Method of producing a porous body for electrolytic capacitor having a lead wire

• US 4,517,727 A
• Filed: 06/28/1983
• Issued: 05/21/1985
• Est. Priority Date: 06/28/1982
• Status: Expired due to Term

• Current Assignee: NEC Corporation
• Original Assignee: NEC Corporation
• Inventors: Igarashi, Hitoshi, Suzuki, Tetsuo, Kubo, Yoshimi, Arai, Yoshio, Shimizu, Shigeaki
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): Schiavelli, Alan E.
• Application Number:
  US06/509,153
• Time in Patent Office: 693 Days
• Field of Search: 29/570, 361/433, 419/2
• US Class Current: 29/25.03
• CPC Class Codes: H01G 9/045 based on aluminium
• CPC Class Codes: H01G 9/052 Sintered electrodes

Abstract

A porous sintered body for an aluminum-titanium alloy electrolytic capacitor has a wire of nitrogenized titanium, or the like, implanted therein. A method of producing such a porous body subjects a titanium wire to a nitriding treatment, and embeds the nitrogenized Ti wire into a press-molded body of the mixture of aluminum and either titanium or titanium hydride powders. Then, the press-molded body is sintered. An excellent LC characteristic is obtained even under the sintering condition, and the aluminum-titanium electrolytic capacitor is devoid of bent lead wires.

Claims

1. A method for producing a porous sintered body for an Al-Ti solid electrolytic capacitor equipped with a lead wire, comprising steps of subjecting a titanium wire to a nitriding treatment, embedding said wire into a mixture of aluminum powder and titanium powder, press-molding the mixtureof said powders with said wire, an sintering the resulting press-molded article.

2. A method for producing an Al-Ti alloy solid electrolytic capacitor comprising the steps of mixing aluminum powder and titanium powder, subjecting a titanium wire to a nitriding treatment, press-molding the mixture of said powders with a part of said wire, sintering the resulting press-molded article in aluminum-vapor atmosphere thereby forming a porous Al-Ti alloy body while forming an Al-Ti alloy region into the surface of said wire, anodizing the resulting sintered article to form a dielectric layer onto said sintered article, and forming cathode layers onto said dielectric layer formed on said porous Al-Ti alloy body.

3. A method for producing an Al-Ti alloy solid electrolytic capacitor as claimed in claim 2, in which said aluminum-vapor is generated from said porous Al-Ti alloy body at the time of said sintering process.

4. A method for producing an Al-Ti alloy solid electrolytic capacitor as claimed in claim 2, in which said wire is prepared by heating a pure titanium wire in a nitrogen atmosphere for converting the surface of said titanium wire into a titanium nitride layer, and diffusing aluminum into said titanium nitride layer by heating said wire in aluminum-vapor atmosphere, said aluminum-vapor being generated from said porous Al-Ti alloy body at the time of said sintering step, thereby forming an Al-Ti alloy layer into said titanium nitride layer, said Al-Ti alloy layer having a composition containing 30 to 70 atom % of aluminum.

5. A method for producing an Al-Ti alloy solid electrolytic capacitor comprising the steps of heating a titanium wire in a nitrogen atmosphere at a temperature in the range of substantially 1,000°

C. to 1,300°

C. for converting the wire surface into a titanium nitride layer, mixing aluminum powder and titanium powder, press-molding the mixture of said powders into a body while embedding a part of said wire into said body, heating the resulting press-molded article in an aluminum-vapor atmosphere for converting said body into a porous Al-Ti alloy body while converting the wire surface into a Al-Ti alloy layer, said aluminum-vapor being generated from said porous Al-Ti alloy body at the time of said heating process, anodizing the resulting heat-treated article in an aqueous phosphoric acid solution for forming a dielectric layer onto said porous Al-Ti alloy body, forming a manganese dioxide layer onto said dielectric layer, and forming a cathode electrode layer onto said manganese dioxide layer.

6. A method for producing a porous sintered body for an Al-Ti solid electrolytic capacitor equipped with a lead wire, comprising steps of subjecting a titanium wire to a nitriding treatment, embedding said wire into a mixture of aluminum powder and titanium hydride powder, press-molding the mixture of said powders with said wire, and sintering the resulting press-molded article.

7. A method for producing an Al-Ti alloy solid electrolytic capacitor comprising the steps of mixing aluminum powder and titanium hydride powder, subjecting a titanium wire to a nitriding treatment, press-molding the mixture of said powders with a part of said wire, sintering the resulting press-molded article in aluminum-vapor atmosphere thereby forming a porous Al-Ti alloy body while forming an Al-Ti alloy region into the surface of said wire, anodizing the resulting sintered article to form a dielectric layer onto said sintered article, and forming cathode layers onto said dielectric layer formed on said porous Al-Ti alloy body.

8. A method for producing an Al-Ti alloy solid electrolytic capacitor comprising the steps of heating a titanium wire in a nitrogen atmosphere at a temperature in the range of substantially 1,000°

C. to 1,300°

C. for converting the wire surface into a titanium nitride layer, mixing aluminum powder and titanium hydride powder, press-molding the mixture of said powders into a body while embedding a part of said wire into said body, heating the resulting press-molded article in an aluminum-vapor atmosphere for converting said body into a porous Al-Ti alloy body while converting the wire surface into a Al-Ti alloy layer, said aluminum-vapor being generated from said porous Al-Ti alloy body at the time of said heating process, anodizing the resulting heat-treated article in an aqueous phosphoric acid solution for forming a dielectric layer onto said porous Al-Ti alloy body, forming a manganese dioxide layer onto said dielectric layer, and forming a cathode electrode layer onto said manganese dioxide layer.