Codes: G02F 1/163 Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor

Abstract

In order to control the absorptance of an electrochromic layer, the invention provides a plurality of steps for establishing different levels of coloring action. Quantities of charge are supplied to and removed from the layer, via one or the other of two constant-current sources, timed with clock pulses to a forward/backward counter. For decoloring processes, smaller quantities of charge are removed from the layer than are supplied to it during a corresponding coloring process. The quantities of charge removed for decoloring processes are, however, slightly greater than the quantities of removed charge needed to reach steps having exactly the same absorptance, so that even in the case of numerous changes between the color steps, destruction of the layer is definitely avoided. Preferred fields of use are lenses, particularly eyeglass lenses, filters and dimmable mirrors, each having an applied electrochromic layer whose absorptance is controlled for step-wise change.

Claims

1. Apparatus for step-wise charge control of an electrochromic layer, said layer being in uncolored state for the condition of no charge in said layer, said layer being colored to a first state for a first charge in said layer, and said layer being colored to a second and greater colored state for a second and greater charge in said layer, said apparatus comprising:

selectively operable means for selecting a change of layer state to one of said states regardless of the currently existing state of said layer;

said selectively operable means including comparator means responsive both to the existing state and to the selected state and having (1) a first control output for the case of the layer in the selected state being more colored than in the existing state (A<

B), (2) a second control output for the case of the layer in the selected state being less than in the existing state (A>

B);

a constant-current charging circuit connected to charge said layer in the event of a signal in said first control output;

a constant-current charge-removal circuit connected to remove charge from said layer in the event of a signal in said second control output;

first interval-timing means connected for response to said first control-output signal and connected to said charging circuit to determine a timed incremental charge in said layer in the direction of increased color development in said layer, and second interval-timing means connected for response to said second control-output signal and connected to said constant-current charge-removal circuit to determine a timed decremental removal of charge from said layer, the timed interval for a charging increment to produce a given layer-coloring increment under control of said first interval-timing means being greater than the timed interval for a corresponding decrement of charge removal to produce a corresponding color-removing decrement under control of said second interval-timing means, and said decrement of color removal being selected to be slightly in excess of the increment of layer coloring, whereby regardless of the number of selected increment-decrement cycles there will be no cyclic growth in the coloring of said layer.

2. Apparatus according to claim 1, in which said first interval-timing means includes a first generator of clock pulses and said second interval-timing means includes a second generator of clock pulses, said first generator producing pulses of lower repetition frequency than the repetition frequency of second-generator pulses, and counting means connected to both of said generators to count a predetermined number of clock pulses, whereby for a first control-output signal the predetermined number of counted first-generator pulses will determine a greater interval than said predetermined number of counted second-generator pulses in the event of a second control-output signal.

3. Apparatus according to claim 1, in which said first and second colored states are part of a greater plurality of colored states for a corresponding plurality of different charges in said layer.

4. Apparatus according to claim 2, in which said counting means includes a forward/backward counter whereby a reading of said counter characterizes the state of the color of said layer.

5. Apparatus according to claim 4, in which said selectively operable means includes means for selecting one of a plurality of predetermined counter readings corresponding to a desired one of a plurality of states of the color of said layer, and in which said comparator means is responsive to the selected counter reading and to the existing counter reading.

6. Apparatus according to claim 5, in which the maximum selectable counter reading corresponds to the maximum tolerable charge in said layer.

7. Apparatus according to claim 5, in which the means for selecting one of a plurality of predetermined counter readings comprises one key for each of said plurality, and storage means (40) and encoding means (41 to 44) associated with the respective keys.

8. Apparatus according to claim 5, in which the means for selecting one of a plurality of predetermined counter readings comprises an optical sensor (70) electrically responsive to sensed brightness, and an A/D converter connecting the output of said sensor to said comparator means.

9. Apparatus according to claim 8, in which said A/D converter is in the form of a comparator chain (72).

10. Apparatus according to claim 8, in which said A/D converter comprises a plurality of operational amplifiers (97 to 99) connected as differential voltage compensators with hysteresis.

11. Apparatus according to claim 2, in which said first clock-pulse generator is one of a plurality of different clockpulse generators available for use in the incrementing of charge in said layer, each of the generators of said plurality being of different characteristic pulse-repetition frequency, whereby a different interval is timed by each generator of said plurality for the predetermined number counted by said counting means, and means responsive to the existing state of said counting means for determining which one of said plurality of generators is to be connected for a further coloriing of said layer, whereby each one of said plurality of generators may serve a different fraction of any non-linearity in the coloring response of said layer.

12. Apparatus according to claim 2, in which (a) said counting means includes a forward/backward counter, (b) said comparator means includes an A=B output, and (c) said selectively operable means includes a coding device (41 to 44) having an input characterized by a plurality of NAND gates (45 to 48) connected via an OR gate (81) to said A=B output, said OR gate (81) being also connected via a flank-differentiating network (82, 83), and inverter and delay elements (84) to the input (22) of the forward-backward counter.

13. Apparatus according to claim 2, in which (a) said counting means includes a forward/backward counter, (b) said comparator means includes an A=B output, and (c) said selectively operable means includes a coding device (41 to 44) having an input characterized by a plurality of NAND gates (45 to 48) connected via and OR gate (81) to said A=B output, said OR gate (81) being also connected via a flank-differentiating network (82, 83) and logic elements to the output of the forward/backward counter.

14. Apparatus according to claim 1, in which each of said constant-current circuits utilizes the emitter circuit of a transistor (14, 15) as the constant-current source, the respective transistors being connected via base resistors (16, 17) to said comparator means.

15. Apparatus according to claim 1, wherein said electrochromic layer is an element of a sunglass lens.

16. Apparatus according to claim 1, wherein said electrochromic layer is an element of a dimmable mirror.

17. Apparatus according to claim 1, wherein said electrochromic layer is an element of an optical filter.