Processing of lignocellulose materials

• US 4,515,816 A
• Filed: 02/23/1983
• Issued: 05/07/1985
• Est. Priority Date: 02/23/1983
• Status: Expired due to Fees

• Current Assignee: Naturlizer Incorporated
• Original Assignee: Agro-Systems Incorporated
• Inventors: Anthony, Wilson B.
• Primary Examiner(s): Penland, R. B.
• Application Number:
  US06/469,131
• Time in Patent Office: 804 Days
• Field of Search: 426/54, 426/69, 426/626, 426/636, 426/807
• US Class Current: 426/69
• CPC Class Codes: A23K 10/26 from waste material, e.g. feathers, bones or skin A23K10/24 takes precedence
• CPC Class Codes: A23K 10/32 from hydrolysates of wood or straw
• CPC Class Codes: A23K 50/15 containing substances which are metabolically converted to proteins, e.g. ammonium salts or urea
• CPC Class Codes: Y10S 426/807 Poultry or ruminant feed

Abstract

Lignocellulose-containing materials are chemically converted to a form which is suitable for feeding to ruminant animals by wetting the materials with dilute acid, storing the wet material at ambient temperature and pressure in a low acid environment to effect mild hydrolysis of the materials, drying the acidified materials and partially neutralizing the dried material with ammonia.

Claims

1. A process for treating lignocellulose-containing material to render it amenable to digestion by ruminant animals comprising:

adding dilute aqueous acid to the material to form a wet mass in which the pH is in the range of about 2-3, the concentration of the added acid being sufficient to effect acid hydrolysis of the lignocellulose-containing material without charring thereof;

storing the wet acidified mass in a low oxygen environment in a closed vessel for a time period of about 5 to about 21 days under ambient conditions of temperature and pressure; and

drying the wet acidified mass thereby enhancing the effect of the acid on the mass.

2. A process as in claim 1 wherein the dried mass is thereafter neutralized by adding ammonia thereto.

3. A process as in claim 1 wherein the acid is aqueous sulfuric acid of a concentration in the range of about 1.5% to 5% by weight.

4. A process as in claim 3 wherein the amount of concentrated acid is 1.5% to 2.5% by weight of the dry weight of the lignocellulose material.

5. A process as in claim 1 wherein the wet acidified mass is dried to a moisture content of not greater than about 13% by weight.

6. A process as in claim 2 wherein the wet acidified mass is dried to a moisture content of not greater than about 13% by weight and wherein the ammonia is anhydrous ammonia.

11. A process as in claim 1 wherein said acid is a mineral acid.

7. A process for treating lignocellulose material to render it amenable to digestion by ruminant animals comprising:

adding to the lignocellulose dilute aqueous sulfuric acid of strength 2% to 5% by weight in an amount equal to 1.5% to 2.5% of concentrated acid based on the weight of the initial lignocellulose material to thereby form a wet mass containing about 40% to 80% by weight water;

storing the wet acidified mass in a closed vessel for a period of about 5 to 21 days under ambient temperature and pressure;

drying the wet acidified mass after storage to a moisture content no greater than about 13% by weight; and

adding anhydrous ammonia to the thus dried mass in an amount to give the mass a pH in the range 4.5 to 5.5.

8. A two-stage acid hydrolysis process for treating lignocellulose-containing material to render it amenable to digestion by ruminant animals comprising:

in a first stage adding to the material dilute aqueous mineral acid selected from the group consisting of sulfuric acid, hydrochloric acid, phosphoric acid and sulfurous acid to form a wet mass containing free liquid, in which mass the pH is in the range of about 2-3, the concentration of the added acid being in a range effective to cause acid hydrolysis of the lignocellulose-containing material without charring thereof and storing the wet acidified mass in a low oxygen environment for a time period of about 5 to about 21 days under ambient conditions of temperature and pressure to thereby effect substantial disruption of lignin-cellulose bonds in the material by acid hydrolysis; and

in a second stage drying the wet acidified mass to a moisture content of not greater than about 13% by weight to concentrate the acid within the lignocellulose material by removal of water thereby enhancing the oxidative effect of the concentrated acid on the material and enhancing breakdown of the lignin-cellulose bond and freeing of the cellulose.

9. A process as in claim 8 wherein the drying step is an ambient air drying step carried out by dispersal of the material in ambient air and leaving the dispersed material in contact with the ambient air for at least several days.

10. A process as in claim 9 including the further step of neutralizing the dried material to a pH of 4.5 to 5.5 by adding anhydrous ammonia thereby forming an ammonium salt.