Process for improving product yields from delayed coking

• US 4,518,487 A
• Filed: 03/19/1984
• Issued: 05/21/1985
• Est. Priority Date: 08/01/1983
• Status: Expired due to Term

• Current Assignee: Conoco Incorporated (ConocoPhillips)
• Original Assignee: Conoco Incorporated (ConocoPhillips)
• Inventors: Janssen, Harry R., Graf, Harlan G.
• Primary Examiner(s): Gantz, Delbert E.
• Assistant Examiner(s): Myers, Helane
• Application Number:
  US06/590,607
• Time in Patent Office: 428 Days
• Field of Search: 208/131
• US Class Current: 208/131
• CPC Class Codes: C10B 55/00 Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material cracking oils C10G
• CPC Class Codes: C10B 57/045 containing mineral oils, bitumen, tar or the like or mixtures thereof
• CPC Class Codes: C10G 9/005 Coking (in order to produce liquid products mainly)

Abstract

A delayed coking process in which the coker furnace feed is free of conventional heavy recycle. Elimination of this material from the coker furnace feed produces, based on fresh feed to the process, increased liquids and decreased coke. Coker furnace feed is initially combined with a diluent hydrocarbon having a lower boiling range than conventional heavy coker recycle and then transferred to the coker furnace. The hydrocarbon diluent is much lower in coke-forming components than the heavy recycle which is normally combined with the fresh feed and fed to the coker furnace.

Claims

1. A process for improving the product yields from delayed coking of a heavy hydrocarbon oil feedstock in a coking unit comprising a coker furnace, a coking drum and a coker fractionator to produce delayed coke and cracked liquid and gaseous hydrocarbon products comprising the steps of:

(a) delayed coking said heavy hydrocarbon oil in said coking drum under conditions at which delayed coke having a volatile matter content of not more than 15 percent by weight is produced;

(b) passing overhead vapors from said coking drum to said coker fractionator;

(c) condensing the highest boiling fraction of said overhead vapors and removing said fraction from said process; and

(d) adding a diluent hydrocarbon having a lower boiling range than said highest boiling fraction to said heavy hydrocarbon oil feedstock prior to heating said heavy hydrocarbon oil feedstock to coking temperature in said coker furnace, said diluent hydrocarbon being added in an amount sufficient to effectively prevent coke deposition in said coker furnace, whereby the yield of delayed coke having a volatile matter content of less than 15 percent by weight is lower, and the liquids yield is higher, than the yields which would be obtained if said highest boiling fraction of said overhead vapors were combined with said feedstock.

2. The process of claim 1 wherein delayed coke having a volatile matter content of from 6 to 12 percent by weight is produced.

3. The process of claim 1 wherein said feedstock is initially combined with said diluent hydrocarbon, fed to a feed surge drum, and then passed directly, without addition of any other hydrocarbon material, to said coker furnace.

4. The process of claim 1 wherein said diluent hydrocarbon has a boiling range of from about 450°

to about 750°

F.

5. The process of claim 1 wherein said diluent hydrocarbon has a boiling range of from about 510°

to about 650°

F.

6. The process of claim 1 wherein said diluent hydrocarbon is a product sidestream from said coker fractionator.

7. The process of claim 6 wherein said feedstock is selected from the group consisting of petroleum vacuum resid, petroleum atmospheric resid, coal tar pitch, tar sand bitumen, slurry oil, decant oil, shale oil, pyrolysis tar and mixtures thereof.

8. The process of claim 6 wherein heavy gas oil from said coker fractionator is returned to a flash zone of said fractionator to contact incoming coker vapors and condense the highest boiling fraction therefrom.

9. The process of claim 8 wherein said diluent hydrocarbon is the only material combined with said feedstock prior to feeding said feedstock to said coker furnace.